酮基化作用

As well as activity was exhibited. Theaddition of cinchonidine led to a remarkable increase in the reaction rate, as confirmed bythe IR study that the modifier activates the carbonyl groups of the reactant through itsquinuclidine nitrogen. On the contrary,〓 exerted a strong inhibition effect on theenantioselective hydrogenation. Chapter 3 Finely dispersed polyvinylpyrrolidone-stabilized iridium andbimetallic clusters were prepared by the alcohol-water reduction method.

第三章 采用醇水还原的方法制备了聚乙烯基吡咯烷酮稳定的铱纳米簇及双金属纳米簇，对丙酮酸甲酯的催化氢化表明，在铱金属簇催化体系中，辛可尼定不仅诱导了一定的对映选择性，同时对反应活性有明显的促进作用，平均反应速率可提高2-6倍。

Secondly,a mixture of acetone and methyl formate was added into the methanol solution of sodium methoxide to prepare sodium formyl acetone by Claisen reaction.

以金属钠为原料，甲醇为溶剂，先制成甲醇钠的饱和甲醇溶液，再滴加丙酮和甲酸甲酯进行Claisen酯缩合制得丁酮烯醇钠，最后在强酸作用下与甲醇进行缩醛化反应合成了4，4-二甲氧基-2-丁酮，过程总收率达到73.1%，纯度98.7%。

In the end, a Novel and facile method has been used to synthesize functionalized cyclopentadienes by Nazarov cyclization ofα-alkenoyl ketene dithioacetals under Vilsmeier conditions.

从合成的α-烯酰基二硫缩烯酮类化合物出发，经过Vilsmeier试剂作用下的Nazarov环合反应，合成了官能化环戊二烯类化合物。

Aegle marmelos ; Anti-lipid peroxidation ; 4-Methoxy-1-methyl-2-quinolone; Superoxide dismutase; Catalase ; GSH-peroxi

木桔；抗脂质过氧化作用； 4－甲氧基－1－甲基－2－喹诺酮；超氧化物岐化酶；过氧化氢酶；谷胱甘肽过氧化物酶

In this dissertation, I will represent my studies on the nitration of Chalcone derivatives, reaction of epoxide ketone, and the aromatization of 3,5-disubstitued 2-isoxazolines with nitric oxide.

本文主要研究了：(1)NO与查尔酮及其衍生物的硝化反应，反应以较高的产率得到了a-硝基化合物；(2)NO对环氧酮的开环反应，反应生成了顺式羟基硝酸酯；(3)3，5-二取代的-2-异恶唑啉在NO作用下可以发生芳环化反应，生成了对应的2-异恶唑化合物。

Experimental study indicated: the flavone of rhizome drynaria can improve the cytoactive of marrow stroma cell of rats, promote its multiplicative division, and protect the marrow stroma cells' apotosis with lipidsion.The flavone of rhizome drynaria's serum can extently protect the osteoblast apoptosis of rats induced by TNF-α and the osteoblast senescence of rats induced by t-BHP.

实验研究表明：骨碎补总黄酮能够提高大鼠骨髓基质细胞的活性，促进其增殖分裂，并对脂质化大鼠骨髓基质细胞凋亡具有保护作用，而且骨碎补总黄酮含药血清对TNF-α诱导的大鼠成骨细胞凋亡和t-BHP诱导的大鼠成骨细胞衰老均具有一定的保护作用。

Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.

硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1，2-氧硼杂环戊烷与〓反应，再经PCC氧化，分子内缩合得到二氢茉莉酮。1，2-氧硼杂环戊烷的C-B键除氧化断裂之外，也能够在〓或KF作用下卤化断裂成碳卤键。

Some useful fluorine-containing intermedi-ates were synthesized by the reaction of activated methylenecompounds or silyl enol ether with 2,2-dihydropolyfluoro-alkanoates or 2-hydropolyfluoroalk-2-enoates in the presenceof different bases.

进一步研究表明，在氢化钠的作用下，苯乙腈，苄基苯基甲酮也可以与2-氢多氟-2-烯酸乙酯发生亲核加成反应，苄基苯基甲酮的加成中间体经多聚磷酸环化，得到了间位氟烷基取代的α-萘酚衍生物。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。