配基

The comparison of hydrolysis-polycondensation reaction and microstructure of ORMOSILs derived by TEOS, MTES, VTES, ETES confirms that the influence of organic group such as methyl, vinyl, ethyl and ethoxyl on the hydrolysis and polycondensation reaction rate depends on several factors including electron-donating capability, size and number of ethoxyl group which can participates polycondensation reaction.

确认甲基、乙烯基和乙基和乙氧基等改性基团对硅醇盐水解-缩聚反应速度的影响是取决于有机改性基团的电负性、尺寸和可水解的-OR基团数目等因素综合作用的结果，其水解速度依MTES＞TEOS＞VTES＞ETES的顺序递减。由于Si原子上可聚合的基团数目减少，导致MTES、VTES和ETES的聚合反应速度降低，而与水解速率失配。

In this paper, with 2-oxo-propionic acid salicyloyl hydrazone as a ligand, one calcium complex, three copper complexes and thirteen rare earth(RE=La, Ce, Pr, Nd, Sm, Eu. Gd, Tb, Dy, Er, Tin, Yb and Lu) complexes have been synthesized. The crystals of four complexes were obtained, and the crystal structures were determined by single crystal X ray diffraction. One of the crystals is calcium complex, the other are binary and trinary complexes of copper.

本文选用2-羰基丙酸水杨酰腙作为配体，在水中分别与钙、铜、稀土(RE=La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Er、Tm、Yb和Lu)的盐反应，共制得了17种未见文献报道的配合物，另外还培养了2-羰基丙酸水杨酰腙、咪唑与铜、钙的二元及三元配合物的四种单晶，对La-Gd的稀土的配合物进行了溶解热的测定，并用Gauss-98软件包对铜的配合物进行了有关量化计算。

A series of L-histidine Schiff bases that include Sal-His (H2L^1), Br-Sal-His(H2L^2), NO2-Sal-His (H2L^3) and their Cu complexes were synthesized, and the catalytic behavior of Schiff-base-Cu for the oxidation of β-ionone to 4-oxo-β-ionone as well as the effects of substitutents on these properties were examined.

合成了芳环上含不同取代基的Schiff碱配体（水杨醛缩组氨酸(H2L^1)、5-溴水杨醛缩组氨酸(H2L^2)、5-硝基水杨醛缩组氨酸(H2L^3)及其铜配合物，研究了其作为催化剂应用于催化分子氧氧化β-紫罗兰酮制备4-氧代－β-紫罗兰酮中的行为。

The induced supramolecular chirality was found to be dependent on the absolute configuration of lateral residues, that is, the polymers with-configurational oxazolinyl chromophores tended to form chiral aggregates with levorotatory handedness, while polymers obtained from the-monomer offered dextrogyrate one upon the addition of Cu salt. A model, in which side groups would arrange in a helix fashion, is employed for describing the unusual chirality.

由此提出了侧基在Zn／Cu协同配位作用下形成螺旋状排列的模型，即侧基螺旋模型。N-噁唑啉苯基马来酰亚胺与甲基丙烯酸甲酯共聚得到了耐热性能好(热分解温度大于296℃)的光学活性聚合物~(25D=-7.8°(来源：Af4BC论文网www.abclunwen.com)～-36.6°。

Basal leaves petiolate, not rosulate, simple, lyrate, pinnatifid, pinnatisect, bipinnatisect or/and dentate.

具叶柄的基生叶，不莲座状，单，大头羽裂，，羽状全裂，或/和配位基。

Two classes of specific binding sites in the polymer matrix were investigated by Scatchard analysis, which indicated that two kinds of complexes between functional monomers and templates were formed before the polymerization process. Comparing with the structure of TNT and acrylamide, one kind of complex between TNT and acrylamide was strongly charge-transfer complexing interaction by p-πcomplex between electron-rich amino group of acrylamide and electron-deficiecy-benzene ring of TNT, the other was hydrogen bonding interaction between amino group (-NH_2) of acrylamide molecule nitro group (-NO_2) of TNT.

Scatchard分析结果表明，在TNT印记聚合物微球中存在两类结合位点，这表明在聚合反应之前，TNT与功能单体丙烯酰胺分子之间存在两种不同类型的作用力而自组装成两类的模板分子-功能单体复合物，一类可能是由于富电子的丙烯酰胺和缺电子的TNT的苯环通过p-π配键而形成的电荷转移复合物，另一类可能是由于丙烯酰胺的胺基与TNT的硝基之间的氢键作用而形成的复合物。

The protonation constants of formylformic acid thiosemicarbazone (A, H2FFTSC) and glycylglycine and stability constants of binary complexes formed they with Mn, Co, Ni, Cu and Zn and trinary complexes of M-FFTSC-GG at 25±0.1℃ and in the presence of 0.1 mol.L-1 KNO3 were determined. The relation between the stability of binary complexes of M-FFTSC and their disinfectivity and disinfection mechanism were discussed.

在25±0.1℃，I=0.1 mol.L-1 KNO3条件下，应用pH法测定了甲酰基甲酸缩氨基硫脲(A配体，缩写H2FFTSC)，甘氨酰甘氨酸的质子化常数，它们与锰、钴、镍、铜和锌的二元配合物以及过渡金属-甲酰基甲酸缩氨基硫脲-甘氨酰甘氨酸三元配合物稳定常数，讨论了过渡金属席夫碱配合物的杀菌活性与其稳定性之间的关系，对杀菌机理提出了一些看法。

A new series of the ligands of liquid crystal polymers with T-shaped two-dimensionl mesogens was synthesied by solution condensation polymerization by using 4,4'-(α,ω-alkylenedioyloxy)-dibenzol dichlorids with 2,4-dihydroxy-4 '-alkoxyl azobenzene as the monomers.

摘 要 以4，4′-二苯甲氯和2，4-二羟基-4′-烷氧基偶氮苯为单体，通过溶液聚合，合成了一系列新的含T-型二维液晶基元的液晶高分子配体。

A new series of the ligands of liquid crystal polymers with T-shaped two-dimensionl mesogens was synthesied by solution condensation polymerization by using 4,4'-(,-alkylenedioyloxy)-dibenzol dichlorids with 2,4-dihydroxy-4'-alkoxyl azobenzene as the monomers.

以4，4′-二苯甲酰氯和2，4-二羟基-4′-烷氧基偶氮苯为单体，通过溶液聚合，合成了一系列新的含T-型二维液晶基元的液晶高分子配体。

Synthesis and application of formaldehyde-free dye-fixing agent ENF;2. Chlorine-resistant reactive dye-fixing agent CRS was prepared by mixing polyamine CS and polymer CR synthesized by dimethyldiallyl-ammonium chloride and allylamine.

文章以二甲基二烯丙基氯化铵和烯丙基胺为原料合成聚合物CR，与胺类聚合物CS复配制备活性染料耐氯固色剂 CRS，用于棉活性染料染色布固色整理，研究其耐氯性能。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。