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The change of remaining litter weight was the largest in the earlier 30 days during 60-day litter decomposition, and there was no significant difference in subsequent 30 days. The phenolic acid content of litter was significantly reduced with the decomposition time prolonging, and the releasing quantity of phenolic acid was the highest at the tenth day. The amounts of soil Aerobic azotobacter, Ammonifier and Aerobic cellulose-decomposer and the soil chemical properties such as pH, phenolic acid content, NH+4-N and available phosphorus were significantly affected by the litter aqueous extract of four decomposition stages.

凋落物分解的60d中,凋落物残留量在前30d内变化最大,30d后无显著变化;凋落物中酚酸含量随分解时间的延长,呈显著降低的趋势,且在分解10d时,酚酸释放量最大。4个分解动态的凋落物浸提液显著地改变了土壤好气性自生固氮菌、氨化细菌、好气性纤维素分解菌的数量和土壤pH值、酚酸含量、铵态氮、有效磷等化学性质。

The phenolic acid content of litter was significantly reduced with the decomposition time prolonging, and the releasing quantity of phenolic acid was the highest at the tenth day. The amounts of soil Aerobic azotobacter, Ammonifier and Aerobic cellulose-decomposer and the soil chemical properties such as pH, phenolic acid content, NH+4-N and available phosphorus were significantly affected by the litter aqueous extract of four decomposition stages.

凋落物分解的60 d中,凋落物残留量在前30 d内变化最大,30 d后无显著变化;凋落物中酚酸含量随分解时间的延长,呈显著降低的趋势,且在分解10 d时,酚酸释放量最大。4个分解动态的凋落物浸提液显著地改变了土壤好气性自生固氮菌、氨化细菌、好气性纤维素分解菌的数量和土壤pH值、酚酸含量、铵态氮、有效磷等化学性质。

And the culturable bacterial degraders were increased from 10^6CFUg^(-1) soil to 10^8CFUg^(-1) soil after inoculating with the degrader. Moreover, the bacterial population increased faster in 100mgg^(-1) microcosoms than in 500mgg^(-1) microcosoms, revealing that the inoculated bacteria could survive and enhance the biodegradation of chlorophenol in cuntaminated soil.

接种外来微生物后,土壤中可以培养的氯酚降解菌的总数从开始的10^6CFUg^(-1)增加到10^8CFUg^(-1),并且,在氯酚含量为100mgg^(-1)的土壤样品中,微生物数目的增加比在氯酚含量为500mgg^(-1)土壤样品中更快。

We take biodegradation experiments toward three colonies with different density phenolic waster water, and test their rate of phenolic degrading and speed of bacteria growth in different time period. The results show that the rates of pheolic degrading are more than 95% in 500mg/L phenol and 250mg/L cresol culture solution.

对这三株菌种进行不同浓度的含酚废水降解试验,测定其不同时间段的酚降解率和菌株生长速度,结果表明BP-1,BP-2,BP-3菌在500mg/L的苯酚,250mg/L的甲酚溶液中的降酚率均达到了95%以上。

Alkylphenols are applied widely as the rubber additives surfactants in domestic and industrial products, antioxidants and so on. As it's decomposer, nonylphenol has a steady chemical characteristics and exist widely in environment. As it's molecule structures are similar as 17beta-estradiol in human body, and it can combine with estradiol receptor simulating it, disrupt endocrine system and induce health damage effect. Many studies on environmental endocrine disrupting chemicals approved that NP have weaken estradiol functions.

烷基酚被广泛用作塑料增塑剂、农药乳化剂、纺织行业的整理剂等,作为其降解产物壬基酚(nonylphenol,NP)的化学性质稳定,环境分布广泛,由于其分子结构与人体内雌二醇的分子结构相似,许多环境内分泌干扰的实验研究结果证实壬基酚具有雌激素样作用,可以模拟雌激素与体内雌激素受体结合,干扰机体的内分泌代谢,导致健康危害效应。

IR studies of Co metal ion complexes with salicylaldehyde benzoyl hydrazone in solid state brings out the deprotonation of phenol in the formation of Co in pH 5—6 solution.On the contrary,the phenol is protonated in the formation of Co 2 in pH 8—10 solution,which is the same as the result of Zn 2 formation.

