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Additionally, the quantum chemical study on the isomeriaation mechanism of the enol ester of 2-acyl-l,3-cyclohexanedione was performed, which was discovered by Yang when he synthesized the derivate of 2-acyl-l,3-cyclohexanedione.

第三部分工作是对杨定亚在合成2-酰基-1,3-环己二酮类化合物的衍生物时意外发现的烯酯异构化反应机理进行了研究。

In this article, different soft templates formed by sodium bis (2-ethylhexyl) sulf-osuccinate, nonyl phenol polyethyleneoxy ether (Oπ-10) and cetyltrimethyla- mmonium bromide were used to fabricate CaCO3, BaCO3 and CeO2/CuO nanoparticles with different morphology.

本文分别利用丁二酸二(2-乙基己基)酯磺酸钠、壬基-酚基-聚乙氧基醚(Op-10)和十六烷基三甲基溴化胺形成的不同软模板合成了具有不同形貌的CaCO3, BaCO3和CeO2/CuO纳米粒子。

It showed that the blend system had much slower Rp than that of hybrid monomer, either of acrylate double bond or propenyl ether double bond, and propenyl ether double bond conversion of hybrid monomer was much higher than that of the blend system at the end.

杂化单体与相同类型的混合体系相比,每种基团的反应动力学性质都得到了促进,丙烯酸酯和丙烯基醚双键的聚合速率都有了很大提高,丙烯基醚双键的转化率较混合体系有很大增加。

When SiO〓-NH〓-Rh-Co complex was used to catalyze the hydroformylation of methyl methacrylate, an optimal conversion of 93.4% and optimal selectivity of 84.4% for the normal aldehyde were both obtained at Rh/Co ratio of 2/1, which were both higher than that catalyzed by SiO〓-SiNH〓-Rh and SiO〓-Si-NH〓-Co momometallic catalysts. Clearly a synergistic action between Rh and Co atoms presented in the complex.

我们以SiO〓-Si-NH〓-Rh-Co催化甲基丙烯酸甲酯的醛化反应,当催化剂中Rh/Co比为2/1时,催化活性最高,可达93.4%,对正构产物β-甲酰异丁酸酯的选择性达到84.4%,都高于单金属催化剂,表明了金属间存在相互作用。

Glycerol triacetate was synthesized using several acidic functional ionic liquids as the catalysts.

将几种酸功能化离子液体应用于三醋酸甘油酯的合成反应中,筛选出了一种催化效果好又可以重复使用的离子液体[HSO3-pmim][HSO4]。

The influence of reed produced allelopathy material eathyl-2-methyl acetoacetate on respiration action, photosynthesis action and antioxidant enzymes system of Microcystis aeroginosa were studied.

研究了芦苇产生的化感物质2-甲基乙酰乙酸乙酯对铜绿微囊藻呼吸作用、光合作用和抗氧化酶体系的影响。

Quantum chemical and molecular mechanical methods were employed to study the acylation in the acetylthiocholine hydrolysis catalyzed by acetylcholinesterase.

应用量子化学和分子力学方法研究乙酰胆碱酯酶催化硫代乙酰胆碱水解反应中的乙酰化反应,计算了反应物、过渡态、产物及中间体的几何结构及电子结构。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物,通过2-氨基-5-(3-吡啶基)-1,3,4-噻二唑与酰基叠氮化物反应,设计合成了7个新的N-[5-(3-吡啶基)-1,3,4-噻二唑-2-基]-N'-取代苯基脲,其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

According to the determination of fatty acids, we established an HPLC method for the analysis of VPA in serum by RP-HPLC after transfered VPA into an ester which has chromophoric characteristics.

本文参照脂肪酸衍生化测定条件,建立了将丙戊酸转化为具有紫外吸收特征的酯,再经紫外检测的RP-HPLC测定方法。

The five major pathogenic fungi of three fruits rot diseases are : Dothiorella gregaria,Colletotrichum gloeosporioides,Trichothecium roseum,Macrophoma kawatsukai and Coniothyrium olivaceum. Ameng which Coniothyrium olivaceum is a new jujube pathgenic fungus.

从苹果、板栗、枣的病果上,分离到5 种病原真菌,其中Coniothyrium olivaceum 为枣果新病原-测定了6 种寄主上的Dothiorella gregaria 形态、酯酶同功酶及菌丝融合力,认为是一复合种,可区分为3 个专化型。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。