酰化

The better reaction conditions are as follows: Reaction temperature is 40°C, Reaction time is 5 hour; the ratio of L - phenylalanine to acetic acid and N - formyl - L- aspartyl anhydrideis 1:10.2:1.1, Its yield is 95.4%.

在查阅文献的基础上，得到较优的α-L-天冬氨酰L-苯丙氨酸甲脂盐酸盐的合成方案，在甲醇一水体系中，N-甲酰-α-L-天冬氨酰-L-苯丙氨酸在浓盐酸的作用下60℃水解90分钟，后冷却到15℃加入浓盐酸在20～30℃保温反应96小时，进行甲脂化，形成甲脂盐酸盐，结晶析出。

LIN Hailin,CUI Yingde,DU Lin,CHEN JianpingInstitute of Applied Chemistry,Zhongkai University of Agriculture and TechnologySuper water absorbent resins P,SA/NaAA,SA/NaAA/PVA and SA/NaAA/AM were synthesized from sodium alginate,acrylic acid,polyvinyl alcoholand acrylamide,with N,N–methylenebisacrylamide as crosslinking agent,(NH4)2S2O8 - NaHSO3 as initiator,by means of aqueous solution polymerization.

以醚化海藻酸钠、聚乙烯醇、丙烯酰胺、丙烯酸为单体，N， N–亚甲基双丙烯酰胺为交联剂，过硫酸铵-亚硫酸氢钠为引发剂，采用水溶液法制备聚丙烯酸钠p吸水树脂和海藻酸钠/丙烯酸钠、海藻酸钠/丙烯酸钠/聚乙烯醇（SA/NaAA/PVA）及海藻酸钠/丙烯酸钠/丙烯酰胺吸水性复合树脂。

Results show that, by using thionyl chloride and N,N-dimethyl formamide as chlorinating reagent and dichloromethane as solvent and taking -15℃ as reaction temperature, Z-iomer crystals with pale white color and stable to temperature can be obtained with an overall yield of 70%.

以2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酸为原料，经盐酸化、氯代等反应合成了Z-2-（2-氨基噻唑－4-基）－2-甲氧亚氨基乙酰氯盐酸盐；氯代时以用亚硫酰氯和N，N-二甲基甲酰胺的混合物代替五氯化磷作氯化剂，并考察了温度和溶剂对氯代产物中Z-异构体和E-异构体收率的影响。

Result of thermogravity analysis showed that the thermal stability of polyvinylamine chloride lowers with increasing in amination degree. Moreover, properties of dilute aqueous solutions of three types of poly chloride with different amination degree were compared by use of viscosimetric, conductometric, and potentiometric measurements. Results showed that both the electrostatic interaction of neighboring groups on the chain and the reduced viscosity of poly chloride are increased with increasing the degree of amination of poly . The equivalent conductivity is decreased with the increasing the concentration of poly chloride and increased with the increasing the amination degree of poly .

研究了聚乙烯胺盐酸盐的热稳定性和水溶液性质，发现：随着胺化度的提高，聚乙烯胺盐酸盐的对热稳定性逐步降低；聚乙烯胺盐酸盐是一种典型的聚电解质，其水溶液的pH值随平均分子量的变化并不明显，而随着聚乙烯胺胺化度的升高，pH值降低；随着聚乙烯胺盐酸盐的平均聚合度由82.3增加到201.8，它的m值（用于表征聚电解质侧链基团之间相互作用大小的常数）从5.13升高到5.58，而当聚乙烯胺盐酸盐的平均聚合度增加到311.4时，它的m值反而降低到了5.48；随着胺化度由55.65%升高到82.36%，m值由3.65提高到5.50；随着聚乙烯胺盐酸盐的平均聚合度的提高，聚乙烯胺盐酸盐的平均解离常数由7.48降低到7.26，同时随着胺化度的提高，聚乙烯胺盐酸盐的平均解离常数也由8.33降低到7.37；随着聚乙烯胺盐酸盐浓度的提高，溶液的摩尔电导率逐步降低，随着聚乙烯胺胺化度和聚合度的提高，溶液的摩尔电导率有所升高；在pH值为4左右时，聚乙烯胺盐酸盐的比浓粘度分别达到极值，而与聚合度的大小关系不大；聚乙烯胺盐酸盐的特性粘数明显高于其原料聚丙烯酰胺的特性粘数，分子量对特性粘数的影响十分明显，胺化度对特性粘数的影响并不显著。

