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酰化

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Manganese oxides supported on SBA-15 Mn(subscript xO/SBA-15 were prepared by incipient wetness impregnation of SBA-15 with furfuryl alcohol solution of manganese acetylacetonate or manganese nitrate followed by removal of the carbon resulted from carbonized FA.

采用溶液浸渍法将乙酰丙酮锰或硝酸锰的糠醇溶液分别灌注到SBA-15的孔道内,一定条件下将糠醇碳化后再将碳烧除,即可得到高度分散的MnO/SBA-15复合催化剂。

Treatment under mild condition with solvent of lower polarity was in favor of keeping the molecular structure and properties such as water-solubility, gelatination, etc. Acetyl groups were partially eliminated when purified by Pb2 method, leading to increased crystallinity and glass temperature, which resulted in losts of water-solubility and gelatinability. Owing to the slight oxidative degradation with H2O2 method, the changes of chain size and some functional groups of KGM molecule led to decrease of viscosity and excessive swelling rate.

采用温和条件及低极性溶剂有利於保持KGM本身的分子结构以及水溶性、凝胶性等性能;而Pb2法由於部分脱去了KGM的乙酰基,导致结晶度变大,玻璃化温度升高,最终失去水溶性和凝胶性;H2O2法则由於对KGM造成了氧化降解,也改变了分子链的大小以及部分基团,从而导致粘度降低以及溶涨速度较快。

In these chloroplasts carbon dioxide combines with phosphoenolpyruvate to form oxaloacetic acid, which is transported to the bundle sheath cells, where the carbon dioxide is released, then fixed by the enzyme ribulose bisphosphate carboxylase to form glycerate 3-phosphate, the first step in the Calvin cycle.

在叶肉细胞的叶绿体中二氧化碳与磷酸烯醇丙酮酸结合形成草酰乙酸,后被运到邻近的维管束鞘细胞,在那里二氧化碳被释放,后被核酮糖二磷酸羧化酶固定形成3-磷酸甘油酸,这是卡尔文的循环第一步。

The latter is hydrolyzed in the acidic conditions, then the recovered copolymer of EO and glycidol with multi pending hydroxymethyls is esterified with 2-bromoisobutyrylbromide to produce the ATRP macroinitiator with multi pending bromoisobutyryl groups .

共聚物poly的羟基与2-溴异丁酰溴进行酯化反应,得到侧链挂有2-溴异丁酸酯基结构的可以用于原子转移自由基聚合体系的大分子引发剂Poly_

The pegylated polylactide-poly glycolide nanoparticle, whose surface was co-modified withmaleimide-polyethylene glycol and methoxy-polyethylene glycol, was made by double-emulsion and solvent evaporation method andcovalently conjugated with thiolated lactoferrin via its maleimide functionalgroup.

第一章首先由复乳/溶媒蒸发法制备马来酰亚胺—聚乙二醇(Maleimide-PEG,MAL-PEG)和甲氧基聚乙二醇表面共修饰的聚乳酸-聚羟基乙酸纳米粒,然后通过其表面MAL-PEG与巯基化Lf共价连接而制备Lf-NP_。

In this dissertation, the sodium bentonite was modified using hexadecyl trimenthyl ammonium bromide and cationic polyacrylamide.

本文以市售钠基膨润土为原料,分别以十六烷基三甲基溴化铵和阳离子聚丙烯酰胺为改性剂,制各了新型复合插层有机膨润土。

The sodium bentonite was modified by organic reagent hexadecyl trimenthyl ammonium bromide and cationic polyacrylamide. The structures of modified organo-bentonite and the effect of concentration of the intercalating reagent and reacting time on decoloring capacity were studied.

用阳离子有机改性剂十六烷基三甲基溴化铵和阳离子聚丙烯酰胺复合插层改性钠基膨润土,分析了改性膨润土的结构,研究了改性剂质量浓度及二次改性时间对复合插层膨润土脱色效果的影响。

Based on this monomer, several novel polyimides bearing side chain s composed of cyano-biphenyl mesogenic end groups and hexylene spacer were prepared.

合成了一种含氰基联苯氧基侧链的二元胺单体,然后通过两步法热酰亚胺化工艺制备了新型的含氰基联苯基团侧链的聚酰亚胺。

The amphiphiles, 4-8, can not form reverse bilayers in organic solvent, which result in that the molecular interactions unable to meet the need for hydrophile-lypophile balance, so that they crystallize and exhibit no gelling abilities. The mono-chained L-alanine derivatives, 1-3, can self-assemble into bilayer aggregates, through intermolecular hydrogen bonding and homochiral effect in a number of organic liquids, which are juxtaposed and interlocked by van der Waals interaction, and finally gelate the organic liquids.

单链酰基化L-丙胺酸两亲物1-3在一些低极性的有机溶剂可以通过分子间氢键相互作用及同手性聚集作用形成有序的反双分子膜结构,这些有序反双分子膜结构单元依靠vander Waals力相互作用可以平行排列且相互之间进行连结形成长纤维状的聚集体,纤维状聚集体在有机介质中可以进一步相互连结形成三维网状结构,进而胶凝有机溶剂。

Results CsA clearly decreased creatinine clearance and increased urinary excretion of N-acetyl-β-D-glucosaminidase in rats as compared with those in the vehicle group. Morphologic changes consisted of vacuolization of tubular cell, expansion of the interstitium and interstitial fibrosis, hyalinization of afferent arterioles. Severity of the injury was related to the dosage of CsA. Striped interstitial fibrosis and arteriolopathy were more severe in the rats treated with CsA and low-salt diet than with CsA and normal diet.

结果 用CsA的大鼠出现尿量增多、内生肌酐清除率下降、尿N-乙酰-β-D-氨基葡萄糖苷酶排泄增多等;病理上表现为不同程度的细胞浊肿、空泡变性及灶性分布的间质纤维化和小动脉病变,随CsA剂量的增加,病变呈加重趋势;结合低钠饮食,CsA慢性肾毒性病变明显加重。

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