配基

The thermolysis of the isomerized products derived from norbornadiene-coordinated carbonyl iron complexes gave two sorts of the thermolytic products based on different substituents on the olefin ligands. One is the corresponding diiron dimer complex, and the other is the complex in which the C-C bond of the cycloolefin ligand is broken.

以降冰片二烯三羰基铁络合物衍生出来铁卡宾络合物的异构化产物的热解，随着烯烃配体上取代基的不同，而分别得到了络合物发生二聚和烯烃配体发生碳碳键断裂的两类热解产物。

In the fourth chapter, four new complexes of hydrazide of podophyllic acid with transition metals have been prepared. Elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA were used to characterize them. The results show that general formula of the complexes is M〓(n=0 or 2). The ligand is linked through the carbonyl oxygen and the terminal nitrogen of the hydrazide base to the transition metal ions in bidentate mode.

第四章 合成了四种鬼臼酰肼的过渡金属配合物，通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征，研究结果表明，配合物的组成为M〓（n=0或2），配体是通过羰基氧和肼基上的端氮以双齿形式与金属离子配位的。

The X-ray structure analysis reveals that the metal is in a square-planar N2O2 coordination environment formed by the phenolate-O, the imine-N and the deprotonated amide-O atoms of hydrazone ligand and the N atom of Himdz.

配合物的晶体结构分析表明，中心金属通过酰腙配体的酚基氧原子、亚胺基氮原子、去质子酰胺氧原子以及咪唑的氮原子形成平面四方形的N2O2配位环境。

A series of the ligands including 6-bromo-piperonal dimethyl acetal, bis (9-fluorenyl) silane, and the dimer of indene have been synthesized and characterized.

合成了溴代胡椒醛二甲基缩醛基配体，合成了手性配体甲基苯基双芴基硅烷，合成了茚的二聚体，对其进行表征，培养单晶并测定了晶体结构。

At the same time, the importance of donor atoms pertaining to the side chain in the complexation reaction of three lariat azacrown ethers with alkali metal ions has been analyzed through the Fukui function.

同时，利用福井函数，对侧臂在氮基臂式冠醚与碱金属配位过程中的重要性进行了分析，结果表明氮基臂式冠醚的侧臂上供电子原子对整个冠醚分子与金属配位过程中有着十分重要的作用。

In this thesis, we transfer the microgroove patterns onto the Poly substrate to avoid the cracks by means of replica molding method. Different from traditional polymer alignment layers, the bendable materials serve not only as substrates but also as alignment layer; thus, we successfully fabricated the flexible alignment-layer free twisted nematic liquid crystal cell.

在本研究中，我们使用复制成形法，直接将奈米沟槽转印到软性高分子基板上，来改进脆裂的问题，不同以往的高分子薄膜，我们是让基板本身就具有配向液晶分子的功能，做出不需额外配向层的可挠式扭转向列型液晶元件。

The result is that both tin atoms are five-coordination, have a distorted trigonal bipyramidal geometry with an additional week interaction between another oxygen atom and tin atom.

分子中四个羧酸酯基有桥联双齿和单齿两种不同的配位模式；在内环锡和外环锡的配位单元中，锡均形成具有五配位的畸变三角双锥配位构型，同时另有一氧原子与中心锡原子之间有弱相互作用。

By means of UV-vis spectrophotometer, the complex abilities of calix [4] arene ligands with metal ions were researched, and the effect of solvent systems was discussed.

使用紫外-可见分光光度法研究了杯[4]芳烃配体与金属离子的络合性质，并考虑了溶剂对配体与金属离子配位的影响，评价了杯[4]芳烃的不同取代基对过渡金属离子及稀土离子的配位作用。

In order to get the information of interaction between metal complex and DNA and select metal complexes which can cleave DNA effectively, twenty seven transition metal complexes containing O/N coordinate atoms have been synthesized in this thesis. We report the synthesis, crystal structure and properties of the complexes. One of the complexes is the first μ〓-oxalato tetranuclear Cu complex, in which there is ferromagnetic interaction between the copper atoms bridged by oxalate ions. Two trinuclear copper complexes containing partial cubane Cu〓O〓 cores have been synthesized and discussed the magnetic properties.

