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Synthesis of methyl pentyl carbonate by transesterification of dimethyl carbonate and pentanol

首次用磷酸铝分子筛催化戊酸与正戊醇的酯化反应合成了戊酸正戊酯。

During these years (1997-2000) in the research area of annonaceous acetogenins 5 natural products and a number of chiral-pure analogs of annonaceous acetogenins have been synthesized using sugars as the starting materials. Their high activity and selectivity against cell line of colon tumor and a relationship between activity and configuration have been found too. In the respect of inhibitor of sialidase two new methodologies for the synthesis of chiral-pure 3-deoxy-ulosonic acid using hetero-Diels-Alder reaction or asymmetric propargylation as the key reaction were developed. On the topic of anti-leukemia marine natural product clavulactone a synthetic method based on the free radical cyclization and starting from sugar has been developed. In other title of PKC inhibited agent sphingosine a new synthetic route with SN2' as the key reaction has also been disclosed.

项目期间(1997-2000)在番荔枝内酯方面从糖出发合成了五个天然产物和一批手性纯的类似物,它们对肠癌细胞有很高的活性和选择性,并与构型有关;在唾液酸酶抑制剂方面发展了二类全新手性纯高碳糖的合成方法-杂原子D-A反应或丙炔基不对称加成为关键的反应;抗白血病海洋天然产物群柱虫内酯方面研究了由糖出发和自由基环化反应的合成方法;对PKC 起抑制作用的鞘氨醇方面也开创了新的合成途径-由糖出发并以SN2'反应为关键反应。

The technological conditions with methylacrylic acid and hexadecanol as raw-material and the synthesis of hexadecyl methylacrylate by direct-esterification are studied.

研究了以α-甲基丙烯酸和十六醇为原料采用直接酯化法合成α-甲基丙烯酸十六酯的工艺条件。

Liquor with uncooked materials is a kind of safe, hygeian and pure new technological liquor.

摘 要:回顾了生料糖化与发酵的研究历程,阐述了淀粉构造,生淀粉糖化机理,生料酒曲组分,生料酿酒和生料酒曲在大、小曲酒、黄酒生产方面的应用方法;以及与己酸菌、酯化酶共酵来提高酒质的技术措施;提出生料酒是一种安全卫生纯净的新工艺白酒。

The methods of synthesizing polyurethane (Toluene, 2, 4-diisocyanate TDI and Isophorone diisocyanate IPDI) with paper were investigated.

研究了甲苯-2,4二异氰酸酯,异佛尔酮二异氰酸酯对纸张聚氨酯化处理的方法及反应机理。

It is reviewed that sulfamic acid can be utilized as a green catalyst in many important organic reactions such as esterification and transesterification,group protection,imino-Diels-Alder,rearrangement,substitution and condensation.

综述了近年来氨基磺酸作为一种绿色催化剂在有机合成中的应用,主要包括酯化与酯交换、基团保护、氮杂Diels-Alder、重排、取代及缩合等反应。

0 H; reaction temperature: 140~ 150°C ; molar ratio of p toluene sulphonic acid to salicylic acid, 1∶11, with no water carrying reagent; yield: about 98%.

应用对甲苯磺酸作为水杨酸和 2 -乙基己醇的酯化催化剂,成功合成了水杨酸- 2 -乙基己酯。

The thermal stability and corrosion behaviour of petroleum acid ester and esterified high acid crude oil were studied.

研究了石油酸酯和酯化高酸原油的热稳定性及腐蚀性规律。

Preparation of starch succinate with low substitution degree was studied by using corn starch as raw material,succinic anhydride as esterifying reagent,water as solvent and sodium hydroxide as catalyst.

以玉米淀粉为原料,丁二酸酐为酯化剂,以水为媒介,氢氧化钠为催化剂对低取代度淀粉丁二酸酯的制备工艺进行了研究。

Then the aluminium sulfates were prepared by sulfation and salt formation, and their IR spectra were analyzed.

在此基础上再经硫酸酯化和成盐修饰制备了各自的硫酸酯碱式铝盐。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。