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STUDY ON THE EQUILIBRIUM AND COORDINATION COMPOUND OF IRONEXTRACTION WITH N,N-DI (1-METHYLHEPTYL)ACETAMIDE IN HYDROCHLORIC ACID

N,N-二(1-甲基庚基)乙酰胺在盐酸介质中对铁的萃取平衡及其配合物的研究-中国学术期刊网络出版总库

Anilido-imino nickel complex 1 {(C6H3Me2-2,6)N=CH-5-NO2-C6H3N (C6H3Me2-2,6)}NiBr was first synthesized, and its catalytic behavior toward polymerizations of norbornene and ethylene in the presense of methylaluminoxane were investigated in detail. The complex activated with methylaluminoxane exhibited high activities for norbornene polymerization.

首次合成了苯胺基亚胺镍配合物1{(C6H3Me2-2,6)N=CH-5-NO2-C6H3N(C6H3Me2-2,6)}NiBr,研究了其在助催化剂甲基铝氧烷的作用下对降冰片烯、乙烯的均聚以及对降冰片烯和乙烯的共聚的催化性能。

Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体,初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用,20℃和20mol%催化剂量下,获得了32.5%ee和72%收率的产物。

This study uses the soil parameter reduction coefficients to model the seismic pile responses affected by liquefied soils. One dimensional wave equation analyses were conducted for the solutions. Based on the bore-hole data and nearby seismic record, the soil parameter reduction coefficients of liquefied layers can be obtained through a pre-analysis for liquefaction potential of the site. The reduction coefficients were used to reduce the soil modulus for liquefied soils, and the lumped mass analysis is performed to obtain the free-field response of the site. The ground deformations are superimposed onto the pile elements for discrete wave equation analysis, and the non-linear pile responses can be simulated through the modified Bouc-Wen model. Thus the deformations and failure mechanism of the pile are able to investigate.

中文摘要本研究之土质参数折减系数模式,系以一维波动方程模拟地盘液化状态下之桩基础动力反应,依据现场土层钻探资料与邻近测站之地震纪录,由土壤液化潜能评估法配合日本相关规范求得液化土层之土质参数折减系数,以此系数对土壤强度模数进行折减,并使用集中质块法求取自由场之地盘液化反应,再以此为前置解作用於桩基础之波动方程求解,桩身刚度以简化之Bouc-Wen模式模拟其非线性行为,以了解液化地盘内基桩之变形行为与破坏机制。

Long-range excited energy transfer from carbazole to RE complexes was observed through static PL investigation.

通过对聚合物的荧光光谱研究,观察到从咔唑基到稀土金属配合物的长程能量转移。

Three kinds of novel N-heterocyclic carbene allyl palladium complexes (Catalyst 1, 2 and 3) were synthesized. Norbornene polymerizations were carried out using three catalysts activated with methylaluminoxane in toluene.

研究了以3种N-杂环卡宾螯合烯丙基钯配合物1、2和3为催化剂,甲苯为溶剂,甲基铝氧烷为助催化剂催化降冰片烯的聚合。

In these complexes, there are hydrogen bond reciprocity between carboxyl groups and crystal lattice water molecules.

在这些配合物中,羧基氧、配位水分子和晶格水分子之间存在大量的氢键相互作用。

The hydrolysis of phosphodiester promoted by dinuclear complexes Cu (Ⅱ-Cu and Co -Co bearing special functional oxime group has been studied.

探讨了含特殊功能基肟基的双核Cu(Ⅱ-Cu及Co-Co配合物催化磷酸二酯的水解。

Infrared, ultraviolet, and mass spectrometry Gaoxiaoyexiang tests showed that benzene p rosin in neighbouring seats husband alkali metal objects with catalytic, the oxide containing hydroxy generated, ethylene, or a functional group, such as the Food oxide product.

红外、紫外、高效液相色谱和质谱测试表明,松香在邻苯二胺席夫碱金属配合物的催化下,氧化生成了含羟基、环氧基、过氧基等官能团的氧化产物。

In cooperation with the serial NSPO sounding rocket programs and application of the research results of the Institute of Aeronautics and Astronautics, National Cheng Kung University in the current proposal, we propose a series of Indigenous Propulsion Experiment payload Onboard Sounding Rockets, including: hydrazine monopropellant, hydrogen peroxide monopropellant, micro-propulsion and bipropellant subsystem.

配合NSPO推动的系列探空火箭发射计画,利用国立成功大学航太系教授过去多年研发成果,本计画拟规划一系列探空火箭酬载进行卫星推进控制系统实验与高空测试,包括:联胺单基推进、过氧化氢单基推进、微推进(micro-propulsion)、双基推进等系统,以建立自主关键技术之发展。

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