酮酰亚胺

Part 2. Annulation reaction of 3, 4-dichlorocoumarin (1) and 3, 4-dichloromaleimide (8) by a new general annulation strategy developed in this group with 2-phenylbenzofuran (15), 3-phenylbenzofuran (16), 2, 5-diphenyloxazole (17), 2, 5-diphenylthiazole (18), 2-methyl-4-phenylthiazole (19) and 2, 3-dimethoxy-1, 3-butadiene (40) were investigated.

二。在本课题组前一阶段提出的从二氯代环烯酮与1，1-二芳基乙烯的光化反应以及光化反应中得到的环丁烷产物的连续电环化反应对3，4-二氯马来酰亚胺以及3，4-二氯香豆素进行增环反应的工作基础上，研究了3，4-二氯香豆素（1）和3，4-二氯马来酰亚胺（8）与5个α-苯基取代的环烯烃2-苯基苯并呋喃（15），3-苯基苯并呋喃（16），2，5-二苯基噁唑（17），2，5-二苯基噻唑（18），2-甲基-4-苯基噻唑（19），以及一个丁二烯——2，3-二甲氧基丁二烯（40）进行的芳香族增环反应。

They are 4-(2- hydroxy-3-butynlenoxy) benzoic acid (1, WA), 5-chloro-7, 8-dihydroxy-7-methyl- 6-oxo-3- [ -3, 4-dihydroxy-3, 5-dimethyl-l-heptylene] -1H-8, 8a-dihydrobenzo [2, 3-c] pyran (2, WB),-2-(2-methyl-2-dibutene diamido)-2-butenoic acid (3, B5262), 3, 4-dihydro-9, 10-dihydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3- c] pyran-1-one (4, A73 semi-Vioxanthin), 8, 8'-bis (6, 9-dioxo-3,4-dihydro-10- hydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3-c] pyran-1-one)(5, A122 Xanthomegnin), 2, 5-dioxo-3a-hydroxymethyl-3, 3a, 6, 6a-tetrahydro-furo [2, 3-b] furan (6, 1003-2), 7-acety1-5-chloro-6, 8-dioxo-7-methyl-3- [ -3, 5-dimethyl-1, 3- diheptylene] -4aH-benzo [2, 3-c] pyran (7, M2-2 sclerotiorin), respectively.

它们分别被命名为4-（2-羟基-3-丁炔氧基）苯甲酸（1，WA）、5-氯-7，8-二羟基-7-甲基-6-氧代-3-[-3，4-二羟基-3，5-二甲基-1-庚烯基]-1H-8，8a-二氢苯并[2，3-c]吡喃（2，WB）、-2-（2-甲基-2-丁烯二酰亚胺基）-2-丁烯酸（3，B5262）、3，4-氢-9，10-二羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮（semi-Vioxanthin，4，A73）、8，8'-双（6，9-二氧代-3，4-二氢-10-羟基-7-甲氧基-3-甲基-1H-萘并［2，3-c］吡喃-1-酮）（Xanthomegnin，5，A122）、2，5-二氧代-3a-羟甲基-3，3a，6，6a-四氢-呋喃并［2，3-b］呋喃（6，1003-2），7-乙酰基-5-氯-6，8-二氧代-7-甲基-3-［-3，5-二甲基-1，3-庚二烯基］-4aH-苯并2，3-c］吡喃（Sclerotiorin，7，M2-2）。

The catalytic system composed of NHPI and transition metal ion can catalyze effectively ethane into acetic acid,cyclane into dicarboxylic acid,toluene into benzoic acid,alkene into epoxide,alkyne into acetylenic ketone,and amide into imide;NHPI used alone can catalyze adamantane to be carbonylated,hydrogen peroxide prepared by oxidization alcohol;NHPI combined with as...

NHPI与过渡金属离子组成的催化体系能高效地催化乙烷氧化为乙酸、环烷烃氧化为二元羧酸、甲苯氧化为苯甲酸、烯烃氧化为环氧化物、炔烃氧化为炔酮、酰胺氧化为酰亚胺；NHPI单独使用能催化金刚烷发生氧化羰基化反应、催化氧化醇制取过氧化氢；NHPI与有机助催化剂如偶氮二异丁腈、溴化季铵盐、蒽醌和醇等也能催化分子氧氧化反应。

Phthalimide,anthranilic acid,2methyleneglutaronitrile bromina 1bromobutane 1,2benzisothiazole3one.

