配合基

Reaction of NaOAr, SmCl_3 and aryloxo-functional N-heterocyclic carbene precursor [HO-4, 6-di-~tBu-C_6H_2-2-CH_2{CHMe}]Cl in 4:1:1 molar ratio in THF in one-pot hadnt afforded an anionic phenoxide complex of samarium (5) supported by a bridged bisphenoxo through the cleavage of aryloxo-functional N-heterocyclic carbenes.

4将NaOAr、SmCl_3和[HO-4，6-di-~tBu-C_6H_2-2-CH_2{CHMe}]Cl以4∶1∶1摩尔比，采用一锅煮的方法，希望得到芳氧基功能化的氮杂环卡宾稀土芳氧配合物没有取得成功，而是得到了断裂的产物O-4，6-di-~tBu-C_6H_2-2-[CH{NNMe}[(O-4，6-di-~tBu-C_6H_2)_2CH_2][O-2，4-di-~tBu-C_6H_3]Sm(5)。

Studies on the reactions of isomerized products of butaduene and isoprene iron complexes with triphenyl phosphine and triphenyl phosphite

丁二烯-和异戊二烯二羰基铁配合物的异构化产物与三苯膦和亚磷酸三苯酯的反应研究

Mn-complexes in which Mn atom ligand with the N atom within ligand can stimulate the recovery of electron transfer and oxygen evolution. The trinuclear Mn-complex is extremely sensitive to the addition of CaCl2. It is suggested that there is an interaction between Ca2 and carboxyl within the trinuclear Mn-complex during photoactivation and this interaction benefits the ligation of Mn atom to the apo-WOC and form an active WOC. Binuclear MnMn complex shows slightly higher efficiency than binuclear MnMn complex in restoration of O2 evolution activity. It is suggested from our results that recovery of electron transport and O2 evolution with synthetic Mn-complexes is affected by different factors. Cl- can stimulate the reconstitution of WOC at the concentration of over 100mM;the maximal recovery of O2 evolution activity requires the presence of CaCl2 and 33 kDa protein polypeptide together. Bicarbonate can stimulate the reconstitution of WOC.

锰配合物中锰原子与配体中的氮原子配位连接时，能显著恢复电子传递活性和放氧活性；三核锰化合物在重组时对CaCl2的存在非常敏感，我们认为Ca2 与三核锰化合物中的羧基之间存在一定的相互作用，而这种作用有助于锰原子的光配位进而使三核锰化合物易于组装成有活性的水氧化复合物：双核锰化合物MnMn比双核锰化合物MnMn在恢复放氧活性方面更有效；影响锰化合物电子传递能力恢复的因素与影响锰化合物放氧活性恢复的因素不同；在锰蔟重组过程中，氯离子的浓度必须在100mM以上，才能有效进行光重组；最大光重组效率的获得必须有钙离子和33kDa多肽同时存在；碳酸氢根离子促进锰化合物与去锰光系统II的光组装。

Two ligands L~Ⅵand L~Ⅶhave been designedand synthesized containing different terminal groups and using benzo-12-crown-4 as theskeleton, and their 18 rare earth nitrate and picrate complexes also have been synthesizedand characterized.

第二章：以五种不同种类水杨酰胺为功能末端基设计合成出以苯并-15-冠-5为骨架的配体L~Ⅰ～L~Ⅴ，并合成了其稀土硝酸盐和苦味酸盐的10个系列共51个稀土配合物。

This molecule possesses C~2 point group symmetry. The structures of the complexes B and C are completely same.

配合物B和C具有完全相同的结构，它们是以4个苯甲酸根为桥，2个phen和2个C~6H~5COO^-为端基的中心对称双核分子，其中6个苯甲酸根的成键状态可分为3种状况。

When the tongs installs on the machine bed principal axis, the tongs install the to should have the enough match accuracy with principal axis cowgirl surface, and guarantee the gearing the stability dependable.

当夹具体在机床主轴上安装时，夹具安装基面与主轴相应表面应有足够的配合精度，并保证安装稳定可靠。

The integrated analytical results show that the novel ligand coexists in ketoform and enolform structures under the measuring conditions, the ketoform structure may change into the enolform structure during the coordination and bonds with the central ion by two O atoms of the enolized hydroxyl group of pyrazolone ring and H2O and the N atom of the imine group and the N atom containing H of benzimidazole ring by losing the proton. And the coordination number of these complexes is four.

综合各种分析结果显示：配体在测试条件下以酮式和烯醇式结构共存，配位时酮式可能转化为烯醇式结构，按去质子的方式以吡唑啉酮环羟基和H2O上的两个O原子以及亚胺基上的N原子和苯并咪唑环上的含氢N原子与中心离子成键，配合物的配位数为4。

Caution: adding aluminized tape to a punch or cavity will most likely requiring grinding the mating half respectively.

注意： 放置铝基带到冲头或凹模型腔时，冲头和凹模在配合面处都应当粗抛光。

The Eu 〓·phen was also incorporated in TiO〓 by sol-gel method, it could be found that no fluorescence quench was observed under the chosen concentration ranges and the fluorescence lifetime were longer than the pure complex.

本文中还通过溶胶凝胶法将Eu〓·phen掺入TiO〓基体中，通过荧光光谱的研究表明在所选择的掺杂范围内没有出现荧光猝灭，且荧光寿命比掺杂前的纯配合物延长。

A new method of solvent-thermal synthesis of Meso-tetra(4-carboxyphenyl) zincporphyrin complexs, using the propionic acid and the DMF as solvents and the salt of zinc, catalyst-;pyrrol,4-carboxybenzaldehyde, as reagents.

报道了用丙酸和DMF作溶剂和催化剂，直接用吡咯，4 羧基苯甲醛，锌盐合成Meso 5，10，15，20 四锌卟啉配合物的新型方法———溶剂热合成。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。