配体

Here we show that allosteric proteins can be regulated predominantly by changes in their structural dynamics.

他们出乎意料地发现，即便是当处在一个从结构上来讲没有活性的构形时，CAP也能被蛋白动态的变化所激活，以便与配体结合。

The simultaneous allosteric modulation of ligandgated ion channels by general anesthetics is entirely additive.

同时发生的全麻药对配体门控离子通道的变构调制作用完全是相加性的。

The modulation effect of Zn2+ on IATP belongs to allosteric modulation and may be achieved by changing the affinity of ligand-receptor.

结论Zn2+对ATP-激活电流调制效应可能是通过改变配体和受体的亲和力而实现的变构调制。

Advantages of specific coupling between biotin and avidin or streptavidin allow firefly luciferase to be immobilized on solid support coated with avidin or streptavidin, so that more flexible and convenient methods of luminescence assay will be available in application.

利用生物素与配体亲和素或链霉亲和素的特异性耦合，可以将荧光素酶固定到亲和素或链霉亲和素包被的磁珠上，从而使荧光检测的应用更加灵活和方便。

Thus we cooperate to study the function and mechanism of this catalyst in the asymmetric borane reduction reaction, and the following results are obtained.

于是，我们和其合作来深入研究该类配体的不对称催化机制和功能，得到了如下有意义的结果

Part Ⅰ The Research of Chiral Phosphorus Catalysts in the Enantioselective Borane Reduction of Prochiral Ketones ABSTRACT In this paper, the preparation of varied types of chiral phosphorus ligands and their applications as catalysts in the asymmetric borane reduction of prochiral ketones were investigated.

第一部分对映选择的潜手性酮的硼烷还原反应中手性磷催化剂的研究本文研究了多种不同类型的手性磷配体催化剂的合成及其在酮的不对称硼烷还原反应中的应用。

All the prepared compounds were characterized by 〓H NMR、〓P NMR and elemental analysis. The catalytic activity of each prepared chiral phosphorus compound in the borane reduction of prochiral ketones was studied.

对每一种手性磷化合物，考察了其作为配体催化剂在潜手性酮的不对称硼烷还原反应中的催化效果，讨论了影响不对称诱导的各种因素。

In the reduction of 1, 6-diphenyl-1, 6-hexanedione catalyzed by the bis-squaryl proline, good enantioselectivities were obtained, the ee values were up to 90%.We also studied the asymmetric borane reduction of prochiral ketone catalyzed by a series of thiazolidine ligands.

本文考察了由L-半胱氨酸衍生的2-位无取代基的以及2-位芳基取代的噻唑烷酸及醇配体在前手性酮的不对称还原反应中的催化性能。

The Aphos-Pd_2 system was proved very efficient for the coupling of alkyl boranes and the results are collected in Chapter 4.At the temperature of 50℃,a variety of aryl chlorides successfully coupled with alkyl boranes as well.

该类型配体对烷基硼试剂与溴代芳烃和烯烃的Suzuki偶联反应有着很好的效果，并且被成功地用于一系列氯代芳烃的反应，但反应温度为50℃。

Fluorimetric determination of traces of europium using a new chelator and acetate or phosphate in dimethylsulfoxide as enhancers.

论文合成了一种开链大环有机配体的稀土及稀土金属配合物及其作为分子功能材料的理论和应用研究。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。