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Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethyl malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effective base.

在这类催化反应中,碱的选择具有重要的影响:以K3PO4为碱, Pd2/L1催化体系在丙二酸二乙的α-芳基化中,富电子溴代芳烃显示较好的活性; Pd2/L1催化的乙酰乙酸乙α-芳基化时,以 K2CO3为碱,催化体系显示较好的活性,这个催化体系可控制反应得到α-芳基乙酰乙酸乙,而不是脱乙酰基的产物。

Base played a crucial role in this reaction: in the Pd2/L1 catalyzed α-arylation of ethy malonate, K3PO4 is the base of choice; in the α-arylation of ethyl acetoacetate, K2CO3 is the most effectiv base.

在这类催化反应中,碱的选择具有重要的影响:以K3PO4为碱,Pd2/L1催化体系在丙二酸二乙的α-芳基化中,富电子溴代芳烃显示较好的活性;Pd2/L1催化的乙酰乙酸乙α-芳基化时,以K2CO3为碱,催化体系显示较好的活性,这个催化体系可控制反应得到α-芳基乙酰乙酸乙,而不是脱乙酰基的产物。

Through the analysis of energy and exergy,the bottleneck of the traditional process for ester acetates ' production is revealed.

通过传统液相化法醋酸生产工艺过程的能量分析和火用分析,指出醋酸生产工艺高能耗、高物耗的瓶颈,挖掘过程节能降耗的潜力。

According to the results of the former study in our laboratory, trans-1, 2-cyclohexanediol is produced with a lot of acids and water, for extraction of trans-1, 2-cyclohexanediol from the solution, ethyl acetate and butyl acetate were used as extraction reagents, the solubility data of the trans-1, 2-cyclohexanediol in corresponding mixed solvents of some sorts of acetates and water are needed.

根据本实验室前期研究结果可知,反式-1,2-环己二醇是在酸性和大量水存在的条件下得到的,为了把反式-1,2-环己二醇从反应液中萃取出来,本工艺所采用的萃取剂是乙酸乙和乙酸丁,需要获得反式-1,2-环己二醇在这些类与水混合溶剂中的溶解度数据,因而对反式-1,2-环己二醇进行相关固液相平衡的研究是非常迫切和必要的。

The premary tests show that three of them can obviously improve the mechanical properties of soft PVC/L-CaCO3 materials;however, they almost heve no effect on PP/L-CaCO3 blends. This suggests that the coupling effect of the aluminates be not only re...

初步试验表明,有3种铝酸可明显提高软质PVC/L-CaCO_3共混物的力学性能,但4种铝酸对PP/L-CaCO_3共混物的力学性能均无改善,说明铝酸的偶联作用不但与它们的分子结构有关,而且和偶联的对象有关。

In gabexate group 30 patients(M 11, F 19; age 56 a±13 a) received 100 mg gabexate in 5% glucose in 0.9% sodium chloride injection 500 mL, iv drip, q 8 h for 3 d and 100 mg.d-1 after then. The patients of the 2 groups stopped the therapy when all the symptoms had disappeared and the amylases in blood and urine had turned to be normal.

加贝组在常规疗法基础上加用加贝[常州金远药业制造有限公司,每支100 mg,批准文号(92)卫试字X-41号]100 mg加入5%葡萄糖氯化钠注射液500 mL中静脉滴注,q 8 h, 3 d后加贝改为100 mg静脉滴注qd,至临床症状消失,血、尿淀粉酶正常后停药。

Cellulose acetate butyrate,which is widely applied as coatings additive, is synthesized in the heterogeneous system. The activation is required because of the strong hydrogen intramolecular and intermolecular bondings and the regulation of the crystalline region in cellulose microfibrils.

中文摘要纤维素醋酸丁酸(Cellulose acetate butyrate是一种广泛应用于涂料工业的添加剂,由于纤维素具有分子内与分子间强氢键作用以及纤维素纤维的局部规整的结晶序列等特征,一般纤维素在化反应前都需要进行预活化处理,工业上纤维素醋酸丁酸的合成方法一般都在非均相体系中进行的。

A series of PVC membrane electrodes with nicotine containing different plasticizeres such as octyl phthalate, nonyl phthalate and di octyl dicaproate, and electric active substances such as association of nicotine-tetraphenyl borane, nicotine-silicotungstic acid, nicotine-phospho-wolframic acid and nicotine-Reineckate ammonium were prepared.

以尼古丁为研究对象,研制了一系列含有不同增塑剂(苯二甲酸二辛、苯二甲酸二壬和癸二酸二辛)和电活性物质(尼古丁四苯硼缔合物、尼古丁硅钨酸缔合物、尼古丁磷钨酸缔合物和尼古丁雷氏盐缔合物)的PVC膜电极。

The main contents and conclusions are as follows:(1) Synthesis of 1,6-hexamethylenedicarbamate catalyzed by yttrium nitrate Yttrium nitrate was employed as the catalyst in the synthesis of 1,6-hexamethylenedicarbamate from alkyl carbamates.

主要内容和结论如下:(1)硝酸钇为催化剂合成1,6-己二氨基甲酸采用硝酸钇作为小分子氨基甲酸烷基和1,6-己二胺合成1,6-己二氨基甲酸的催化剂。

Synthesis of N-substituted carbametes catalyzed by ionic liquids Ionic liquids were introduced into the syntheses of N-substituted carbamates from alkyl carbamates and amines.

离子液体为催化剂合成N-取代氨基甲酸将离子液体引入到小分子氨基甲酸烷基和有机胺合成N-取代氨基甲酸反应。

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