In this Ph. D. dissertation, reverse microemulsion method was fully used infabricating and modifying polyacrylamide with functional and high-relative moleculeweight. The copolymerization of 2-acrylamide-2-methylpxopanesulfonic acid, fluorescent monomer 4-methoxy-N-(2-N\', N\'-dimethylamino ethyl)naphthalimide alkyl chloride quaternary ammonium salt, fluorescentmonomer 4-(N\'-methyl-1-piperazinylallyl)-N-butyl-naphthalimide chloride quaternaryammonium salt, Cationic monomer dimethylethylammonium bromide and hydrophobical monomer octadecylacrylate with acrylamide and properties of the copolymers werestudied. The interaction between five polymers and Al_2O_3(012) crystal surface have beensimulated by Materials Studio 3.0 program package, binding energies and non-bondinteraction energies and deformation energies have also been acquired.

本文以制备具有较高相对分子质量和功能型PAM为研究目的，将反相微乳液法运用到其制备及改性的有关环节，通过反相微乳液聚合工艺，将几种改性功能单体2-丙烯酰胺基-2-甲基-丙磺酸、荧光单体2-(4-甲氧基-1，8-萘二甲酰亚胺基)-乙基二甲基烯丙基氯化铵、荧光单体4-(N'-甲基-1-哌嗪基)-N-丁基-1，8-萘烯丙氯季铵盐、阳离子单体丙烯酰氧乙基-二甲基-乙基溴化铵和疏水单体丙烯酸十八酯与AM共聚，制备AMPS改性PAM、荧光示踪型PAM、阳离子单体DMB改性PAM和OA改性PAM等四类不同功能单体改性PAM，并研究其应用性能。

The latices were stable ,thixotropic and monodisperse .The particle sizes range from 192 to 94 nm depending on the acrylamide fractions. The Hofmann reactions of these latices were carried out to introduce primary amines on the particle surface.

由于一直以来，丙烯酰胺-苯乙烯的共聚物胶乳只能用于制备两性胶乳，为了得到较高的胺化度，我们对不同单体配比的丙烯酰胺-苯乙烯共聚物胶乳进行Hofmann反应，探讨了丙烯酰胺在单体中所占的比例对Hofmann反应的影响。

The first committed step in fatty acid biosynthesis is the carboxylation of acetyl CoA to form malonyl CoA using CO2 in the form of bicarbonate HCO3-.

在脂肪酸的从头合成过程中，参入脂肪酸链的二碳单位的直接提供者并不是乙酰CoA，而是乙酰CoA的羧化产物——丙二酸单酰CoA(malonyl-CoA)。

The water-contact angle and swellibility of the complex membrane were also studied.The results indicated that the hydrophilicity of the composite membrane increased,and the quaternary ammonium made the membrane sensive with PH.

结果表明，磷酰胆碱改性超支化聚酯具有一定的抗凝血性，抗凝血性基本随着磷酰胆碱结构含量的增加而提高，与磷酰胆碱结构在复合膜中的绝对含量相比，羟基的转化率对血液相容性的影响更大。

A series of polys based on pyromellitic dianhydride, biphenylyl tetracarboxylic dianhydride, thiodiphthalic dianhydride bis benzene dianhydride and oxydiphthalic dianhydride were prepared in different solvents.

以所合成的AB_2单体为原料，合成了一系粘度较低、溶解性良好，带端酚羟基、苯甲酰基、乙酰基、氰代苯基和苯酰苯亚胺基的芳香族超支化聚酰亚胺，通过核磁波谱、红外光谱分析和元素分析对其结构进行确证。

Methods 4-Hydroxy- benzonitrile was treated with sodium hydrogen sulfide and anhydrous magnesium chloride in dimethyl formamide to give thioamide, which was then directly cyclized with ethyl 2-chloroacetoacetate without separation to give ethyl 2-(4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(2) in one-pot; then 2 was formylated with Duff reaction adopting hexamethylenetetramine in trifluoroacetic acid to give ethyl 2-(3-formyl-4-hydroxyphenyl)-4-methylthiazole-5-carboxylate(3); finally, the target compound was obtained by the treatment of 3 with hydroxylamine hydrochloride and sodium formate in formic acid.

采用&一勺烩&方法，以4-羟基苯甲腈为起始原料，首先与硫氢化钠和无水氯化镁在N，N-二甲基甲酰胺中反应，所得中间体不经分离，直接加入2-氯乙酰乙酸乙酯进行环合反应，得到2-(4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（2）；然后通过六亚甲基四胺/三氟乙酸进行Duff反应，得到2-(3-甲酰基-4-羟基)苯基-4-甲基-5-噻唑甲酸乙酯（3）；再经盐酸羟胺/甲酸/甲酸钠体系脱水得到目标化合物。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。