酚类

Amount of auxochrome phenolic hydroxyl(0.29 unit/C9)in lignin from H_2O_2 bleaching chemi-mechanical pulp is slightly higher than one of material(0.28 unit/C9), so amount of auxochrome phenolic hydroxyl can not be effectively decreased by alkaline peroxide bleaching process.

麦草化学机械浆纸浆经过碱性H_2O_2漂白，木质素中酚羟基含量(0.29个/C9)略高于原料中的酚羟基含量(0.28个/C9)，说明H_2O_2漂白不能有效地减少木质素中酚羟基这类助色基团的数量。

The result showed that, the effect of the synergistic reaction of alkyl-phenol-polyoxythylene ether phosphate dispersant TERSPERSE 4896, nonyl phenyl polyoxyethylene ether dispersant TERSPERSE 2210 and XG to suspension was different. Both the rheological curves were same presented as pseudoplastic fluid when they stored in R. T (18~25℃) for 10 days, but the rheological curve of suspension with the synergistic reaction of TERSPERSE 2210 and XG was changed to dilatant fluid when it stored in R.

结果表明，烷基酚聚氧乙烯磷酸酯类分散剂TERSPERSE 4896、壬基酚聚氧乙烯醚类分散剂TERSPERSE 2210与增粘剂黄原胶协同使用所得悬浮体系，室温(18~25℃)贮存10d仍表现出二者共同的流变特性，呈假塑性的流变曲线；但室温贮存150d后，含TERSPERSE 2210与黄原胶的悬浮体系的流变性质发生了明显变化，由假塑性流体向膨胀型流体转变。

They have close relationship as the former may provide new ideas and approaches for the later, while the later may be the simulation for the former and gives it helps in degradation products identification and mechanism explanation. It is necessary to choose a suitable system, which has high potential of treating EDs and close relationship to the natural environment, to combine the researches in the two aspects. Our group has been engaged in researches on the photochemical properties and application to water pollution control of different ferric species including Fe -OH complexes, Fe -polycarboxylate complexes, Ferric oxides and Fe -humic acid complexes. Fe -oxalate complexes system has higher efficiency than the other ferric species systems in photooxidation and degradation of organic compounds. This thesis is focused on the photodegradation of nine EDs estradiol (E2), estrone (E1), 17α-ethynyl estradiol (EE2), diethylstilbestrol , bisphenol-A , 4-Nonylphenol , 4-Octylphenol , di-n-butyl phthalate , and di (2-ethylhexyl) phthalate .

因此从处理效率和环境化学意义两方面考虑，结合本课题组在不同铁形态（包括Fe-OH配合物、Fe-多羧酸配合物、Fe氧化物、Fe-腐殖酸配合物等）的光化学特性及其在水污染控制中的应用方面较系统的研究工作基础，本论文选择了四类共9种典型的内分泌干扰物（雌二醇（E2）、雌酮（E1）、17α-乙炔基雌二醇（EE2）己雌酚、双酚A、壬基酚、辛基酚、酞酸二丁酯和酞酸二乙基己基酯），研究了它们在Fe-草酸盐配合物体系中的光降解效果，推测其降解机理，探索环境内分泌干扰物光氧化处理的新体系，同时为预测其在环境中的光降解行为提供了依据。

The recoveries of the five compounds were between 95％ and 105％. CONGLUSION:This method is simple and effective, and can be used to determine phenolic acids from leaf of Ilex purprea Hassk.

首次建立了同时测定四季青中5种酚酸类成分的含量测定方法，可以用于同时测定四季青中的5种酚酸类成分的含量。

The pigment in colored cotton fibers was extracted by methanol at room temperature. The results of color reactions HCl-Mg reaction, NaBH4 reaction, NaOH reaction, FeCl3 reaction and Pb(Ac2 reaction of the pigment extractive showed that the pigment extracted by methanol was flavone or flavonol with two adjacent hydroxide groups (Table 2, Fig. 1). The results of UV spectral analysis further proved that the pigment extracted by methanol from brown fiber belonged to flavone with two adjacent hydroxide groups in B ring, and that from the green fiber contained not only flavone but also flavonols with two adjacent hydroxide groups both in A ring and B ring and indican replaced a hydroxide group at 3-site of A ring Fig.

通过盐酸－镁粉反应、四氢硼钠还原反应、碱反应、醋酸铅反应、氯化铁反应和紫外光谱吸收的分析表明，甲醇室温提取的棕色棉纤维色素可能是黄酮类化合物，B环上带有邻二酚羟基；甲醇室温提取的绿色棉纤维色素除黄酮类化合物外，还含有3-位羟基被糖甙化的黄酮醇类化合物，A、B环上都带有邻二酚羟基。

By using high performance liquid chromatographycombined withthin-layer chromatography,three PG:salicin,salicortin and deltoidin weredetected in the bark of P.deltioides,Five kinds of PG were detected in the leaves,which included trmuloidin and tremulacin besides the three PG.

