酮缩醇

The quantity of catalyst was equal to 0.6% of feedstocks,the reaction temperature was 78～110 ℃,and the reaction time was 45 min. The test results have shown that H_4SiW_(12-O_(40)/MCM-48 is an excellent catalyst for synthesizing butanone 1,2-propanediol ketal with its yield reaching over 91.9%.

实验表明：H4SiW12O40/MCM-48是合成丁酮-1，2-丙二醇缩酮的良好催化剂，在n∶n(1，2-丙二醇)=1∶1.6，催化剂用量为反应物料总质量的0.6%，环己烷为带水剂，反应时间45 min的优化条件下，丁酮-1，2-丙二醇缩酮的收率可达91.9%。

Secondly,a mixture of acetone and methyl formate was added into the methanol solution of sodium methoxide to prepare sodium formyl acetone by Claisen reaction.

以金属钠为原料，甲醇为溶剂，先制成甲醇钠的饱和甲醇溶液，再滴加丙酮和甲酸甲酯进行Claisen酯缩合制得丁酮烯醇钠，最后在强酸作用下与甲醇进行缩醛化反应合成了4，4-二甲氧基-2-丁酮，过程总收率达到73.1%，纯度98.7%。

The acid property of zirconium oxychloride was characterized by means of DTA and FT-IR spectra of pyridine absorbed on the surface.

采用DTA和吸附吡啶的FT-IR表征氯氧化锆的表面酸性，用Hamm ett指示剂测定其酸强度，以催化合成环己酮2，3-丁二醇缩酮为探针反应优化缩酮反应条件，并考察它对其他缩酮反应的催化活性，比较了不同催化剂对缩酮活性的影响。

We also found for the first time that the reaction between ketone and alcohol to ketal was catalyzed by benzamide and their derivatives, and the related mechanism is proposed. Furthermore, under the same irradiation condition, the photo-reaction of succimide with alcohol as well as the photolysis of benzene sulfonamide was also found and studied.

并首次发现在紫外光激发下，苯甲酰胺对酮和醇生成缩酮的反应有一定的催化作用，进而对一系列芳酰胺类化合物作了对比实验，发现芳酰胺类化合物均能对缩酮的生成有催化作用，并对芳酰胺的作用机理进行了初步探讨。

Master the Keto-Enol tautomerism; reactions of enols:α-H substitution reactions;α-halogenation of aldehydes and ketones;α-bromination of carboxylic acids; acidity ofα-H atoms: enolate ion formation; reactivity of enolate ions; alkylation of enolate ions; mechanism of carbonyl condensation reactions;condensations of aldehydes and ketones: the Aldol reaction; dehydration of Aldol products; the Claisen condensation reaction; the Michael addition.

熟练掌握酮式－烯醇式互变异构；烯醇的反应：α-H的活性；醛酮的α卤代反应；羧酸的α-溴代反应；α-H的酸性：烯醇负离子的形成；烯醇负离子的反应；烯醇负离子的烃基化；羰基化合物的缩合反应机理；醛酮的缩合反应－Aldol缩合；Aldol缩合产物的脱水反应； Cleisen 酯缩合反应；麦克尔加成反应。

The ketalization of cyclohexanone and 1,4-butanediol catalyzed by the Hβ zeolite was studied.Effects of reaction time,mole ratio of reactants and amount of catalyst on the yield of ketal were studied.Results showed that the Hβ zeolite was an efficient catalyst for the synthesis of ketal.

研究了Hβ分子筛催化1，4-丁二醇与环己酮的缩合生成新型七元环缩酮的反应，考察了反应时间、酮与醇的配比、催化剂用量、催化剂重复使用等因素对醛与醇缩合反应的影响。

The quantity of catalyst was equal to 0.6% of feedstocks,the reaction temperature was 78～110 ℃,and the reaction time was 45 min. The test results have shown thatH_4SiW_(12-O_(40)/MCM-48 is an excellent catalyst for synthesizing butanone 1,2-propanediol ketal with its yield reaching over 91.9%.

实验表明：H4SiW12O40/MCM-48是合成丁酮-1，2-丙二醇缩酮的良好催化剂，在n∶n(1，2-丙二醇)=1∶1.6，催化剂用量为反应物料总质量的0.6%，环己烷为带水剂，反应时间45 min的优化条件下，丁酮-1，2-丙二醇缩酮的收率可达91.9%。

The results showed that the suitable condition for the reaction are as follows: benzaldehyde/1, 2-propylene molar ratio is 1:1.4, the mount of potassium dodecatungstocobaltate trihydrate (K5CoW12O403H2O) is 0.5g, the volume of cyclohexane is 9 mL, and reaction time is 70 min.

实验结果表明，杂多化合物K5CoW12O403H2O是合成环己酮l， 2-丙二醇缩酮的良好催化剂，在酮醇物质的量比为l：1.4、催化剂质量为0.5g、带水剂环己烷体积为9mL、反应时间为70min的最佳条件下，环己酮l， 2-丙二醇缩酮的收率最高可达94.2%。

In this work,the non\|aqueous carbonyl nickel slips were prepared by ball\|milling using Cyclohexanone\|butyl alcohol,Glycerol trioleate,Poly\|vinyl\|butyl and polyethylene glycol as the solvent,dispersant,binder and plasticizer,respectively.

本文以环己酮丁醇为溶剂，三油酸甘油酯为分散剂，以聚乙烯醇缩丁醛为粘结剂，聚乙烯乙二醇为增塑剂，通过球磨工艺制备了非水基羰基镍粉浆料。

The o-aminobenzaldehyde ethylene acetals can be synthesized from corresponding o-nitrobenzaldehyde by reducing the nitro-group after the protection of carbonyl by ethylene. 2-Aminophenyl ketone ethylene ketal can also be prepared from 2-nitrophenyl ketones by this method.

邻氨基苯甲醛乙二醇缩醛可以由含不同取代基的邻硝基苯甲醛经羰基以乙二醇缩醛保护后还原硝基得到，邻氨基芳香酮乙二醇缩酮可以同样的方法由邻硝基芳香酮得到。

Lugalbanda was a god and shepherd king of Uruk where he was worshipped for over a thousand years.

Lugalbanda 是神和被崇拜了一千年多 Uruk古埃及喜克索王朝国王。

I am coming just now,' and went on perfuming himself with Hunut, then he came and sat.

我来只是现在，'歼灭战perfuming自己与胡努特，那麼，他来到和SAT 。