酯化值

In this research,the indexes relating to the quality of the fried oil,including the content of the ploymers,acid value,iodine value,saponification value,peroxide value,the content of the diglyceride,oxidation stability,viscosity,were detected.The results showed that with the frying time prolonging,the content of the polymers and viscosity increased greatly,iodine value and saponification value decreased,peroxide value and acid value increased,and the content of unsaturated fatty acid reduced,a little of diglyceride produced.

在食用油煎炸过程中，对油脂品质相关的指标(包括酸值、碘值、皂化值、过氧化值、脂肪酸组成、氧化稳定性、黏度、聚合物的含量以及甘一酯、甘二酯和甘三酯的含量)进行检测，结果表明，随着煎炸时间的延长，煎炸油中的聚合物含量大大升高，黏度增大，有少量甘二酯生成，不饱和脂肪酸含量下降，碘值、皂化值降低，酸值、过氧化值升高。

The reaction time, reaction temperature and catalyst influencing on esterification were investigated, and the acid value, flashing point and other properties were determined.

考察了反应时间、反应温度、催化剂等反应条件对酯化反应的影响，并对增塑剂的酸值、闪点及其他主要性能指标进行了测定，改进了酯化反应工艺条件，讨论了样品色泽、酸值及闪点的影响因素。

The effects of reaction temperature, reaction time, catalyst dosage, addition of esterification agent and the ratio of monoglyceride to glycerol were examined.

分别考察了反应温度、反应时间、催化剂添加量、酯化剂添加量和单甘酯与甘油的比例对酸值的影响。

The invention relates to a preparation process for synthesizing polyethylene terephthalate 1, 3- terephthalate catalyst, which comprises adding titanic acid ester, germanium compounds and cobalt compound into liquid dispersed phase of organic solution, wherein the total weight concentration is 4-10%, and preparing the catalyst through mechanical stirring or ultrasonic wave mixed ligand for 10-60 minutes in 0-120 DEG C, wherein the adding content of titanic acid ester, germanium compounds and cobalt compound are respectively 200-500ppm, 50-300ppm and 100-400ppm of reaction monomer mass of terephthalic acid or dimethyl terephthalate.

本发明涉及一种合成聚对苯二甲酸1，3-丙二醇酯催化剂的制备方法，将钛酸酯、锗化合物和钴化合物加入到有机溶剂的液体分散相中，总重量浓度为4～10％，在0-120℃通过机械搅拌或超声波混配10-60min制得；钛酸酯、锗化合物和钴化合物加入量分别是对苯二甲酸或对苯二甲酸二甲酯反应单体质量的200-500ppm、50-300ppm、100-400ppm；用此催化剂制备PTT产品，酯化和缩聚反应时间相对于单独使用钛酸四丁酯缩短了30-60min，产品特性粘数0.70-1.05dL/g，色相b值在2-6之间，切片可用于加工新型合成纤维及工程塑料产品。

With the observation of the outward appearances, it can be known roughly that if the sample was added with adulterations. Since the beeswax dissolves in the benzene but the adulterations, such as gypsum, starch and so on do not, these can be determined. By the verification of acid value and alcohol dissolve ability, the acid or non acid added can be determined. By the change of saponification value, the ester or non ester added can be determined. By the carbonification degree in the concentrated sulphuric acid, the mineral wax, such as paraffin wax added can be determined.

通过样品外观的观察初步定性是否掺有杂质；利用纯蜂蜡在苯中溶解，而掺入的石膏、面粉和淀粉等杂质在苯中不溶而定量鉴定这类杂质；由酸值变化和乙醇溶解物的量，测定掺入的硬脂酸等酸性物质或其它的非酸性物质；由皂化值变化，定量测定掺入的动物脂等酯类物质或其它的非酯类物质；根据蜂蜡中的烃类在浓硫酸中可被炭化，加入的石蜡等矿物蜡不被炭化来测定此类掺杂物。

In this paper, di-isobutyl oxalate was prepared from oxalic acid and isobutyl alcohol using NaHSO_4 and p-toluenesulfonic acid as catalysts.

以草酸和异丁醇为原料，在酸性催化剂作用下进行酯化反应合成出一种新型柴油十六烷值改进剂——草酸二异丁酯。

The results show that the optimal parameters of esterification are as follows: 4% of SO42-/ZrO2, molar ratio of methanol to litsea cubeba kernel oil 101, 68 ℃ of reaction temperature and 4 h of reaction time, the acid value decreases to 2.52 mg/g. Compared with the traditional acidic-catalyzed method, this method has the advantages of no acid proof equipment, easy to recycle catalyst and no acidic waste water emission. The optimal parameters of transesterification are as follows: 25 ℃ of reaction temperature, 0.5% of hexadecyl-trimethyl-ammonium bromide, 1% of NaOH, molar ratio of methanol to the oil 61 and 15 min of reaction time. The ester exchanging rate is 97.6%. This method adopts phase transfer catalyst and produces industry prospect, which has many advantages such as energy-saving and time-saving under room temperature.

研究结果表明，固体酸SO42-/ZrO2催化酯化反应的最佳条件为：油重4%的SO42-/ZrO2，醇油摩尔比为101，温度为68 ℃，反应时间为4 h，原油酸值降到2.52 mg/g；该法相对浓硫酸催化酯化法具有不需耐酸设备、催化剂易回收、无废水排放等优点；相转移催化酯交换反应的最佳条件为：温度为 25 ℃，0.5%的十六烷基三甲基溴化铵，油重1%的NaOH，醇油摩尔比为61，反应15 min，原油酯交换率达到97.6%；采用相转移催化技术，反应在常温下进行，大大减少了能耗，缩短了反应时间，具有的产业化前景。

As to the high polarity, high boiling point resultant—trimesic acid, the analysis methods of infrared spetrum, gas chromatography-mass spectroscopy, vapour-phase chromatography, acid number titration and so on are seperately used to characterize its property. Infrared spetrum and gas chromatography-mass spectroscopy are used to have a qualitative analysis on the resultant and are compared with the stand diagram. Sulfuric acid-methanol esterification and rapid esterification are used to prepare the trimesic acid trimethyl-ester and have a FID quantitative analysis. So that we make sure the purity of trimesic acid in the resultant and also we have an acid alkali titration on the resultant to get its acid number, in order to verify the purity of trimesic acid in the resultant.

对于高极性、高沸点的固体产物均苯三甲酸，分别采用红外光谱、气质联用、气相色谱、酸值滴定等分析手段进行了表征：利用红外光谱、气质联用的方法进行产物的定性分析，并与在同一仪器、同一条件下做出的标准谱图进行比对；采用硫酸-甲醇酯化法和快速酯化法制备出均苯三甲酸三甲酯，对其进行气相色谱FID定量分析，进而确定固体产物中均苯三甲酸的纯度；用酸碱滴定法确定固体产物的酸值，以对固体产物中均苯三甲酸的纯度进行验证。

The production process of fatty acid methyl ester with high acid value acidulated oil and fatty acid replaced superior quality fat and oil by high temperature gas phase method and supplemental ester translation process was also introduced.

对间歇式酯化-酯交换工艺进行了具体分析，并着重介绍了采用高温气相法及补充酯交换工艺，以高酸值酸化油和脂肪酸代替高档油脂生产脂肪酸甲酯的生产工艺。

Under the optimal reaction conditions the acid value of the esterified production is the lowest,and the esterified degree is complete.

在最优条件下，鱼油的乙酯化产品酸值最低，乙酯化程度最高。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。