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In this paper, the catalytical esterification of palmitic acid with 1 hexadecanol by lipase immobilized by microemulsion base organo gel that consisted of bis (2 ethylhexyl)sodium sulphsuccinate/heptane/water/gelatin in apolar organic solvent was studied.

研究了以AOT二(2 乙基已基琥珀酸酯磺酸钠/正庚烷/水/明胶组成的反相微乳凝胶固定化脂肪酶,在有机溶剂中催化棕榈酸和十六醇的酯化反应。

For developing an immunoassay for multiple residues of pyrethroid pesticides, the hapten N-2- carbanmoyl-(3"-phenoxyphenyl) methyl 3-(2"-Cldoro-3",3",3"-trifluoropropenyl)-2, 2-dimethylcyclopropane- carboxylate was synthesized from cyanohydrin and 3-(2"-Chloro-3",3",3- trifluoropropenyl)-2, 2-dimethylcyclopropanecarboxylic acid via hydrolysis and esterification. The synthesis of the hapten was foundation of preparaing anti- cyhalothrin polyclonal antibodies.

为了制备对单一拟除虫菊酯高特异性的抗体,以菊酸和氰醇为起始原料,通过水解、酯化反应合成了半抗原N-2-氨甲酰-(3-苯氧基苄基)甲基-3-(2-氯-3,3,3-三氟丙烯基)-2,2-二甲基环丙烷羧酸酯,为进一步制备抗三氟氰菊酯的特异性抗体奠定基础。

The determination of the components in transesterification of sucrose octaacetate with ethyl oleate by HPLC was studied.

研究了高效液相色谱分析法在油酸乙酯与蔗糖八乙酸酯转酯化反应中组分定量分析上的应用。

The invention relates to a process for producing polyethylene terephthalate 1, 3-propanediol, which comprises the following steps: using titanic acid ester as major catalyst, using germanium compounds and cobalt compounds as synergic catalyst, conducting esterification reaction for poly terephthalic acid and 1, 3-propanediol according to the molar 1:1.05-2.2 under the nitrogen pressure of 0.1-0.4MPa and 230-265 DEG C, or conducting ester exchanging reaction for poly terephthalic acid and 1, 3-propanediol according to the molar ratio 1:1.8-2.2 in 160-220 DEG C, decompressing reaction to high vacuum 10-150Pa, wherein the final temperature of reaction is 265-275 DEG C, recovering to normal pressure with nitrogen to obtain the PTT product.

本发明涉及一种生产聚对苯二甲酸1,3-丙二醇酯的方法,采用以钛酸酯为主催化剂,锗化合物和钴化合物为协同催化剂,对苯二甲酸二甲酯和1,3-丙二醇按摩尔1∶1.05-2.2,在0.1-0.4MPa氮气压力和230-265℃下进行酯化反应,或对苯二甲酸二甲酯和1,3-丙二醇按摩尔比1∶1.8-2.2,在160-220℃进行酯交换反应,将反应减压至高真空10-150Pa,反应终温在265-275℃,用氮气恢复到常压,得到本PTT产品;大大缩短了反应时间,直接聚合制备特性粘度在0.7-1.05dL/g的PTT切片,使反应产物色相良好,PTT产品可用于纤维加工及工程塑料领域。

In this paper, the applications of the environmental friendly solid acid catalysts for esterification were studied and the activities of these catalysts were discussed, by which the solid acid ferric sulfate x-hydrate was used first as catalyst in the synthesis of dimethyl fumarate and ethyl chloroacetate and solid super acid SO42-/Fe2O3 was used first as catalyst in the synthesis of ethyl p-nitrobenzoate.

本文研究了对环境友好的固体酸催化剂在酯化反应中的应用,首次以固体酸Fe_2(SO_4)_3·xH_2O为催化剂合成了新型防霉剂富马酸二甲酯和化工原料氯乙酸乙酯,以固体超强酸5O_4~(2-)/Fe_2O_3为催化剂合成了医药中间体对硝基苯甲酸乙酯,并探讨了这些催化剂的催化活性。

A novel type of amphiphilic tri-block copolymers with both pH and temperature sensitiveness: poly-poly (dimethylamino ethyl methacrylate)-poly (ε-caprolactone)(PEG-PDMAEMA-PCL) was synthesized via sequential oxyanionic polymerization of macro-molecular: PEG, with a hydroxyl at one end, and dimethylamino ethyl methacrylate andε-caprolactone, with the potassium naphthalene as the initiator.

在本文中,报道了一类新型的兼具pH和温度敏感的双亲性嵌段共聚物:聚乙二醇-聚甲基丙烯酸N,N-二甲氨基乙酯-聚己内酯(PEG-PDMAEMA-PCL)及聚甲基丙烯酸N,N-二甲氨基乙酯-聚己内酯(PDMAEMA-PCL)的制备;并利用动态光散射和氢核磁共振光谱(~1H NMR)对该嵌段共聚物的水溶液性质进行研究;在此研究结果的基础上,初步探讨了其在仿生物矿化中的应用。

Methyl α-naphthaleneacetate was synthesized by using α-naphthaleneacetic acid and methanol as raw materials and solid superacid TiO2/SO42- as a catalyst.

以固体超强酸TiO2/SO42-为催化剂,研究了α-萘乙酸与甲醇的酯化反应,探讨了催化剂种类、用量及活化温度等反应条件,发现固体超强酸TiO2/SO42-对α-萘乙酸与甲醇的酯化反应具有较高的催化活性,并使后处理简化。

In this thesis, the method of the synthesis of the common intermediate compoundof this style has been further studied. It is confirmed a procedure for esterifying the alanine.

本论文对该类化合物的常用中间体(1)的合成方法进行了改进性试验,避免了使用苄酯或叔丁基酯进行丙氨酸酯化,减少了反应的复杂性,简化了后处理方法。

The research on fluorinated polyurethane-acrylate emulsions were reviewed in this article,including the aspects of categories,structure characteristics,synthesis methods and properties.

介绍了目前国内外氟化聚氨酯-丙烯酸酯乳液的研究现状,综述了已见报道的氟化聚氨酯-丙烯酸酯乳液的种类、结构特点、合成工艺以及性能,并指出了国内相应领域研究的不足和今后研发的重点和方向。

The synthesized high ester valuePVSK was characterized and compared with high ester value PVSK sample from Japanese company.

用红外光谱法对合成的高酯化度PVSK进行了表征,并与日本生产的高酯化度PVSK进行了比较。

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According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm~150rpm时取得最大值,此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世,形体几无变化。

When I was in school, the rabbi explained everythingin the Bible two different ways.

当我上学的时候,老师解释《圣经》用两种不同的方法。