为了解金属配合物与DNA的相互作用及筛选能有效切割DNA的金属配合物，为无机药物合成及应用提供基础信息，本文利用十个含N、O原子的多齿配体设计合成了二十七个未见文献报道的过渡金属配合物，并解析了它们的晶体结构：其中包括首例μ〓-草酸根的四核铜配合物；合成了两个具有μ〓-OH〓三核缺角立方烷结构的Cu配合物；以HCBP衍生物为配体合成了七个过渡金属配合物；以SCN〓、N〓，C〓O〓等为桥联配体，以dmpyen为端基配体合成了十一个配合物。

Base Station type Software versionTypes of carrier frequency board adoptedTypes of combiner adoptedWhether had obtained the network license or notIndoor type or outdoor type Whether the master port is separated from the remote-port The maximum carrier frequency capacity of single cabinet The maximum supportable sector numbers of single cabinetWhether it is dual-carrier frequency board or notMust it be paired configuration if it's dual-carrier frequency board (namely, the type of single carrier frequency station could only configure the dual-carrier frequency on hardware) The maximum achievable configuration of a single station of the single cabinetReceiver sensitivity The maximum expand capacity of a single base station (the maximum number of TRX in configuration / the number of cabinets which is required)(fill in according with the three sectors) Top box transmitted power (given separately a grade one combine and a grade two combine) The maximum output power of amplifier (voice, a single logical carrier frequency) The maximum output power of amplifier (EGPRS, a single logical carrier frequency)Whether it has tower-interfaceWhether it has built-in lightning protectionWhether it support the ultra-long cover / whether it need for software support (give simple description that how hardware and software could achieve this) The supporting condition of EGSM (it should be supported including by the carrier frequency, combiner) Dual-band carrier wave (whether it supports the mixed use of 900 M/1800M in the same cabinet) The commonality of duplicate parts Whether it can built-in transmission unitThe single cabinet size (high × width × deep) Installation method Whether it can place against the wallThe basic frame full-configured weight and the supportable number of carrier frequencyThe expansion frame full-configured weight and the supportable number of carrier frequency

基站型号软件版本号采用载频板型号采用合路器型号是否已取得入网许可室内型or室外型是否是主远端分离单机柜最大载频容量单机柜最大支持的扇区数是否是双载频板如是双载频板，是否必须成对配置(即单载频站型只能硬件配置双载频)单机柜可达到的单站最大配置接收机灵敏度单基站最大扩展能力(最大配置TRX数/需机柜数)(按3扇区填写)机顶发射功率(分别给出一级合路与两级合路)功放最大输出功率功放最大输出功率(EGPRS，单个逻辑载频)有无塔放接口有无内置避雷装置是否支持超远覆盖/是否需要软件支持(简单描述软硬件如何实现)EGSM支持情况(包括载频、合路器均应支持)双频段载波（是否支持900M/1800M在同一机柜内混合使用）备件通用性是否可以内置传输单元单机柜尺寸安装方式可否靠墙放置基本架满配重量及支持载频数扩容架满配重量及支持载频数是否支持基本架与扩容架跨扇区满配功耗满配时重量供电方式机柜进出线方式合路器损耗合路能力：几合一单扇区最大支持几载频合路到一副天线/采用几个合路器单扇区载频达到需要增加一副天线时，是否支持两级合路换以不增加天线如两级合路插损为是否支持基带跳频和合成跳频每单个合路器在从低载频数向高载频数扩容时，是否还需要增加硬件可用性指标MTBFMTTR系统中断服务时间硬件是否支持EGPRS本次报价软件版本号开始支持EGPRS的软件版本号其他特点注： 1 应分别填写出来按照本次报价要求所采用的全部BTS型号和采用的合路器型号 2 列出本报价要求的全部室外型基站与高功放单元

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。