邻苯二甲酰亚胺，邻氨基苯甲酸，2亚甲基戊二脯，2溴2溴甲基戊二脯，溴代正丁烷，1.2苯并异噻唑3酮。

The major contents in this thesis are described as follows:(1) Seven new thiol fluorescence reagents containing 2-phenylbenzoxazole (or 2-phenylbenzothiazole) derivatives or benzanthrone as fluorphore and iodinacetylamine or maleimide as reaction groups have been synthesized.

本论文的研究工作主要分为以下几个方面：(1)以碘乙酰胺或马来酰亚胺为反应基团和以2-芳基苯并噁唑类化合物或苯并蒽酮为荧光团，首次合成了七种新的碘乙酰胺类和马来酰亚胺类巯基荧光试剂。

Study on an efficient process for the preparation of trifloxystrobin starting from 2-methylacetophenone bypartial oxidation,esterification,reaction with methoxyamine,bromization and condensation with 3'- acetophenone oxime.

以邻甲基苯乙酮为原料，经过高锰酸钾的碱性氧化，甲醇酯化，再与甲氧基胺盐酸盐肟化后，用N-溴丁二酰亚胺溴化，最后和间三氟甲基苯乙酮肟缩合得到目标产物肟菌酯。

Therefore, this paper selected the direct oxidation route to synthesize α-isophorone, and according to the principles of green chemistry, oxygen was used as the oxidant, with non-metal N-hydroxy-phthalimide as catalyst, for preparation of Isophorone.

因此本论文的研究选用以α-异佛尔酮直接氧化的路线，且根据绿色化学的原则，以氧气为氧化剂，用一种无金属参与的N–羟基邻苯二甲酰亚胺为催化剂催化α-异佛尔酮，为氧代异佛尔酮的制备提供一条全新的途径。

Huapai products:pchlorophenol,ochlorophenol,2,4dichlorophenol,2,6dichlorophenol,2,4,5trichlorophenol,2,4,6trichlorophenol,4chloro2benzyl phenol,pbromophenol,2,4,6tribromophenol,1chloro4(1,1dimethyl ethyl) benzene ether,3bromoanisole,mbromofluorobenzene,2tetra hydrofuran,αbromo4chloro acetophenone,αbromo4methoxy acetophenone,4chloro benzophenone,4chloro2methylaniline,n(2hydroxyethyl)ethane diamine; n(2aminoethyl)ethanolamine,2,3dibromopropionyl chloride,4bromo benzene sulphonyl chloride,terephthaloyl chloride,isophthaloyl chloride,nchlorosuccinimide,nbromosuccinimide,pchloranil;tetrachloro1,4benzoquinone,5chloroisatin.

华派公司产品：对氯苯酚，邻氯苯酚，2，4二氯苯酚，2，6二氯苯酚，2，4，5三氯苯酚，2，4，6三氯苯酚，4氯2苄基苯酚，对溴苯酚，2，4，6三溴苯酚，对氯苯基叔丁基醚，间溴苯甲醚，间溴氟苯，α溴甲基四氢呋喃，α溴代4氯苯乙酮，α溴4甲氧基苯乙酮，4氯二苯甲酮，4氯2甲基苯胺，N(2羟乙基)乙二胺， 2，3二溴丙酰氯，对溴苯磺酰氯，对苯二甲酰氯，间苯二甲酰氯，N氯代丁二酰亚胺，N溴代丁二酰亚胺，四氯苯醌，5氯靛红。

In this contribution novel acid-base sulfonated poly(phthalazinone ether nitrile ketone)s membranes are introduced.The membranes are composed of SPPENKs as the acidic compounds,and polyetherimide as the basic compounds,furthermore,redissolving SPPENKs and PEI in N-methylpyrrolidone then cast directly onto clean glass substrates in dust free environment at 60℃ aiming at enhancing membrane toughness and other relative properties.

以合成的一系列不同磺化度的碘化聚芳醚腈酮为acidic聚合物，以聚芳醚酰亚胺为basic聚合物，并将其溶解在 N -甲基-2-吡咯烷酮中配成质量分数为10%的成膜液，60℃下刮制成膜，制得acid-base型磺化聚芳醚腈酮质子导电了聚合物膜。

In this thesis, the design, synthesis and application of substituted 1,8-naphthalimides and napthopyrones conjugated with uridine, substituted 1,3,5-triazine, 1,2-dibromoethane, ethyl bromoacetate have been studied.

本论文研究了取代l，8-萘酰亚胺和萘并吡喃酮与尿苷、取代均三嗪、二溴乙烷、溴乙酸乙酯偶合和双l，8-萘酰亚胺之间偶合的设计、合成及应用。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了