配基

An isonitrile ligand, 2 methyl cyclohexylisonitrile is synthesized and a copper salt Cu(I 4BF 4 of this ligand is also prepared. The isonitrile and its copper salt are characterized by IR and elemental analysis.

合成了一种新的异腈配体 2 甲基环己基异腈及其铜络盐，并经红外光谱和元素分析等表征予以确认。

In order to reduce the non-specific binding between oligonucleotides and bases mutation caused by the complicate secondary structure of DNA and excessive PCR amplification, a frequently phenomenon in one-step gene synthesis, we used a two-step method including assembly PCR and digestion-ligation step to synthesis Aspergillus niger lipase gene lipA.

本研究主要针对一步法长片段基因合成中复杂结构的非特异性配对和过多的PCR引入碱基错配等问题，采用二步法(组装PCR和酶切-酶连)合成了黑曲霉脂肪酶基因lipA。

Base bed top layer ; unbound graded aggregate ; experimental study ; machiner y paving

基床表层；级配碎石；试验研究；机械摊铺

An LC dendrimer having novel structure characteristic was given, which has metal coordination bond and mesomorphic moiety.

给出一种具有新的结构特点的液晶性树枝状大分子，它兼有配位金属和介晶基元。

The results show that during oxidation, a methoxyl group in the ligand ring broke, and the phenoxy- and water-bridged Cu complex formed.

实验结果表明：在Cu配合物氧化过程中，能使配体环上的一个甲氧基发生断裂，形成苯氧桥和水桥联的Cu配合物。

A combinational PPD, SL2, is devdoped, comprising 2 EVA polymers, a high molar mass polymer of long chain alkyl acrylate, a tercopolymer with strong polar functionalities, and a resin/asphaltene modificator.

研制了由2种EVA、一种高分子量聚丙烯酸高级醇酯、一种具强极性基的三元共聚物及胶质沥青质改性剂组成的复配降凝剂SL2。

In this dissertation, polyethylene glycol monomethyl ether of 2000 molecular weight as soluble support, an array of soluble polymer-supported tartrate esters were designed, synthesized, and applied in asymmetric epoxidation of allylic alcohols.

本论文以平均分子量为2000的聚乙二醇单甲醚为可溶性支载体设计和合成了一系列可溶性聚合物支载的酒石酸酯配体，并将它们用于烯丙基醇的不对称环氧化反应。

ATRP initiation systems consist of organic chloride initiators (RCl, RBr or aryl sulfonyl chloride, etc.), transition-metal catalysts in lower oxidation state Cu(I, Fe, Ru, Ni, etc. and organic electronic-donating ligands (2,2'-bipyridine―bipy or bpy, PPh3, multidentate ligand compound 1,1,4,7,7-pentamethyldiethylenetriamine, etc.).

普通ATRP引发体系包括引发剂主要为氯或溴化物，芳基磺酰氯；低价过渡金属卤化物如Cu， Fe，Ru，Ni等；有机配体如2，2'-联吡啶，PPh3，脂肪族多元胺等。

The grafting of polycaprolcatone on starch by ring-opening polymerization of e -caprolactone was initiated from the starch hydroxyl functions in the presence of a catalyst such as stannous octoate Sn(0ct2, Dibutyltin dilaurate or titanium tetrabutoxide. The grafting ration could reach 16%. IR, X-ray diffraction and DSC were used to investigate the grafting-polymer.

在辛酸亚锡Sn(Oct_2、二月桂酸二丁基锡和钛酸丁酯等催化剂作用下，淀粉羟基引发己内酯单体进行配位聚合，淀粉接枝率可以达到16％，并通过红外光谱、X—ray衍射及DSC等测试手段对反应产物进行了表征。

The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.

晶体结构研究表明配体H4L为顺式桥联分子，晶体中存在两种氢键，一种是草酰胺基团的O原子与苯环上的酚羟基形成O-H…O氢键[d=2.906(2)，∠O-H…O=151.8°]；另一种是草酰胺基团的氨基与相邻草酰胺基上的O原子形成N-H…O氢键[d=2.849(2)，∠N-H…O=158.7°]，通过上述两种氢键将化合物H4LB连接成二维网络结构。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。