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Secondly,a mixture of acetone and methyl formate was added into the methanol solution of sodium methoxide to prepare sodium formyl acetone by Claisen reaction.

以金属钠为原料,甲醇为溶剂,先制成甲醇钠的饱和甲醇溶液,再滴加丙酮和甲酸甲酯进行Claisen酯缩合制得丁酮烯醇钠,最后在强酸作用下与甲醇进行缩醛化反应合成了4,4-二甲氧基-2-丁酮,过程总收率达到73.1%,纯度98.7%。

The synthesis of glyoxylic acid by ozonization of maleate was studied, the influence of technological parameter on the reaction during ozonization process were investigated.

对马来酸酯臭氧化合成乙醛酸的技术进行了研究,重点考察了臭氧化过程中的工艺参数对反应的影响。

In this thesis, three different chain length hybrid monomers, containing acrylate and propenyl ether group, was synthesized by three-step reaction through 1.3-propanediol, 1.4-butanediol, 1.6-hexanediol, allyl bromide and acryloyl chloride.

本文以1.3-丙二醇、1.4-丁二醇、1.6-己二醇、烯丙基溴及丙烯酰氯为主要原料,通过三步反应合成了三种不同链长的丙烯酸酯-丙烯基醚杂化单体。

2-Substituted-3,4-dihydro-1(2H)-isoquinolinones were synthesized from methyl 3-hydroxy-ben- zoates via allyl etherification, Claisen rearrangement, oxidation, reductive amination and aminolysis for the first time.

以3-羟基-4-甲氧基苯甲酸甲酯等为原料,通过烯丙基醚化、Claisen重排、氧化、与伯胺反应、还原、分子内酯的胺解六步反应合成了一系列2-取代-3,4-二氢-1-异喹啉酮类化合物。

A method for separation and determination of amino acids using pre column derivatization with 6 aminoquinoline N hydroxysuccinimido carbamate AccQ.

对Waters公司采用 6 氨基喹啉 N 羟基琥珀酰亚胺基氨基甲酸酯柱前衍生化测定氨基酸的方法进行了改进。

In Na2CO3-NaHCO3 buffer solution, the apparent activation energy and activation parameters for cetyl trimethylammonium bromide micelle-catalytic hydrolysis of p-nitrophenyl propionate have been measured, and the effects of inorganic salts (such as NaCl, NaBr and Na2SO4) on them have also been investigated.

在Na2CO3-NaHCO3缓冲溶液中,测定了对硝基苯酚丙酸酯的十六烷基三甲基溴化铵胶团催化反应的表观活化能和活化参数;考察了无机盐(NaCl, NaBr, Na2SO4)对该催化反应的影响。

In this dissertation, I will represent my studies on the nitration of Chalcone derivatives, reaction of epoxide ketone, and the aromatization of 3,5-disubstitued 2-isoxazolines with nitric oxide.

本文主要研究了:(1)NO与查尔酮及其衍生物的硝化反应,反应以较高的产率得到了a-硝基化合物;(2)NO对环氧酮的开环反应,反应生成了顺式羟基硝酸酯;(3)3,5-二取代的-2-异恶唑啉在NO作用下可以发生芳环化反应,生成了对应的2-异恶唑化合物。

Synthesis of isopropyl chloroacetate catalyzed by acidic ionic liquids was studied,including influences of different ionic liquids,reaction temperature,reaction time and quantity of ionic liquid.

研究了功能化酸性离子液体催化合成氯乙酸异丙酯的反应,考察了不同离子液体、反应温度、反应时间和离子液体与反应物物质的量比等对反应的影响。

The synthesis of ascorbyl laurate from methyl laurate and ascorbic acid was studied.

以月桂酸甲酯和维生素 C为原料,以固定化的脂肪酶为催化剂,合成了月桂酸维生素C酯。

In chapter 2, the Michael additions of functionalized organozinc iodides with α,β-unsaturated aldhydes, ketenones, esters and l-aryl-2-nitroetheneshave been investigated in the presence of Cu〓/ 2LiCl.

第二章主要研究了在低毒、稳定、易得、价廉的Cu〓存在下,带官能团的有机碘化锌与α,β-不饱和醛、酮、酯及1-硝基-2-芳基乙烯的Michael加成反应,并探讨了反应机理。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。