配合基

The results indicate that the three metal complexes could catalyze the disproportionation of the superoxide anion free radical O2(superscript -, and could be used as the active center model complexes of SOD.

结果表明，3种金属配合物均有一定的催化歧化超氧阴离子自由基O2(上-活性，均可被称作超氧化物歧化酶活性中心的模拟配合物。

Determination of the equilibrium constant of a coordinated compound.

四、铁离子与磺基水扬酸配合物的组成和标准稳定常数的测定，了解用比色法测定配合物的组成和配离子稳定常数的原理和方法，掌握分光光度计的使用及有关试验数据的处理方法。

The thermal stability of diindenyl lanthanidealkoxides is inferior to that of analogous cyclopentadienyl lanthanide complexes.

但是该类配合物的热稳定性相对低于类似的茂基配合物。

A series of oligoaniline-modified mono- and bis-nuclear iron complexes have been synthesized successfully, and their spectroscopic and electrochemical properties have been studied.

合成了一系列齐聚苯胺修饰的三联吡啶铁配合物，研究了齐聚苯胺链长、不同取代基等对配合物光谱性质和氧化还原性质的影响。

1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.

1.1 为了模拟酪酸铁酶活性中心，设计并合成了含有酚羟基和苯骈咪唑基四齿配体N，N-(2-羟基苯)-N，N-二氨，并合成它的铁配合物：Fe〓、Fe〓〓(2)和Fe〓，并经各种谱学手段表征了这些铁配合物。

The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex.

该过渡金属配合物具有由亚苯基桥连接的酰胺基的五边环结构，其中在金属位置附近形成稳定键，因此位阻单体可容易地接近过渡金属配合物。

Compared to the pure complex powder, the excitation spectra of the rare earth complex in the assemblies show blue shifts while the emission spectra show fewer split peaks.

在紫外光激发下，组装体发出相应稀土离子的特征谱线；和纯配合物粉末相比，其激发光谱发生一定的蓝移，而其发射光谱则表现出较少的劈裂；由于基质的保护作用，组装体中的配合物具有较高的荧光寿命和发光效率。

The recent progress in the studies of saccharide -metal complex is reviewed. Especially their synthesis based on saccharide ligand and application is described.

综述了近年来糖－金属配合物的最新研究进展，重点从糖基配体的角度介绍了各类糖－金属配合物的合成与应用研究。

By virtue of the coordination of Cr2L (L = CO; PPh3; C3H5 BF4-) with N-vinylcarbazole, acenaphthylene and their derivatives as organic ligands, a series of organometallic complexes have been synthesized. Their spectra characterization and X-ray diffraction analysis have been performed. It is found that this kind of complexes possesses an electronic structure with highly extensive π- delocalization.

以N－乙烯基咔唑、苊烯及其衍生物作为配体与金属基团Cr2L(L = CO； PPh3； C3H5 BF4-)配位，合成了一系金属有机配合物，并对其进行了光谱表征和单晶X射线衍射分析，发现该类配合物具有高度离域的电子结构。

RCM reactions of 49 and 50 are chosen to evaluate the catalytic performance ofthe complexes 46-48 because they are informative and simple to manipulate. The resultsindicated that ruthenium benzylidene complexes 46 and 48 possess significant thermalstability and cyano group tolerance.

由于烯烃49、50的闭环交互置换反应简单、清晰，故用来考察新钌卡宾配合物的催化性能，结果表明配合物46、48具有良好的热稳定性及耐氰基性能。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了