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It is the first time to report that C8-acetyl is displaced by long chain fatty acyl for triester-aconitines in the ester-exchange reactions.

型乌头生物碱的C位乙酰基被各种长链脂肪酰基取代的交换反应为首次报道。

Ployster acrylated acylate 7O.

丙烯酸 48.85 树 7O.O

Orthogonal test was performed to examine the influences of reaction conditions on microwave-assisted synthesis of 2'-oxo-cyclopentanecarboxylic acid ethyl ester from diethyl adipate.

以己二酸二乙为原料,在微波辐射下经Dieckmann缩合反应合成2'-羰环戊基甲酸乙

Sucrose vinyl adipoyl ester was synthesized from sucrose and divinyl adipate in organic solvents using an immobilized alkaline proleather.

用固定化蛋白酶FG-F在有机溶剂中催化蔗糖和己二酸二乙烯合成了蔗糖己二酸单乙烯

1,6-Dimethyl adipate with selectivity of 100% was synthesized by batch and continuous esterification process using adipic acid and methanol as raw materials,DNW-I strong-acid cation exchange resin as catalyst.

摘 要:以DNW-I型强酸型正离子交换树脂为催化剂,己二酸和甲醇为原料,经间歇化和连续化反应后通过精馏可制备选择性为100%的1,6-己二酸二甲

A series of polyurethane anionomers were synthesized from isophorone diisocyanate, polyneopentanediol adipate and dimethanol propionic acid.

用异佛尔酮二异氰酸、聚己二酸新戊二醇和二羟甲基丙酸合成了负离子型聚氨离聚体。

We investigated constituent of triterpenoid saponins ofAlbizzia, two new compounds together with two known compounds were isolated from Albizzia julibrissin Durazz. by using column chromatography (macroreticular resin, silica gel, Sephadex gel, reverse phase silica gel),preparative HPLC methods et al.On the basis of spectroscopic analysis, including IR,ESI-MS,~1H-NMR,~(13)C-NMR,HMBC,HMQC,~1H-~1HCOSY and chemical methods, the structure of two new compounds were identified as 3 - O -[β-D-xylopyranosyl(1→2)-β-D-fucopyranosyl (1→6)-β- D -2- deoxy - 2 - acetoamidoglucopyranosyl] -21-O-[(6S)-2- trans- 2,6-dimethyl - 6 - O-β- D - quinovopyranosyl -2,7- octadienoyl] - acacic acid- 28 - O-β-D-glucopyranosyl(1→3)[α-L-arabinofuranosyl(1→4)]-α-L-rhamnopyranosyl(1→2)-β-D-glucopyranoside acacic acid 3- O -β- D- glucopyranosy(1→3)-β- D- fucopyranosl(1→6) [β-D- xylopyranosyl (1→2)]-β-D-glucopyranoside ;two known compounds were acacic acid lactone 3- O -β-D- xylopyranosyl-(1→2)-β-D-fucopyranosl (1→6)- 2-deoxy -2 -acetoamido -β-D- glucopyranoside ; acacic acid lactone 3- O-β-D-xylopyranosyl(1→2)-α-L- arabinopyranosl (1→6)- 2- deoxy - 2- acetoamido -β-D-glucopyranoside . The study lays chemical foundation and chemical reference substance for enhancing quality standard of Albizzia julibrissin Durazz.

本研究论文在综述国内外对合欢属Albizzia三萜皂苷化学成分和药理作用研究进展的基础上,利用传统植化分离手段和现代分离技术,包括大孔树脂、硅胶、葡聚糖凝胶、反相硅胶等柱色谱,制备高效液相色谱法等技术从中药合欢皮中分离得到了4个化合物,其中,2个新化合物和2个己知化合物,并进一步通过现代分析技术IR,ESI-MS,~1H-NMR,~(13C-NMR,HMBC,HMQC,~1H-~1HCOSY等和化学方法鉴定了2个新化合物的结构分别是:3-O-[β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖基]-21-O-[(6S)-2-反式-2,6-二甲基-6-O-β-D-吡喃鸡纳糖基-2,7-辛二烯酸基]-金合欢酸-28-O-α-L-呋喃阿拉伯糖基(1→4)[β-D-吡喃葡萄糖基(1→3)]-α-L-吡喃鼠李糖基(1→2)-β-D-吡喃葡萄糖苷,金合欢酸3-O-β-D-吡喃葡萄糖基(1→3)-β-D-吡喃夫糖基(1→6)[β-D-吡喃木糖基(1→2)]-β-D-吡喃葡萄糖苷;2个已知化合物结构分别是:金和欢酸内3-O-β-D-吡喃木糖基(1→2)-β-D-吡喃夫糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷,金和欢酸内3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃阿拉伯糖基(1→6)-β-D-2-去氧-2-乙酰氨基吡喃葡萄糖苷。

The processing technique of synthesis and purification of medium-chain triglycerides by alcoholysis, using camphor tree seed oil as material, was investigated by orthogonal analysis, and the optimum condition of the processing technique and performance parameter of product were obtained.

以樟树籽仁油为原料,通过正交实验法研究了用醇解法合成和纯化中碳链甘三的生产工艺,得到了中碳链甘三生产工艺的最佳条件及产品的物性参数。

First esterification solution is prepared by alcoholysis PET. Then the feeding method, esterification and condensation temperature, catalytic-stable system and so on are adjusted.

化母液以醇解聚方法制备,然后通过对加料方式、化和缩聚温度、催化稳定体系等生产运行参数的调整,生产出质量良好的共聚切片。

The key technology of "fattyacid-oil process" in production of alkyd resin is the alcoholysis of oils. The alcoholysis of fattyacid-oil is the result of esterification of fatty acid and alloholysis of oils, of which the medium effect of esterified product of fatty acid and polyols will promote the alcoholysis of oils with polyols.

制造醇酸树脂的"脂肪酸-油法"的技术关键依然是油脂的醇解,整个脂肪酸-油脂体系的醇解是脂肪酸化与油脂醇解并行反应的结果,其中,脂肪酸与多元醇的化产物的介质效应有力地促进了油脂与多元醇的醇解反应。

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