配基

Background and Objective: The basic structure of salicylaldehyde amino acid Schiff base compounds includes a C=N chemical bond.

背景与目的：水杨醛氨基酸Schiff碱基本结构中含C＝N键，当基与金属离子配位后生物活性增强，表现出一定的抗癌、抑菌等活性。

Make up a 1.5-3% solution of your semicarbazone in 3 mL of ethanol.

用3 mL乙醇配成1.5-3%缩胺基脲的水溶液6。

So Fr-bark can be used in soilless seeding to make mixed media instead of peat

因此杉树皮可以代替泥炭配成复合基质，在无土育苗中使用。

The binding interaction of DNA with the di-iron complex 〓, designed as a model for the di-iron active site in mammalian purple acid phosphatase , are examined firstly and spectroscopically.

对所有研究的含有双核铁、双核锌及双核铜的配合物促进DNA双链水解断裂的反应性进行比较，我们发现要有效地水解断裂DNA双链，对DNA骨架的磷酸基氧原子有一定配位作用的双核金属离子是必要的，因为两个金属离子间存在协同作用，这与有关的天然酶类似。

The stereochemical effect of the chiral amino acid residues on the formation of penta-coordinate phosphorus intermolecular mixed carboxylic-phosphoric anhydride from N-phosphorylamino acids was studied with density functional theory calculations at B3LYP/6-311G level.

用密度泛函方法在B3LYP/6-311G水平上对N-磷酰化氨基酸生成五配位磷酸羧酸混酐反应中手性氨基酸残基侧链的立体化学效应进行了研究。

However, when trans-4-aryl-3-buten-2-ones were taken as the substrates, the electron-rich but less sterically hindered ligand 9c gives the best results (up to 96.4 % ee) with highly catalytic activity.

而富电子但空间位阻小的配体9c对亚节基丙酮类底物获得最好的结果(%。4%ee)，同时还表现了最好的化学活性。

In this dissertation , the fading status of several mid-temperature vinyl sulphone reactive dyes with different color and relatively low cost in light and perspiration has been tested according to the ATTS standard. A team of three prime color reactive dyes with high light-perspiration fastness (Levafix Fast Red CA、Reactive Yellow 3RS、Reactive Navy RGB) has been selected and the influence of different dyeing process parameter on their match performance were studied and finally the proper normal dyeing process was confirmed.

其次，本文从实际应用角度出发按照ATTS汗液标准测定了一些不同色相的成本相对较低的中温型含乙烯砜活性基的活性染料在光照及汗液组分作用下的褪色情况，从中筛选出了具有较高耐光汗复合色牢度的活性染料三原色Levafix Fast Red CA、活性黄3RS、活性藏青RGB，并研究了不同工艺参数对其配伍因子的影响，确定了常规最佳工艺。

The ligand of the chiral Schiff base and acetylacetone vanadium are subjected to complexation in situ, hydrogen peroxide is taken as an oxidant, aryl alkyl thioether asymmetric oxidation reaction is catalyzed in a toluene or dichloromethane solution under low temperature or room temperature, enantioselectivity of chiral sulphoxide is 72 percent to 95 percent ee, and yield is 42 percent to 83 percent.

将上述手性西佛碱配体与乙酰丙酮氧钒原位络合，采用双氧水为氧化剂，在甲苯或二氯甲烷溶液中低温至室温下催化芳基烷基硫醚不对称氧化反应，手性亚砜的对映选择性为72％-95％ee，产率为42％-83％。

Two of the four alcohol oxygen atoms O3 in theligands act as oneμ2 bridged atom and the other two O6 act asμ3 bridge to link to Cuatoms together, resulting in the tetranuclear structure.

而立方烷型四核铜骨架配合物是分子中四个Schiff碱配体各提供一个亚氨基N、一个酚基O和一个醇羟基O，与四个Cu一起形成立方烷型四核铜骨架。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。