酰化

The effects of reaction temperature, phase transfer agent and the concentration of rhodium catalyst were examined.

研究了采用水溶性铑膦络合催化体系对双环戊二烯的氢甲酰化反应，考查了反应温度、相转移剂CTAB、铑催化剂浓度等对反应的影响。

The degradation kinetics, effect of irradiation on the degree of deacetylation of chitosan and the main chain scission mechanism have been studied.

用 γ射线照射壳聚糖使之发生辐射降解，研究了降解反应的动力学、辐射对壳聚糖脱乙酰化度的影响以及大分子链的断链机理。

It is noticed that this method is also fit for the phosphorylation of serine methyl ester with active hydroxy in side chain.

试验表明，对于侧链上有活性基团的丝氨酸甲酯的核苷磷酰化衍生物的合成，该方法同样适用。

Results After induction by VEGF or PDGF for 1 week,most of adherent mononuclear cells became round and small, while few grew into spindle-shaped cells.

结果新鲜脐血分离单个核细胞培养1周后贴壁细胞的EPCs特异的Dil标记乙酰化低密度脂蛋白鉴定为80％阳性。

In the study, N4 -acetyl-sulfamethazine(N4 -ACE-SM2) was synthesized, the determination method of sulfamethazine(SM2) and N4-ACE-SM2 in sturgeon muscle and water were developed, bioconcentration and depuration of SM2 in the sturgeon were completed at last.

本研究合成了磺胺二甲嘧啶(SM_2)的主要代谢产物N~4-乙酰化磺胺二甲嘧啶(N~4-ACE-SM_2)，并建立了SM_2和N~4-ACE-SM_2在鲟鱼肌肉和水中的检测方法，进一步利用流水式鱼类试验，对SM_2在鲟鱼体内的生物富集和生物清除进行了研究。

By azo compound became chromophore monomer disperse red -19, and through Sulfonyl of the compound was synthesized by the C, and through 1HNMR its structure was characterized, the results show that the synthesis of compounds C of very high purity, synthetic polymers can meet at the request of the monomer, but also of the compound D, through 1HNMR its characterization, showed that high purity compounds D, is expected to be functional after the adoption of To all the excellent performance PEEK electro-optic polymer materials.

本文通过偶氮化合成了生色团单体分散红-19，并通过磺酰化反应合成得到了化合物C，并通过核磁共振氢谱对其结构进行了表征，结果表明，所合成的化合物C的纯度非常高，完全能满足聚合物合成时对单体的要求，同时也合成了化合物D，通过核磁共振氢谱对其结构表征，显示化合物D纯度很高，应有望通过后功能化合成出各种性能优良的聚醚醚酮电光高分子材料。

By treatment with TMSOTf, peracetylated chitobiose,-triose, and -tetraose weretransformed into corresponding oxazolines.

全乙酰化的几丁二糖，三糖和四糖在TMSOTf处理下转变成相应的〓唑啉化合物。

The methodrapidly separates a large amount of different kinds of urushioldiacetates.Because the silver ion is very sensitive to theconfiguration and the degree of unsaturation of the unsaturated bonds,urushiol diacetate were well separated.

本文采用涂渍〓的离心旋转薄层层析法，发挥分离速度快，分离量大，固定相利用率高，分离效果好及〓对双键位置及构型作用灵敏等优点，因而使乙酰化漆酚达到了满意的分离。

Significant processing steps can include: a phase changes involving either the desired molecule or the solvent, inert carrier or vehicle, e.g., dissolution, crystallization, evaporation, sublimation, distillation or absorption; b a phase separation such as filtration or centrifugation; c any chemical change involving the desired molecule, e.g., removal or addition of water of hydration, acetylization, formation of the salt; d an adjustment of the solution containing the molecule such as adjustment of pH or pO2; e a precision measurement of contained or added BPC components, in-process solutions, recycled materials is performed, i.e., weighing, volumetric measuring, optical rotation, spectrophotometric determinations, etc.; and f changes occur in surface area, particle size, or lot uniformity, e.g., milling, agglomeration, blending.

意义较大的步骤可能会包括：a相变化，包括指定分子或溶剂，惰性载体或溶媒，如溶出作用，结晶，蒸发，升华，蒸馏或吸附；b相分离，如过滤或离心；c涉及指定分子的任一化学变化，如结晶水的除去或添加，乙酰化作用，成盐；d包含分子的溶解的调节，如调节pH或pO2；e 含有或添加原料药组分，过程内溶液，回收物料的精密测量，如，称重，体积测量，旋光度，分光光度测定，等和f 表面，粒度，或批一致性的变化，如磨碎，凝块，混合。

In this paper, the synthesis ways and applications of 4,5-dimethyl-l,3-dioxolen -2-one were introduced. An appropriate way synthesizing DMDO from acetoin via acylation, cyclization and dehydrochlorination was selected. The influences of various process conditions on the reaction were studied in detail, and the optimum process conditions were obtained by single factor experiments.

本文介绍了医药中间体4，5-二甲基-1，3-二氧杂环戊烯-2-酮的应用情况和合成路线，选择了适于工业化生产的工艺路线，即采用羟基丁酮为原料，经酰化、环合和脱氯化氢等步骤合成DMDO，并采用单因素试验法详细研究了各项工艺条件对反应结果的影响规律，确定了优化工艺条件。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。