配基

Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体，初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用，20℃和20mol％催化剂量下，获得了32.5％ee和72％收率的产物。

In this thesis, we developed chiral proton N-O type ligands and employed them in the enantioselective addition of diethylzinc to N-diphenylphosphinoyl imines. The relationship between the structure of the ligands and the enantioselectivity was systematically studied. Furthermore, enantioselective butylation of N-diphenylphosphinoyl imines withBu〓Zn and enantioselective diphenylzinc addition to imine were also examined.

本文致力于亚胺的不对称催化有机锌试剂加成反应的研究：以手性质子型N-O配体为促进剂，对N-二苯基次膦酰亚胺进行不对称乙基锌加成反应而展开研究工作，系统地考查了手性配体的结构对反应的影响；另外，对N-二苯基次膦酰亚胺的不对称催化丁基锌加成进行了研究，并首次对亚胺的不对称苯基锌加成反应进行了初步探索。

Then, method for calculating ultimate bearing capacity of element of SFRC with steel bars which is unified by introducing the concept of strengthening item which is related to the characteristics of steel fibre andconcrete, has been studied.

本文对配筋钢纤维混凝土构件极限承载力的计算方法进行了研究，引入与基体强度有关的增强项的概念使配筋钢纤维混凝土构件极限承载力的计算方法得到了统一。

This dissertation divides into seven chapters and the main contents and conclusions are listed as following:1. Three series binuclear lanthanide carboxylate coordination polymers 1～7 have been synthesized under hydrothermal conditions by altering the length of carbon chains between carboxyl group and phenyl ring on ligands, which are isophthalic acid, 1,3-phenylenediacetic acid and 1,3-phenoxydiacetic acid, and lanthanide ions such as Pr~(3+), Eu~(3+)and Ho~(3+).

论文共分七章，主要研究内容和结论如下：1、通过改变间苯二甲酸配体的羧基和苯环之间的碳链长度，从间苯二甲酸、间苯二乙酸到间苯二氧乙酸，以及改变稀土离子半径Pr~(3+、Eu~(3+)和Ho~(3+)出发，在水热条件下制备了三个系列双核金属单元的稀土羧酸二维配位聚合物1～7。

By using the meshless method, a numerical ocean engineering basin was established to simulate irregular waves propagated in shallow water. Locating the source points outside the computational domain, the problem of water wave propagation was solved by collocation of only a few boundary points instead of meshes.

采用基于配点和径向基函数的无网格数值模拟方法，建立数值海洋工程水池，将源点布置在模拟波浪场之外，沿边界布置配点而不是划分网格；对深水不规则波经斜坡过渡后在均匀水深浅水域中传播的过程进行无网格数值模拟和波谱的迭代修正。

Other than conventional concept, the N→Rh bond, formed by rhodium in the complex and nitrogen at pyridine ring in the ligand, did not break in the course of the carbonylation reaction, but formed into new active species instead, i.e., the ligand and rhodium as a whole participated in the oxidative addition of CH3I and the formation of CH3COI.

配合物中铑与吡啶环上共轭N形成的N→Rh配键，在羰基化反应过程中并非通常认为的断裂而是形成新的活性物种，即配体与铑作为整体参与了CH3I的氧化加成及CH3COI的生成过程。

These dendritic NOBIN derived Schiff base ligands have been applied to titanium catalyzed hetero-Diels-Alder reaction of Danishefshy's diene and aldehydes, affording the corresponding 2-substituted 2, 3-dihydro-4H-pyran-4-one in quantitative yields and excellent enantioselectivities (up to 97. 2%ee). Comparing the reactivities and enantioselectivities of reaction catalyzed by the titanium complexes of these Schiff base ligands, it was found that a series of ligands L〓 were superior to the other three series of ligands L〓, L〓 and L〓, a significant positive NLE and a dendrimer effect existed in the L〓 dendritic catalyst system. The disposition of the dendritic wedges and the dendron size in the ligands were observed to have a significant impact on the enantioselectivity of the reaction.

NOBIN衍生的树枝状大分子希夫碱手性配体与钛形成的配合物在催化不对称杂Diels-Alder反应中的应用将得到的四个系列NOBIN衍生的树枝状希夫碱三齿手性配体与四异丙氧基钛形成的配合物用于催化Danishefsky's diene与醛的不对称杂Diels-Alder反应，通过反应条件的优化，获得了定量的收率和最高达97.2％ee值的对映选择性；考察了这四个系列NOBIN衍生的树枝状希夫碱钛配合物的催化活性和对映选择性，结果发现它们的活性次序依次为L〓≈L〓＞L〓＞L〓，对映选择性次序依次为L〓＞L〓＞L〓＞L〓。

The catalytic activities of some coordination polymers in synthesis of DPC from oxidative carbonylation of phenol were investigated. Palladium complex Pd(C_2O_4)·0.5(C_4H_8N_2) has better catalytic activity in the typical reaction condition, it was synthesized with PdCl_2, oxalic acid and piperazine hexahydrate by solvothermal method under low temperature and characterized by IR, EA and TG.

以一些配位聚合物作为主催化剂考察它们在苯酚氧化羰基化生成碳酸二苯酯反应中的催化活性，经过比较，筛选出配位聚合物Pd(C_2O_4)·0.5(C_4H_8N_2)(在低温条件下以溶剂热法合成)，采用IR、TG，EA和比表面分析技术对它进行了表征。

The substituted half-sandwich titaconece with bulky alkoxyl group [CpTiC1〓 or CpTi 〓] or indene ring can not be fluorinated by BF〓·Et〓O under the selected condition, but still coordinates with the BF〓, this coordination then enhances the steric effect that stabilizes the precursor and hinders the reduction of the Ti to the Ti species, reflected in the decrease in polymerization activity.

但是这个转化受主催化剂分子的空间位阻和聚合反应温度的影响，当主催化剂为大位阻的烷氧基取代茂钛络合物或茚钛络合物时，在一般的聚合温度下BF〓不能对它们进行氟化，但可以和其中的OR配位，这种配位进一步加剧了空间位阻，从而阻碍了活性中心的形成，导致催化活性的下降。

In this article, the stress inside a quantum-wire structure is studied. Based on the derived expression of the stress inside a quantum-wire structure with arbitrarily shaped cross section, the analytical solution of the stress inside a trigonal quantum-wire structure in an infinite matrix is obtained.

研究了晶格失配和热失配在半导体量子线结构中所产生的弹性场，在分析圆柱形量子线结构弹性场的基础上，推导得到了任意截面形状量子线结构解的一般形式，并给出无限大基体内横截面为三角形量子线结构的解析结果。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。