配体

New flexible ligand derived from this achiral biphenylbackbone was applied in Cu-catalyzed enantioselective 1,4-conjugate additionsof Et_2Zn to chalcone.

进一步衍生得到的非手性联苯型P，N 配体，在Cu催化Et_2Zn对查耳酮的1，4-共轭加成反应中也进行了考察。

In the Cu-catalyzed enantioselective 1,4-conjugate addition of diethylzinc to acyclic enones, the reaction conditions, such as the amount of diethylzinc, solvents, temperature and the reaction time, were investigated in detail with 9a as the standard ligand and chalcone as the typical substrate.

考察了Et_2Zn量、溶剂、反应温度和反应时间等因素对反应的影响，得到了配体与Cu的摩尔比为2.5、1.5倍Et_2Zn用量、甲苯为反应溶剂、-20℃下反应6小时为不对称催化1，4-共轭加成的优化反应条件。

So the key of asymmetric reaction is design and synthesis of the chiral ligands.

因此，手性催化反应的关键是手性配体的设计与合成。

With ethyl cinnamic as substrate of the AD reaction, the recovered ligand 1 and 2 was reused in 'BuOH-H2O (1:1) system.

产物 的光学纯度为98%，产率为39%。反应结束后，可以通过加少量乙醚，沉淀回收配体。

Results The complexes with larger conjugative planar areas, lower energy differences △ε(subscript L/H) between LUMOs and HOMOs were advantageous to improve their DNA-binding affinities, thereby, increase the antitumor activities of complexes.

结果 具有较大面积的插入配体，及较低的HOMO与LUMO轨道能量间隙△ε(下标 L-H有利于配合物与DNA的作用，从而增加配合物的抗肿瘤活性。

Using pyridine-2, 6-dicarboxylic acid as starting material, a novel ligand N^2, N^6-bis(3-methyl-pyridine-2-yl)-pyridine-2, 6-dicarboxamide was synthesized, which contained multidentate and large conjugative system.

以吡啶－2，6-二甲酸为原料，合成含有多个共轭体系多齿配体N^2，N^6-二（3-甲基吡啶）－2-取代吡啶－2，6-二甲酰胺；同时制备它与稀土离子Tb和Eu的配合物，并培养出单晶。

As to the catalytic coupling of aryl bromides, when triphenylphosphine as ligand and malononitrile as subtracts, their isolated yields were generally in 72-88%; While using cyanoacetate instead of malononitrile, the yields were in 67-84%.

当采用常见的三苯基膦为配体、对取代溴苯而言，以丙二腈为底物时，偶联产物的分离产率一般都在72-88％之间；以腈基乙酸乙酯为底物时，分离产率在67-84％之间。

In addition to cyclopropanation, the typical Diels-Alder reaction between cyclopentadiene and N-acryloyl-l,3-oxazolidinine-2-one with Ll-L8/metal complexes have also been studied.

对于新配体在Diels-Alder反应中的对映选择性的研究，我们采用环戊二烯与3-丙烯酰基-2-噁唑啉酮的反应。

PPARγ plays an imporlant role in the modulaltion of thophoblst invasion. PPARγ ligands can inhibit invasion through down-regulating MMP-2 and MMP-9 expressions, these provide experiment basement for deeply investigation of PPARγ ligands in the mechanism of cytotrophoblast invasion.

PPARγ在调节滋养细胞浸润过程中起重要作用，而且其作用可能是通过调节MMP-2和MMP-9的表达实现的，为深入探讨PPARγ及其配体在滋养细胞浸润机制中的作用提供实验基础。

The Schiff base transitional metal complexes of various structures and their metallomicelles as peroxidase models for the phenol and phenolic derivant oxidation have been investigated. Some results are obtained from the studies:(1) the Schiff base transitional metal complexes have high catalytic activity for the phenol and phenolic derivant oxidation, and the structure of the complexes has a great effect on its catalytic activity;(2)a novel kinetic mathematical model for the complexes and their metallomicelles catalyzing the phenolic derivant oxidation has been established;(3) the feasibility and mechanism for the phenolic derivant oxidation catalyzed by the metallomicelle(as the mimetic model of peroxidase)have been discussed.

研究了冠醚Schiff碱金属配合物作为过氧化物酶的模拟模型对酚类物质氧化反应的催化作用，取得如下结果：(1)几种冠醚Schiff碱金属配合物对催化酚类物质氧化具有良好的催化活性，其中配体结构对其催化活性有较大的影响；(2)建立了金属配合物与表面活性剂形成的金属胶束催化酚类物质氧化反应的动力学数学模型；(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。