酮缩醇

Catalytic activity of phosphotungstic acid on synthesizing butanone 1,2-propanediol ketal was discussed,the factors influencing the synthesis were discussed and the best conditions were found out.

探讨了磷钨酸对丁酮1，2 丙二醇缩酮合成反应的催化活性，研究了酮醇摩尔比、催化剂用量、反应时间等因素对产品收率的影响。

In this paper,the ketalization of cyclohexanone and ethylene glycol catalyzed by dealuminated USY was studied.

研究了脱铝超稳Y沸石催化环己酮与乙二醇的缩酮化反应，考察了催化剂硅铝比、催化剂用量、反应物配比、带水剂和反应时间等对缩酮化反应的影响。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

Catalytic synthesis of ketal by urushiol-formaldehyde neodymium polymer from cyclohexanone and ethanediol was studied.

以环己酮和乙二醇为原料，漆酚缩甲醛钕聚合物为催化剂合成了环己酮乙二醇缩酮。

H3PW6Mo6O40/TiO2 was used as the catalyst in the synthesis of cyclohexanone ethylene ketal. The effects of varying the n:n ratio, catalyst dosage and reaction time on the yield were investigated.

以H3PW6Mo6O40/TiO2为催化剂，对以环己酮与乙二醇为原料合成环己酮乙二醇缩酮的反应条件进行了研究，较系统地研究了酮醇物质的量比、催化剂用量、反应时间对收率的影响。

The optimum conditions are: molar ratio of glycol to cyclohexanone is 1.6:1, the quantity of catalyst is equal to 0.25% of feed stocks, and the reaction time is 40 mm. H3PW12O40/MCM-48 is an excellent catalyst for synthesizing cyclohexanone ethylene ketal and its yield can reach over 80.63%.

实验表明：H3PW12O40/MCM-48是合成环己酮乙二醇缩酮的良好催化剂，在n：n＝1：1.6，催化剂用量为反应物料总质量的0.25%，环己烷为带水剂，反应时间40min的优化条件下，环己酮乙二醇缩酮的收率可达80.63%。

Under these conditions, the yield of cyclohexanone glycol ketal could be reach 90.4%, indicating that rare earth composite solid superacid SO4(superscript 2-)/ZrO2(superscript 3+) is a good catalyst for the synthesis of cyclohexanone glycol ketal.

在此条件下，缩酮收率可达90.4%，说明稀土复合固体超强酸SO4(上标 2-)/ZrO2/Gd(上标 3+)是一种合成环己酮乙二醇缩酮的优良催化剂。

Cyclohexanone ethylene ketal was synthesized from cyclohexanone and glycol in the presence of H3PW12O40/MCM-48. The factors influencing the synthesis of molar ratio of glycol to cyclohexanone, the quantity of catalyst and the reaction time were discussed and the best conditions were found out.

报道了以分子筛MCM-48负载磷钨酸(H3PW12O40/MCM-48)为催化剂，通过环己酮和乙二醇反应合成了环己嗣乙二醇缩酮，探讨了H3PW12O40/MCM-48对缩峒反应的催化活性，较系统地研究了酗醇物质的量比，催化剂用量，反应时间诸因素对产品收率的影响。

Condensation of cyclohexanone and pentaerythritol catalyzed by iodine supported on activated carbon was investigated.

为了研究活性炭负载单质碘催化合成季戊四醇双缩酮催化活性，以季戊四醇和环己酮为原料，合成环己酮季戊四醇双缩酮。

Sythesis and application of chlorostyrene-DVB strongly acidic cation exchange resin ;2. For this study,a series of poly( p -amino styrenes) with various amounts of supported hydrogen chloride,and a series of strongly acidic cation exchange resin s with various exchange capacity were synthesized,and their catalytic property for ketalization of cyclohexanone and glycol were investigated.

通过测定固载了不同量的氯化氢的聚和不同交换量的强酸性阳离子交换树脂催化的环己酮与乙二醇的缩酮化反应缩酮的收率，研究了聚合物固体酸催化剂的疏水性对其催化缩酮化反应性能的影响；发现在一定范围内增加催化剂的疏水性，可提高缩酮化反应的收率。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。