配体

Expanding pinacol reductive coupling reaction into asymmetric one with both diastereoselectivity and enantioselectivity may lead to its application in synthesising medicaments and biologic active compounds with structure of vicinal diol. Asymmetric pinacol coupling reaction is also the most compact and effecient method in synthesizing chiral ligands or chiral auxiliary with C〓 symmetry.

将这一反应发展成为既有高度的非对映选择性，又有高度对映选择性的不对称偶联反应在合成许多含有手性邻二醇结构的药物或生物活性物质将有更重要的应用，同时不对称Piancol偶联反应也是合成C〓对称性的邻二醇多用途手性配体或手性助剂的最为简捷有效的方法。

This work is mainly concerned with molecular magnetism of polynuclear complexes and supramolecular crystal engineering.

本论文围绕多核配合物的分子磁学和超分子晶体工程这两个最为活跃的前沿研究领域，选用大环配体tacn（1，4，7-三氮杂环壬烷）和含有外延桥的双草胺。。。

This thesis mainly focuses on overcoming the substrates limition of the present catalytic systems,low catalytic efficiency,and application in total synthesis.1.Conveniently synthesized sulfonamide alcohol titanium complex has been used to catalyze the asymmetric addtition of methyl propiolate to various aromatic and aliphatic aldehydes with high enantioselectivity.

本论文即针对现有催化体系的底物局限性、催化效率低、应用研究少等展开研究：1、我们将简便合成的磺酰胺基醇配体-钛催化体系应用于催化丙炔酸甲酯对各类芳香醛及脂肪醛的不对称加成取得了理想的结果。

This dissertation involves the syntheses, reactivities and structures ofGroup 6 metal carbonyl complexes containing the pyrazole ligands.

本论文开展了对含吡唑类配体的VIB金属羰基配合物的合成、反应及结构的研究，合成了70余个新化合物，并取得了如下研究成果。

However, three isomers are obtained when [3(5)-〓-5(3)-MeS]pyrazole or[3(5)--5(3)-MeS]pyrazole reacts with 〓 in the same conditionpossibly owing to the influence of both the steric and electronic factors.

通过配体与〓的光化学反应，首次分离得到了不对称取代的双吡唑烷VIB金属配合物，但3位取代基的立体位阻减弱了双吡唑烷与〓的反应。

The results show thatthe substitutions containing sulfur atom in the pyrazole ring remarkably affectthe steric and electronic properties of the pyrazole ligands.

因此，我们研究了吡唑环上带上S原子取代基对形成双吡唑烷配体及其与VIB金属羰基配合物的光化学反应的影响。

Two new binuclear complexes, [TpCu(μ-1, 1-N3)2CuTp](1) and [Tp(superscript *)Co2CoTp(superscript *)](2) Tp=tri (pyrazolyl borate and Tp(superscript *)=3,5-dimethyltri borate, have been synthesized and characterized by IR, UV-vis, ESR, and CV. The crystal structures of both complexes have been determined by X-ray single crystal diffraction.

合成了两个新型的含三吡唑硼配体的双核铜配合物[TpCu(μ-1， 1-N3)2CuTp](1)和双核钴配合物[TpCo2CoTp](2)，并通过IR，UV-vis，EPR，CV，X-射线单晶衍射等手段进行表征。

A novel mixed ligands sandwich copper complex with hydrotris borate and bihydrobis borate ligands Tp: hydrotris (pyrazolyl borate; Bp: bihydrobis borate was synthesized.

合成了一种新型Ⅱ三吡唑硼酸根和二吡唑硼酸根混合配体的&三明治&型铜配合物（Tp：三吡唑硼酸根，hydrotris borate；Bp：二吡唑硼酸根，bihydrobis borate）。

A liquid crystal with pyridine group was synthesized from reactants of pyrogallic acid and isonicotinato by esterification reaction.

以焦性没食子酸和异烟酸为原料合成了带吡啶官能团的液晶配体。

On the base of structure and constitute analysis of organic chromium of nicotinate chromium and 〓, which all have evidently biological function, it reports the preparation of the first type of four kinds new organic chromium complexes . H〓O,. H〓O,,, in which Salen schiff base ligand and nicotinate or isonicotinate, or pyromucate, or benzoate ligand are contained simultaneously.

根据具有明显生物学功能的有机铬——烟酸铬和〓配合物的组成及结构特征，合成了第一类四种含有希夫碱Salen配体和烟酸、异烟酸、呋喃甲酸和苯甲酸的有机铬，其组成分别为。H〓O，。H〓O，，。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。