采用薄层色谱与高效液相色谱法相结合的方法，在实验材料的树皮中测定到三种主要的酚甙类物质：水杨甙、柳皮甙和美洲黑杨甙，在叶片中测定到5种酚甙类物质，除上述3种物质外，还包括2′-苯甲酰水杨甙和颤杨甙，对于后两者在前人的研究中未见报道。研究还对5种化学物质进行了分离。

The addition of puerarin, tea polyphenol and acid compositions in VECO effectively improved the effects on soberness, intoxication avoiding, ataxia correcting and memory barrier eliminating. The tea polyphenol has superior behavior on soberness, intoxication avoiding and memory barrier eliminating than that of puerarin, while puerarin is more effective in the function of ataxia correcting than tea polyphenol.

金葛露中加入葛根素、茶多酚和酸类物质有助于解酒、防醉、纠正运动失调和改善记忆障碍，其中茶多酚的解酒、防醉和改善记忆障碍的效果比葛根素明显，葛根素纠正运动失调作用的效果比茶多酚明显。

To further study the chemical constitutes of lipophilic active parts, we prepared Alc95% and Alc50% according to original literature. 20 compounds were isolated by using macroporous resin, silica gel, polyamide, Sephadex LH-20, Rp-18, preparative TLC and preparative HPLC chromato-graphy. The structures of them were elucidated by means of physical and chemical properties, modern spectroscopic analysis techniques—UV、IR、 EI/MS、ESI/MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC. They are nine anthraquinones: chrysophanol (95-1), physcion (95-2), emodin (95-5), aloemodin (95-7), rhein (50-1), sennoside A or B (50-6),ω-hydroxylemodin (95-10), chrysophanol-8-0-β-D-glucoside (95-12), aloemodin-ω-0-β-D-glucoside (95-13); three phenanthaquinones: tanshinone ⅡA (95-3), cryptotanshinone (95-6), tanshinone Ⅰ(95-4); one isoflavone: 7, 3'-dihydroxyl-5' methoxyisoflavone (95-14) and protocaechuic aldehyde (95-9), protocaechuic acid (95-11), astragaloside Ⅳ(50-4), amygdalin (50-5), 2, 3, 5, 4'-tetrahydroxylstilbene-2-0-β-D-glucoside (50-3),-catechin (50-2), cinnamic acid (95-8). Among them, 3'-dihydroxyl-5' methoxyisoflavone (95-14) is a new compound.

经过溶剂萃取、大孔吸附树脂富集、Sephadex LH-20精制、制备TLC及Semi-pre HPLC等手段从中分离了20个化合物，利用理化性质和波谱技术(UV、IR、EI／MS、ESI／MS、〓H-NMR、〓C-NMR、DEPT、HMQC、HMBC)相结合鉴定了它们的结构，分别为9种蒽醌类化合物：大黄酚，大黄素甲醚，大黄素，芦荟大黄素，大黄酸，番泻苷A或B，ω-羟基大黄素(ω-hydroxylemodin)，大黄酚-8-0-β-D-葡萄糖苷(chrysophanol-8-0-β-D-glucoside)，芦荟大黄素-ω-0-β-D-葡萄糖苷(aloemodin-ω-0-β-D-glucoside)；3种菲醌类化合物：丹参酮ⅡA(tanshinoneⅡA)，隐丹参酮，丹参酮Ⅰ(tanshinone Ⅰ)；1种异黄酮：7，3'-二羟基-5'-甲氧基异黄酮（7，3'-dihydroxy-5' methoxyisofla-vone）以及原儿茶醛，原儿茶酸，黄芪甲苷(astragaloside Ⅳ)，苦杏仁苷，2，3，5，4'-四羟基二苯乙烯-2-0-β-D-葡萄糖苷（2，3，5，4'-tetrahydroxylstilbene-2-O-β-D-g1ucoside），Z—儿茶素，桂皮酸。

A series of novel polys: poly, poly and their copolymer poly were synthesized at high temperature by nucleophilic polycondensation of bisphenol 4 (3 phenyl 4 hydroxyphenyl) 2,3 phthalazin 1 one with activated difluorodiphenylketone, dichlorodiphenylsulfone and both together.

将苯基取代类双酚化合物 4-(3 -苯基-4-羟基苯基)-2 ，3 -二氮杂萘-1 -酮与活性双卤单体如 4，4 -二氟二苯酮、4，4 -二氯二苯砜进行高温缩聚反应，合成了高分子量的新型苯基取代杂萘联苯型聚芳醚材料；用1 H NMR、FT-IR表征了类双酚单体及聚合物的结构。

It was investigated how to increase the yield and purity of tannin, flavone and oligoprocyanidms from the root and stalk of sanguisorba, and the stability of polyphenols from sanguisorba was studied, too. The chemical constitutes of sanguisorba were analyzed, the conditions on extracting tannin, flavone and oligoprocyanidins from sanguisorba by general lixiviating process and ultrasonic wave were optimize. The flavone and oligoprocyanidins were separated from sanguisorba and purified. The stability of polyphenol from sanguisorba was studied and the chemical structure of the products was analyzed.

本论文以地榆根茎为原料，对如何提高其主要活性成分鞣质、黄酮类物质以及低聚原花青素得率和纯度以及地榆多酚的稳定性进行了探讨；主要分析了地榆中化学成分，常规浸提和超声波浸提对地榆根茎中鞣质、黄酮类以及低聚原花青素提取条件的优化，地榆根中黄酮类和低聚原花青素的分离纯化，地榆多酚稳定性能以及产品的初步化学结构分析。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。