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Hydroesterification of tert-butyl alcohol with ethanol catalyzed by transition metal triphenylphosphine complexes was first investigated in room temperature ionic liquids.

反应温度为100~140 ℃,CO初始压力为2~6 MPa条件下,研究了室温离子液体与过渡金属三苯基膦配合物构成的催化反应体系中,叔丁醇与乙醇的氢酯基化反应。

The reaction of isomerized butadieneiron complex (I; R = Ph, p-tolyl) with triphenylphosphine and tri-Ph phosphite gave products II (same R; R1 = Ph, OPh), at -60 to -30? When I was reacted with triphenylphosphine in hexane at 60 to 70?

丁二烯二羰基铁配合物的异构化产物,C4H62FeC(OC2H5)Ar(1,Ar=苯基, 2, Ar=对甲苯基),在己烷溶液中于-60到-40℃与三苯膦或亚磷酸三苯酯反应生产产物3-6。

The research results of the seed dormancy showed, the seeds of Valeriana amurensis reached highest germination rate (82%) at the temperature treatment in alteration of 10℃ and 25℃, and soil was fertile sandy.

对黑水缬草种子休眠生理进行研究的结果显示:以沙质壤土为基质,配合(10-25-10)℃的变温条件,黑水缬草的发芽率达到最大,为82.1%;黑水缬草种子浸泡液、粗提液以及乙醚浸提液均对黑水缬草的发芽率有抑制作用。

Chows objective is supplies best quality products, fully support by our strong engineer team and our continually technical improvement, we target to satisfy all customer's needs with ourprofessionalservices and high quality products in each order

着重产品的质量是我们振基一贯的宗旨,配合本公司科研及技术支持,确保每一批售出的产品均能使客户满意。

The results of the TG and DTG curves show that, in the whole intumescing process, APP, PER and MEL cooperate with each other and synergism is generated; The kind of base resin and its contents, the ratio of the component of fire retardant system and their contents all have great influence on the thermal degradation behaviors of fire retardant coating; The concentration of oxygen has no influence on the thermal degradation of fire retardant coating below 345℃, while the influence can not be neglected above 345℃, but compare with the factors mentioned previously, the influence is small.

研究表明,聚磷酸铵-三聚氰胺-季戊四醇三者能密切配合,对阻燃起到协同作用;基料树脂的种类及含量、阻燃体系配比及含量对防火涂料的热分解行为有较大的影响;氧气浓度在低温阶段(345℃以前)对热解行为几乎没影响,而在高温阶段(345℃以后)则对热解行为有影响,但相对于前面的因素对热解的影响来说,氧气浓度对防火涂料的热解行为影响较小。

A new complex, [(C6H6N2O)2Co(H2O)2] Br2 was prepared from picolinamide, Co(NO3)2 and benzyl bromide, and characterized by X-ray diffraction.

用皮考林酰胺、六水合硝酸钴和苄基溴反应制得一种新配合物[(C6H6N2O)2Co(H2O)2]Br2,通过红外光谱、元素分析及X射线晶体衍射对化合物进行了表征。

Secondly, the syntheses of functionalized macrocyclic polyamine complexes containing nucleobases, PNA monomer, imidazolium side, crown ether, ferrocenyl side and their interaction with DNA were studies, respectively.

在功能化大环多胺方面,我们合成了含有碱基、PNA单体、咪唑鎓盐、冠醚、二茂铁等功能化基团的大环多胺衍生物及金属配合物,并研究了其与DNA的相互作用。

The complexes have been characterized by IR spectrum , UV spectrum and X-ray diffraction.

铜的氨基酸配合物具有催化超氧阴离子自由基O_2~

It was observed that not only histidine, but also histidine-Co and histidine-Ni could induce and substitute some Cu and Zn from Cu_2Zn_2SOD, eventually influence the activity of this metalloenzyme. Histidine- metal ion complexes have stronger ability than histidine to displace the bound metal ion from SOD. In addition, the amount of foreign metal ion binding to the SOD was less than that of metal ion lost from SOD. It obviously means that there was apoenzyme in the solution.

实验结果表明: Cu2Zn2SOD酶不仅与组氨酸,而且还可以与组氨酸-CoⅡ)和组氨酸-Ni(Ⅱ相互作用,Cu2Zn2SOD酶中的部分Cu和Zn被诱导和置换出来,并相应地影响了酶的活性;组氨酸-金属离子配合物的作用比组氨酸强,酶活性降低也更明显;酶中结合的外来金属离子的量比从酶上被诱导和顶替下来的金属离子的量要少,说明在溶液中有脱辅基酶的存在。

With the help of recommended abrasives and techniques, through the process of heating – roughly hot rolling – precisely hot rolling in a variety a machines, hot rolls can be shaped into high-precision aluminium belts, which shall better meet the growing needs of the PS baseboards for pots and the simifinished aluminium foil sheets, for there is a big market gap and high grade request for high-precision aluminium belts in the market.

三、建设规模:年产40万吨高精度铝板带热轧卷;工艺技术:采用国际先进的热轧生产技术,由铸锭经加热—热粗轧—多机架热精轧的生产工艺,配合引进的工艺技术磨具可满足制罐料 PS 板基、双零铝箔坯料等市场缺口大的高精度铝板带产品对热轧卷的质量要求;主要设备:包括铸锭铣床一台、推进式加热炉3台、2400mm1+4热连轧生产线一条、轧辊磨床2台(国外引进1台),预计引进设备需用外汇8000万美元。

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