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Generally speaking, the reaction types involvingα-oxoketene--acetals mainly include the regioselective addition-aromatization with organometallic reagents, conjugate addition-cyclization with nitrogen nucleophilicspecies, nucleophilic reactions ofα-carbon, acting as odorless dithiol equivalentsin thioacetalization, Michael additions and [5+1] annulation, as well as the synthetic applications based on the above reactions.

一般来说,基于α-羰基二硫缩烯酮化学的反应主要为:与金属有机试剂的选择性加成反应,与氮亲核体的共轭加成反应,α-碳原子的亲核性及相关反应,烷硫基作为硫醇的替代试剂的应用,α-羰基二硫缩烯酮在碳环、杂环化合物合成中的应用等。

Antiphase evaporation transonic method and high speed agitation method was adopt to prepare semustine PVP magnetic liposome.

加入聚乙烯吡咯烷酮作为磁性粒子包裹剂制备水基磁流体,采用反相蒸发超声法加高速搅拌制备司莫司汀聚乙烯吡咯烷酮磁性脂质体。

These two oils each contain limonene and carvone, but each oil contains a different isomer of these chiral compounds.

这两种精油各自都含有柠檬烯和香芹酮,但每种精油都是由具有不同手性的柠檬烯和香芹酮的异构体所组成的,在这个实验课中,学生会接触到真空蒸馏操作。

Six 3,6-dichloropyridazine-derivatized cinchona alkaloid catalysts were synthesized and applied in IFB reaction.

二氢奎宁二聚体2c最差(56%ee),与环己二酮相比,环戊二酮作为反应原料时,产物的ee值降低。

A novel β-diketone ligand 3-methyl-phenyl-4-octadecyl-5-pyrazolone and nanoparticle Al2O3 modified by the ligand PMOP were synthesized and characterized by infrared spectroscopy, UV-Vis spectroscopy, 1H NMR and photoluminescence spectroscopy.

合成了以β-二酮配体3-甲基-1-苯基-4-吡唑啉酮-5修饰的Al2O3纳米粒子,并用IR、UV光谱、NMR和荧光光谱等手段进行了表征。

Androstenedione and dehydroepiandrosterone as a new steroid material attracts people's attention because of the shortage of diosgenin resource and successful synthesis of AD by degradation of sterols. The followings were included in this thesis: 1. 24 new oxime-ether and oxime-ester compounds from AD were synthesized by cleavage of A-ring through NaIO_4/KMnO_4 oxidation, ring closure by amination, oximation with hydroxylaminechloride in C-17 position.

甾体药物的合成原料一般为薯蓣皂素、剑麻皂素、番麻皂素等,随着薯蓣资源日渐枯竭,使得甾体药物工业不得不寻求新的原料,而微生物降解胆固醇和植物甾醇合成雄烯二酮获得成功,使得AD成为新兴的甾体原料吸引了人们的注意。

Methods N-vinyl pyrrolidone, the hydrophilic monomer, was grafted onto the surface of silicone breast implants by 60Co radiation.The implants were buried in the bilateral subcutaneous layers of the back of rabbits.The unchanged implants were used as the control group.

利用钴60共辐射的方法把亲水性单体 N-乙烯基吡咯烷酮接枝到硅胶乳房假体表面,改变其表面特性后植入兔的背部,以未经改性的正常假体作为对照组,隔一定时间通过组织切片及CT扫描的方法观察假体周围纤维囊壁的形成情况。

L acted as tridentate ligand to chelate with metal atom in enol and ketone form respectively; In complex anion Co atom reside in tetrahedral coordination environment.

钴原子位于八面体配位环境中,配体L分别以烯醇式和酮式充当三齿配体与金属原子配位,配阴离子中Co原子位于四面体配位环境中。

The reactions involved in the co-curing are: cyclodimerization and cyclotrimerization of cyanates, polyetherfication of epoxy groups and cyclotrimerization of cyclic dimers, as well as the formation of oxazolidinone rings.

反应历程首先是氰酸酯发生自聚反应形成二聚体或三聚体,然后二聚体可进一步共聚形成三嗪环,此过程伴随着环氧基的聚醚反应,最后是三嗪环与剩余的环氧基反应形成NFDA1唑烷酮。

A crude hormone of the corpus luteum from which progesterone can be isolated in pure form.

黄体酮卵巢的原始黄体荷尔蒙,其中黄体荷尔蒙以纯净的形态被隔离。

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On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面,更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值,分为几个相等的区间作为横轴,并将各区间内所测定值依所出现的次数累积而成的面积,用柱子排起来的图形,也叫做柱状图。

You rap, you know we are not so good at rapping, huh?

你唱吧,你也知道我们并不那么擅长说唱,对吧?