酰化

The side-chain liquid crystal polymacrylate was synthesized by free radical polymerization form the acrylate monomer which was generated from p-hydroxy benzoic acid, ethylene chlorohydrin and acrylic acid by etherification, esterification and chloration.

以对羟基苯甲酸、氯乙醇和丙烯酸为主要原料，经醚化、酯化和酰氯化反应合成了中间体和含液晶基元的丙烯酸酯单体，后者经自由基聚合合成了聚丙烯酸酯侧链液晶聚合物。

In this dissertation, systematic and extensive conformational search has been performed for asparagine and aspartic acid in gas phase and solution and the properties of the stable conformers are studied using DFT based first-principles calculation. The concerned properties include geometry structure, IR spectra, conformer distributions, intramolecular interactions, ionization energies and electron affinities, protonation and deprotonation processes.

在本论文中，我们对天冬酰胺和天冬氨酸在气相和溶液中的稳定构型进行了系统而全面的寻找，并研究了其稳定构型的几何结构、红外光谱、构型分布、分子内相互作用、电离能、电子亲合能、质子化和去质子化过程等相关性质。

Our data provide a molecular basis for the interplay of histone demethylation and deacetylation in chromatin remodeling.

这些数据为乳腺癌的脱甲基化和脱乙酰基化的研究提供了分子基础。

A novel series of naphthalimide dendrimers has been synthesized, into whose dendron novel specific function units are introduced. The absorption and fluorescence properties of the arrays were studied and discussed. Excitation of the terminal donor chromophores carbazole mainly results in the fluorescence of the core dye alone, whose efficiency is dependent on the dendrimer generation.

在树枝上引入特定的功能单元，将多个具有特定功能团连接起来，形成功能化树枝状周边分子团簇，然后将它们分别与核心色素萘酰亚胺相连接，合成新型周边树枝状功能化的有机发光材料。

The resultant was hydrogenised to remove protective group of amino group, then the product was reacted with NaNO2 to give diazonium salt, which was conjugated with salicylic acid, hydroxybenzene, N-salicyloyl glycine acid to get azo derivatives of 4-ASA.

本文首先对4-ASA的氨基和羟基进行了选择性保护，通过氢化还原法选择性脱除氨基的保护基，然后将氢化产物制成重氮盐，通过与水杨酸、苯酚和水杨酰甘氨酸发生反应生成4-ASA的偶氮衍生物，最后在碱性条件下水解得到最终产物。

The synthesis of a series of photo generating acid by alkylation, acyl chloriding, esterification with the available anthraquinone-2-sulfonic Na is emphasized.

本文以商业化的蒽醌-2-磺酸钠为原料，经过烷基化、酰氯化、酯化3个步骤合成了一系列释酸剂，并利用红外谱图，对每一步所得结构进行表征，对影响反应的因素进行了研究，并对释酸剂的应用结果进行了讨论。

An abnormal condition caused by excessive intake of fluorine ,as from fluoridated drinking water,characterized chiefly by mottling of the teeth.

氟中毒由于过量摄入氟而导致牙齿产生色斑的不正常状况，如饮用氟化的水全氟胍可以由于的三聚氰酰胺，用5%的氟在约－16℃直接进行氟化制得。

The surface hydroxyl group onto magnetic polyvinyl acetate nanoparticles can be obtained by saponification reaction on their surface.

结果表明，磁性聚苯乙烯颗粒与丁二酸酐发生Freidel-Crafts酰基化反应，可以在颗粒表面引入少量羧基；磁性聚甲基丙烯酸甲酯颗粒分别与乙二醇、二缩三乙二醇、聚乙二醇等发生醇-酯交换反应，可以在颗粒表面接枝不同分子链长度的末端羟基；磁性聚醋酸乙烯酯颗粒经过醇解或皂化反应可以获得表面羟基；磁性聚丙烯酸甲酯颗粒通过乙二胺或1，6己二胺的胺解反应可以得到表面氨基，继而与一氯乙酸反应可以引入亚胺二乙酸基团。

It was found that the selective photoreductionreaction of this uranyl compound could take place under pulsed IR laser irradiation and the rate ofphotoreduction depended on the frequency, energy fluence and numbers of pulses of laser.

用TEA-CO_2激光研究了室温下固体的甲酸铀酰钠的红外光化学反应，发现该化合物在脉冲红外激光照射下可产生选择性的光化还原反应，其光化还原率与激光频率、能量密度和脉冲数有关。

The synthesis of fructone from ethyl acetoacetate and ethylene glycol using sulfonated activated carbon as solid acid catalyst was investigated.

以活性炭磺化制得新型固体磺酸磺化炭为催化剂，对乙酰乙酸乙酯和乙二醇合成苹果酯的催化工艺进行了系统研究。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。