酰化

The effects of reaction time and acetic anhydride/anhydroglucose unit molar ratio on the DS of starch acetates were investigated.

考察了反应时间和酰化试剂用量对酰化程度的影响。

Histone acetylation and deacetylation are crucial in the regulation of gene expression.

组蛋白乙酰化和去乙酰化对基因表达的调控至关重要，基因表达的动态变化将会影响染色质的结构。

The glutamine synthetase produced by the engineering bacteria can specially act on NH4 and aminoglutaric acid, the durability to the high concentration ammonium ion has been distinctively improved because of the dissolution of adenosine acylation modification, the major bottleneck of glutamine with enzymatical production has been solved, and the concentration of the obtained glutamine can reach 47.6g/L.

本发明工程菌产的谷氨酰胺合成酶可专一性的作用于NH 4 和谷氨酸，且因解除了腺苷酰化修饰作用对高浓度铵离子的耐受能力显著提高，解决了酶法生产谷氨酰胺的重要瓶颈，生成的谷氨酰胺的浓度最高达到47.6g/L。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

This study was based on the soy protein isolates as raw materials. Chemical modification( acetylation,succinylation ,phosphorylation and urea modification) of SPI were used to improve adhesive strength and water resistance of SPI-based plywood adhesives. Then two modified ways combined were applied to SPI and their adhesive properties were studied. This research also characterized the thermal and adhesive properties of two major soy protein components 7S conglycinin and 11S glycinin after urea modification. Finally, the mechanism of improving SPI's adhesive properties was preliminarily discussed.

本文是以大豆分离蛋白为原料，进行SPI的化学修饰以提高其胶粘特性；采用了磷酸化试剂三聚磷酸钠、乙酰化试剂乙酸酐、琥珀酰化试剂琥珀酸酐和有机溶剂尿素修饰和变性SPI，研究修饰和变性后的SPI作为木材胶粘剂的胶粘性与耐水性，同时研究了两种方法复合修饰SPI对其粘度、胶粘强度和耐水性的影响；然后以SPI为原料，进行7S和11S球蛋白的提取以及胶粘特性的研究，对SPI起胶粘特性的机理进行了初步探讨。

Process for the preparation of phosphatidylserine of formula wherein R and R independently represent a saturated, mono-unsaturated or polyunsaturated acyl C10-C30, X=OH or OM where M=alkaline or alkaline earth metal, ammonium, alkylammonium including the transphosphatidylation reaction between phosphatidylcholine of the general formula wherein R and R and X have the above specified meanings, R=CH2-CH2- NH2 o CH2-CH2-N(CH3)3 and Serine in D, L or racemic form catalysed by the phospholipase D enzyme, characterised in that said reaction is carried out in a hydroalcoholic medium containing an aliphatic alcohol and in the presence of bivalent metal oxide.

本发明涉及制备式CH 2 OR 1 CHOR 2 CH 2 O-P-OCH 2 -CH(NH 2 )-COOHX的磷脂酰丝氨酸的方法，其中R 1 和R 2 独立地表示饱和的、单不饱和的和/或多不饱和的酰基C 10 -C 30 ，X＝OH或OM，其中M＝碱或碱土金属、铵、烷基铵，该方法包括通式CH 2 OR 1 CHOR 2 CH 2 O-P-OR 3 X的磷脂酰胆碱其中R 1 和R 2 以及X具有上述特别的含义，R 3 ＝CH 2 -CH 2 -NH 2 或CH 2 -CH 2 -N (CH 3 3 与D、L或外消旋形式的丝氨酸之间的转磷脂酰化反应，该反应是通过磷脂酶D酶催化的，其特征在于所述的反应是在包含脂族醇的含水醇介质中并且在二价金属氧化物的存在下进行的。

Expanding on our demonstration that acylated peptides derived from the large HBV envelope protein block virus entry in vitro, we show their applicability to prevent HBV or woolly monkey hepatitis B virus infection in vivo, using immunodeficient urokinase-type plasminogen activator mice repopulated with primary human or Tupaia belangeri hepatocytes.

已有的研究《Hepatitis B virus infection initiates with a large surface protein-dependent binding to heparan sulfate proteoglycans》（2007 Hepatology）表明来源于大蛋白的酰化多肽在体外能阻断病毒的进入。利用人源化肝脏或树鼩肝细胞的小鼠模型进行的新研究进一步证实，大蛋白的酰化多肽在防止HBV或者绒毛猴HBV体内感染中具有可行性。

The oxylated SEBS and acetylated SEBS were obtained byFriedel-Crafts reactions using the mild catalyst of 〓/〓 complex.

通过SEBS的草酰化及其产物的水解或SEBS的乙酰化及其产物的氧化可以得到单分散的羧化SEBS。

The optimal derivatization condition is reducting reaction 2.5h at 50℃followed by acetylating 2.5h at 90℃.

总结出了单糖衍生化最佳的反应条件为还原温度50℃、还原时间2.5h；乙酰化温度90℃、乙酰化时间2.5h。

Respectively, glutamic acid derivatized β-CD has been synthesized with epoxy chloropropane as the intermediate, a water-insoluble yellow liquid was got after the acetylating of the by using acetic anhydride, which was used as a novel gas chromatographic CSP; A water-soluble β-CD polymer cross-linked with epoxy chloropropane has been synthesized, and the derivatives of β-CD polymer were synthesized by its alkylating and acetylating. The different β-CD derivatives were coated on silica capillary columns by dynamic method, the chromatographic properties and retention behaviors of the fused silica capillary columns were studied, the results showed that the β-CD derivatives had good stereoselectivity and separation results to some compounds, especially to various positional isomers and enantiomers.

本文还分别以环氧氯丙烷为中间体，合成了七{2，6-二-O-[3-(1，3-二羟基丙氨酸)]}-β-环糊精，再用醋酸酐将其乙酰化，得到了一种淡黄色粘稠液体，合成了一种新型的环糊精衍生物；以环氧氯丙烷作交联剂合成了一种水溶性的β-环糊精聚合物，再将其烷基化和酰基化，合成了β-环糊精聚合物的不同衍生物，用动态法将不同类型的β-环糊精衍生物涂渍在石英毛细管柱上，通过对所制备柱柱性能的测试和对一系列化合物的分离和保留行为的研究，结果表明所合成的β-环糊精衍生物对各类化合物，特别是对位置异构体和对映异构体具有较好的分离效果，显示了很强的立体选择性。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。