配合的

This paper analyzes the cause of distortion of octahedron complexes and tetrahedron complexes and states the general methods to judge the distortion .

分析了八面体配合物和四面体配合物畸变的原因，给出了判断八面体配合物和四面体配合物畸变的一般方法：配合物是否发生畸变要看中心离子电子云是否对称分布，若对称分布，就具有规则的八面体或四面体构型，否则，将会发生变形。

There are two independent molecules of ZnL or Co(IIL and two water molecules in one asymmetric unit of complex 1(or 2), the crystal structure of CuClL1·2H2O consists of one molecule of CuClL1 and two water solvate molecules in the asymmetric unit, while the ZnL·CH3OH (4) comprises of one molecule of ZnL and a methanol molecule in per unit.

在这四个金属配合物中，配合物(1)和配合物(2)的每个不对称单元中有两个独立的ML 分子和两个水分子，配合物(3)的每个不对称单元中有一个CuClL1分子和两个水分子，而配合物(4)的每个不对称单元中只有一个ZnL 分子和一个甲醇分子。

There are two independent molecules of ZnL or Co(IIL and two water moleculesin one asymmetric unit of complex 1(or 2), the crystal structure of CuClL_1·2H_2O consistsof one molecule of CuClL_1 and two water solvate molecules in the asymmetric unit,while the ZnL·CH3OH (4) comprises of one molecule of ZnL and a methanolmolecule in per unit.

在这四个金属配合物中，配合物(1)和配合物(2)的每个不对称单元中有两个独立的MLZn(IIL、CoL分子和两个水分子，配合物(3)的每个不对称单元中有一个CuClL_1分子和两个水分子，而配合物(4)的每个不对称单元中只有一个ZnL分子和一个甲醇分子。

The crystal structures have been determined by single-crystal X-ray diffraction.Cadmium atoms in compounds 1 and 2 show an eight-coordinated distorted square-antiprismatic geometry and a seven-coordinated distorted pentagonal bipyramidal geometryrespectively. Copper atoms in compounds 3 and 4 show a six-coordinated distorted threeprismatic geometry and a four-coordinated distorted tetrahedral geometry respectively.

所有配合物的晶体结构都通过单晶X-射线衍射确定：配合物1中的镉离子周围显示八配位的扭曲四方反棱柱构型；而配合物2中的镉离子周围显示七配位的扭曲五角双锥构型；配合物3中的铜离子周围显示六配位的扭曲三棱柱构型；配合物4中的铜离子周围显示四配位的扭曲四面体构型；配合物5中的锌离子周围显示六配位的扭曲八面体构型。

We studied the fluorescent capability of Binolate lanthanide complexes. Thefluorescent analysis shows that both ligand and complexes exhibit luminescence. Insolid state and solution, they have the different luminescence mechanism, intensity andcolor. So we can synthesize the complexes of dissimilar fluorescence performance bychanging the state and solvent polarity. According to the literatures, the complexes playan important role in luminescence material and probe with the development of theinformation technique.

对合成的八个邻萘酚稀土配合物进行发光性能研究，通过荧光光谱分析显示，配体和配合物都能够发出荧光，并且在固体状态和溶液中的发光机制、光强度及发光颜色都不同，所以通过改变邻萘酚稀土配合物的状态以及所选溶剂极性的不同，可以得到荧光性能不同的邻萘酚稀土配合物；根据查阅的文献可知，这类配合物在发光方面的应用很少，所以在当前信息显示技术高速发展的今天，邻萘酚类发光稀土配合物在发光器件、荧光探针等材料的研究领域当中不仅具有理论意义还有实际的应用价值。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.

1获得了多个文献首报和罕见的特殊结构的配合物：两个同时含有碱金属-过渡-稀土金属的独特的九核配合物；两个具有孔道的稀土-过渡金属异四核配合物；草酰胺类〓四核配合物；两个由双核配合物通过叠氮和单个氯原子连成的四核配合物，尤其是以单个氯桥相连的化合物非常少见；一个由弱配键和氢键连成的具有一维波浪形结构的配合物；一个通过配位键和氢键连成的二维配位聚合物。

The results showed that the different molecular weight of the complexes of Chitosan with copperor zinc, the complexes of carboxymethyl Chitosan with copper and the low-molecular-weight iii complexes of sulfation chitosan with copper had excellent inhibition on Valsa mali. The low-molecular-weight complexes of chitosan with copper had inhibition on Botyosphaeria berengeriana. All of samples had no inhibition on Fusarinm oxysporium.f.sp.vasinfectum and Alternaria Solani under this test conditions.

结果 发现，不同分子量的壳聚糖 Cu、Zn配合物、羧甲基壳聚糖 Cu配合物及低分子量的壳聚糖硫酸酯 Cu配合物对苹果腐烂病菌有明显的抑制作用；低分子量壳聚糖 Cu配合物对苹果轮纹病菌有一定的抑制效果；所有配合物在试验浓度范围内，对棉花枯萎病菌和蕃茄早疫病菌均无抑制作用。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

In the third chapter, eight new complexes of 4, 6-dimethylpyrimidine 2-thioacetic acid with rare earth metals has been synthesized and characterized by means of elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA. The general formula of the complexes is Ln〓(n=4 or 5). In the complexes, the deprotonated ligand coordinated to the rare earth metal ions in chelate bidentate mode. 4 or 5 molecular of crystal water existed in the complexes.

第三章合成了八种4，6-二甲基嘧啶-2-硫代乙酸的稀土配合物，通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征，研究结果表明，配合物的组成为Ln〓n=4或5），在配合物中配体羧基脱去质子后采用螯合双齿的方式与稀土离子形成配位键，同时，配合物中含有4或5个结晶水。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。