配合基

The results indicate that the three metal complexes could catalyze the disproportionation of the superoxide anion free radical O2(superscript -, and could be used as the active center model complexes of SOD.

结果表明，3种金属配合物均有一定的催化歧化超氧阴离子自由基O2(上-活性，均可被称作超氧化物歧化酶活性中心的模拟配合物。

Determination of the equilibrium constant of a coordinated compound.

四、铁离子与磺基水扬酸配合物的组成和标准稳定常数的测定，了解用比色法测定配合物的组成和配离子稳定常数的原理和方法，掌握分光光度计的使用及有关试验数据的处理方法。

The thermal stability of diindenyl lanthanidealkoxides is inferior to that of analogous cyclopentadienyl lanthanide complexes.

但是该类配合物的热稳定性相对低于类似的茂基配合物。

A series of oligoaniline-modified mono- and bis-nuclear iron complexes have been synthesized successfully, and their spectroscopic and electrochemical properties have been studied.

合成了一系列齐聚苯胺修饰的三联吡啶铁配合物，研究了齐聚苯胺链长、不同取代基等对配合物光谱性质和氧化还原性质的影响。

1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.

1.1 为了模拟酪酸铁酶活性中心，设计并合成了含有酚羟基和苯骈咪唑基四齿配体N，N-(2-羟基苯)-N，N-二氨，并合成它的铁配合物：Fe〓、Fe〓〓(2)和Fe〓，并经各种谱学手段表征了这些铁配合物。

The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex.

该过渡金属配合物具有由亚苯基桥连接的酰胺基的五边环结构，其中在金属位置附近形成稳定键，因此位阻单体可容易地接近过渡金属配合物。

Compared to the pure complex powder, the excitation spectra of the rare earth complex in the assemblies show blue shifts while the emission spectra show fewer split peaks.

在紫外光激发下，组装体发出相应稀土离子的特征谱线；和纯配合物粉末相比，其激发光谱发生一定的蓝移，而其发射光谱则表现出较少的劈裂；由于基质的保护作用，组装体中的配合物具有较高的荧光寿命和发光效率。

The recent progress in the studies of saccharide -metal complex is reviewed. Especially their synthesis based on saccharide ligand and application is described.

综述了近年来糖－金属配合物的最新研究进展，重点从糖基配体的角度介绍了各类糖－金属配合物的合成与应用研究。

By virtue of the coordination of Cr2L (L = CO; PPh3; C3H5 BF4-) with N-vinylcarbazole, acenaphthylene and their derivatives as organic ligands, a series of organometallic complexes have been synthesized. Their spectra characterization and X-ray diffraction analysis have been performed. It is found that this kind of complexes possesses an electronic structure with highly extensive π- delocalization.

以N－乙烯基咔唑、苊烯及其衍生物作为配体与金属基团Cr2L(L = CO； PPh3； C3H5 BF4-)配位，合成了一系金属有机配合物，并对其进行了光谱表征和单晶X射线衍射分析，发现该类配合物具有高度离域的电子结构。

RCM reactions of 49 and 50 are chosen to evaluate the catalytic performance ofthe complexes 46-48 because they are informative and simple to manipulate. The resultsindicated that ruthenium benzylidene complexes 46 and 48 possess significant thermalstability and cyano group tolerance.

由于烯烃49、50的闭环交互置换反应简单、清晰，故用来考察新钌卡宾配合物的催化性能，结果表明配合物46、48具有良好的热稳定性及耐氰基性能。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。