酮体

Further investigation will potentially provide the practical technologies for the diagnosis of human acrosome reaction deficiency

孕酮具有促进人精子受透明带诱导顶体反应的作用；小鼠透明带溶解液具有诱导人精子产生顶体反应的效果并确定了mZPS诱导人精子顶体反应的量效关系，为建立人顶体反应缺陷症的实用诊断技术提供基础。

The fluorescence properties of complexes of europium with β-diketone and terbium with benzoic acid and its derivatives were analyzed and the synergic effect of the second ligand was illustrated from the energy matching of the minimum triplet state of ligands and the resonance energy level of rare earth ions.

提出了掺杂离子荧光增强效应的机理。 4。首次采用ab initio CIS方法，在劈裂价层基组3—21G水平上对各配体进行了量化计算，系统分析了前线分子轨道特征和激发态的能级，从配体最低激发三重态能级与稀土离子共振能级的能级匹配，分析了铕与β-二酮的配合物的荧光性能和铽与苯甲酸系列衍生物的配合物的荧光性能，解释了第二配体的协同效应。

These results show that the dual fluorescence of 4-AHBO (5-AHBO) is produced by its different tautomers, hut not by the same isomer: the long wavelength emission is from the keto tautomer, and the short wavelength band is produced by four kinds of enol isomers.

结果表明，4-AHBO(5-AHBO)的双荧光不是由同一种异构体发射的，而是来源于不同异构体的发射：长波区的荧光由酮式构型发射，短波区的发射则可能由四种醇式异构体共同产生。

The dynamic changes of physiological and biochemical indexes of healthy spikes and inoculation ones of the resistant mutants indicated that PAL activity and content and changing tendency of total phenolate and flavoniods and MDA in the healthy spikes of the mutants were similar to that of their susceptible donors, whereas, for the inoculated spikes, content and changing range of these indexes existed significant difference between two kinds of strains, changing from high-resistant variety (Sumai3 ) to their susceptible donors.

以典型抗扩展品种和突变体供体亲本为抗、感对照，对抗赤霉突变体的健康穗及接种穗的生理生化特性研究结果显示，在健康穗中，抗性突变体的PAL活性、总酚、类黄酮及MDA含量及变化趋势与其感病亲本相一致，但在病原菌侵染后，这些生理生化物质的含量与变化程度与其亲本有了明显的差异，其变化范围介于典型高抗品种和感病亲本之间，变化趋势与亲本或抗性品种一致。

The integrated analytical results show that the novel ligand coexists in ketoform and enolform structures under the measuring conditions, the ketoform structure may change into the enolform structure during the coordination and bonds with the central ion by two O atoms of the enolized hydroxyl group of pyrazolone ring and H2O and the N atom of the imine group and the N atom containing H of benzimidazole ring by losing the proton. And the coordination number of these complexes is four.

综合各种分析结果显示：配体在测试条件下以酮式和烯醇式结构共存，配位时酮式可能转化为烯醇式结构，按去质子的方式以吡唑啉酮环羟基和H2O上的两个O原子以及亚胺基上的N原子和苯并咪唑环上的含氢N原子与中心离子成键，配合物的配位数为4。

The excited-state intramolecular proton transfer tautomerism reaction of 6-methyl-4-hydroxy pyri-midine monomers and dimmers was investigated by the ab initio method with the self-consistent reaction field with Tomas's polarized continuum mode and CIS theories at HF level on the basis of 6-311+G* and 6-31G basis set. By studying the potential energy surface, it was found that the monomer's ground-state proton transfer process together with the excited-state proton transfer process is a molecular system of four energy level, but dimmers were not, which can be used to explain the fact that UV-visible absorption and fluorescence spectra of monomer and dimers all corresponded to quinoid.

采用 ab initio HF理论的组态相关CIS方法和连续溶剂模型PCM，分别在6-311+G*和6-31G水平上研究了6-甲基-4-羟基嘧啶单体及二聚体激发态质子转移的异构化反应；对其反应势能面的研究发现，单体基态和激发态的异构化反应一起可以形成四能级的分子电子体系，而二聚体的却不能，由此解释了单体和二聚体的紫外吸收光谱和荧光发射光谱均对应于酮式构型的原因。

Under the conditions of acidity and dehydration, the abnormal Beckmann rearrangement usually occurs in α-electrofugally substituted cyclic ketoximes and gives a ring opened alkene-nitrile compound.

一。非正常Beckmann重排反应在甾体-17-酮肟中的应用对甾体18-甲基修饰是制备生物学重要的18-去甲基甾体的有效方法之一。

Part 7 is the conclusion of this paper.The main research in this paper includes:1 The 22 mixed ligand complexes were synthesized in which bipyridine-, phenanthroline 5-nitrophenanthroline , phenanthroline- 5,6-dikentone and biquinoline are the first ligand and chlorine ion phenylalanine, tyosine asparagic radical 2.6-diaminocaproic radical tryptophan , histidine malonate(mal2-) benzyl malonate (bmal2-) phenethtyl malonate (pmal2-) are the second ligand.

本文具体研究内容包括四部分：一、合成了以联吡啶、邻菲啰啉、5—硝基邻菲啰啉、邻菲啰啉-5，6-二酮、联喹啉为第一配体，以Cl~-、苯丙氨酸根、酪氨酸根、天冬氨酸根asp~(2-、赖氨酸根、色氨酸根、组氨酸根、丙二酸根mal~(2-、苄基丙二酸根bmal~(2-和苯乙基丙二酸根pmal~(2-为第二配体的共22个混配配合物，制备了其中6个混配配合物和1个单配体配合物单晶，用X-射线单晶衍射法测定了晶体结构。

Keywords hypophosphorous acid;thiol isomer thione isomers;enantiomer;proton transfer;isomerization reaction

单硫代次膦酸；硫酮式异构体；硫醇式异构体；对映异构体；质子转移异构化

Determination of Tyrosine in Urine Spectrophotometric Method;2. For chemical pre-extraction, MSTFA/TMSL derivatization reaction, GC/MS analysis, it is confirmed that two main metabolites (19-no-randrosterone and 19-noretiocholanolone) were found in nandrolone urine.

本文对合成的19-去甲雄烷醇酮的四个差向异构体混合物进行气相色谱分离，对诺龙和炔诺酮用药后，留取的人尿样通过化学预处理，MSTFA/TMSI衍生化反应，GC/MS分析，确证了尿样中诺龙的两个主要代谢产物为19-去甲雄酮和19-去甲原胆烷醇酮，炔诺酮的两个主要代谢物是四氢炔诺酮的两个形式，可能是3α-OH-5α-THINE和3α-OH-5β-THINE，在炔诺酮代谢前期，还发现有诺龙的上述两个代谢物存在。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。