水杨醛苯甲酰腙钴络合物在固态的红外光谱分析表明,p H约 5— 6时,生成的络合物Co中的酚羟基脱质子,当 p H控制在 8— 10时,生成的络合物 Co 2 酚羟基质子化,即酚羟基未脱除质子,与络合物 Zn 2 的 IR结果相同。

The result shows that MWNT complex filtering membranes have 13.5% and 42.8% adsorptions for resorcin and alizarin red respectively. And, c-MWNT complex filtering membranes have 33.2% and 80.3% adsorptions for resorcin and alizarin red respectively. Comples filtering membrane have a great affinity for resorcin and alizarin red molecules. The membran been easily renewable, can be used repeatedly.

结果表明:制得的MWNT复合膜分别吸附了13.5%的间苯二酚和42.8%的茜素红;c-MWNT复合膜则分别吸附了33.2%的间苯二酚和80.3%的茜素红,复合膜对间苯二酚和茜素红表现出良好的吸附性,而且制得的复合膜极易再生,可重复使用。

Producted RF and CRF aerogels by process of sol-gel technics, dynamic-exchange, CO2 supercritical drying, and procedural increase in temperature carbonization methods, which have eximious capability and nanometer network structure; Systemic analysis various factors which effect gel course, such as ratio of reactants and the dosage of catalyst, and probed into the better experiments conditions(the concentration of resorcinol and formaldehyde is more than 2% and the value of R/C is between 50 and 300); During gel course , primary investigated the viscosity curve and particle size distribution of sol-solution, and analyzed the reason of catalyst dosage effects particle size of gel, and confirmed that the up-growth of gel follows the theory of " polymerize increase ".The experiment results indicated that ultrasonic with unvarying temperature disposal shortened gel time and optimized quality of gels, and the factors of ultrasonic effect gel reaction velocity were analyzed; Prepared organic aerogels using compounds of resorcin and hydroquinone substitute resorcinol reacts with formaldehyde the first time, and also optimized the proportion of resorcinol and hydroquinone (the proportion of hydroquinone in 10%~40%).

采用溶胶-凝胶工艺结合动态溶剂交换、CO2超临界流体干燥与程序升温碳化方法制备出性能优良、具有纳米网络结构的RF与CRF气凝胶;深入研究了反应物配比催化剂用量等条件对凝胶过程的影响,得到了较佳的RF凝胶制备条件(RF浓度应大于2%,R/C值取50~300);初步研究了凝胶过程中的粘度、粒径变化情况,分析了催化剂用量影响凝胶中粒子尺度的原因,在实验上印证了凝胶生长遵循"聚增长"的理论;通过引入超声波改进了RF气凝胶的制备工艺,缩短了凝胶反应时间,提高了凝胶品质,并探讨了超声波促进RF凝胶反应作用的原因;首次用对苯二酚与间苯二酚复配制备了混合有机气凝胶,优化出复配比(对苯二酚含量为10%~40%)。2。

CH3OH could attack the phosphor atom in 1,3,2-dioxaphopholane of compiound (1) to give O-methyl O-hydroxyethyl-O-phthalimidoethyl thiophosphate in 85% yield; in the presence of potassium hydroxide aryl selenol could attack the carbon atom in 1,3,2-diox-aphopholane of the cyclic phospholipid conjugate of N^1-(2-furanidyl)-N^3--5-fluorouracil to give the corresponding product of ring-opening in high yields.

在室温下,以异丙醇作溶剂,苯硒酚与化合物2不反应。在氢氧化钾存在下,以异丙醇/水作溶剂(体积比20:1,在室温下,硒酚可以有效地进攻中化合物2中1,3,2-二氧磷杂环戊烷中的碳原子生成相应的开环产物。按照这一反应条件,顺利实现了硒酚对N^1-(2-呋喃基)-N^3-羟烷基-5-氟脲嘧啶硫代环甘油磷脂缀合物的亲核开环,生成甘油骨架的端碳原子上带有芳硒基新颖的磷脂核苷缀合物。

Low-boiling phenols in low-temperature coal tar are important chemical raw materials. For the identification and determination of the individual phenol boiling below 210℃ in the low temperature coal tar, the methods of gas chromatography, liquid-liquid chromatography followed by ultra-violet analysis and fractional distillation followed by infrared analysis were evaluated and compared.

随着煤炼油工业的发展,煤焦油中的酚类,特别是低級酚,作为化工原料的利用很重要,我們应用(1)气液色譜法,(2)液液色譜与紫外光譜法結合及(3)精餾与紅外光譜法結合三种不同方法对210°以前的低級酚进行了各种异构体的成分分析,比較分析結果:三种方法对同一样品进行分析时,最大絕对誤差在2%以内,其中以气液色譜法最为快速,液液色譜法次之,精餾-紅外光譜法費时間較多;但后二种方法所得数据較完全。

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