配体

Chapter VI: Nineteen novel ligands containg triazole and benzotriazole are designed and synthesized. Although we did not get the single crystal of complexes, we get five single crystals of compounds and test the biological activity of all the compounds.

第六章：设计、合成并表征了两个系列共19个新型的三氮唑配体，虽然没有得到配合物的单晶，但是我们得到了其中5个化合物的单晶，并初步测试了所有化合物的生物活性。

It was also shown that the free OH in the ligand was very important in selective control by hydrogen bonding to the benzylamine.

主要原因是配体中 BINOL 羟基由于会和苄胺形成分子内氢键而对反应的选择性起到了关键作用。

Lithium complexes 1b,1d and Zirconium complexes 1c,1e,lf were prepared using the benzylamine ligand. X-ray crystal structures of these complexes were determined.

合成了一种新型的硅桥联的多齿胺类配体[PhNHSi(NMe_2)NHPh]，在此基础上研究了其对应的碱金属化合物和过渡金属锆的络合物的制备，并进行它们的X-射线晶体结构的分析。

Three kinds of small molecular copper and zinc superoxide dismutase mimics were synthesized with N, N-bis (benzimidazol-2-ylmethyl) amine (N3), N, N-bis (benzimidazol-2-ylmethyl) methylamine(MN3) and N,N-bis (benzimidazol-2-ylmethyl) benzylamine(BN3) as ligands. The com-plexes were characterized by UV, IR and element analysis and the structures were proposed.

模拟铜一锌超氧化物歧化酶的活性中心，以二(2-苯并咪唑)丙烷为桥、二(2-苯并咪唑亚甲基)胺(N3)、二(2-苯并咪唑亚甲基)甲胺(MN3)及二(2-苯并咪唑亚甲基)苄胺(BN3)为配体合成了3种异双核的小分子模型化合物，并进行了紫外、红外表征及元素分析，推测了可能的结构。

Saccharin,as ligand in crystal,may be existed intypes of monodentate,bidentate,bridge and free anion.

对于糖精作为配体，在晶体中可以以单齿、双齿、桥联、自由阴离子等多种方式存在。

Because the solubility of the complex monomers is very important for polymerization, the bidentate ancillary ligand of the bicycloiridium complexes also has an effect on the luminous properties of the chelating polymer.

实验证明了在这类电磷光聚合物中配合物单元辅助配体合理的分子设计，可以提高配合物单体的溶解度，提高聚合物的分子量和发光性能。

Starting from 2-naphthylamine,2,2′-diamino-1,1′-binaphthyl was obtained via oxidation,coupling reaction and rearrangement.

&配体催化合成&是有机化学研究领域中的前沿和热点，它是化学领域的一门交叉学科。

Much better asymmetric induction was obtained with the catalysis of Ag /MAPs than with Ag /H〓-MAPs, and the binaphthyl backbone of R configuration was found to match to the S, S pyrrolidino group.

含有中心手性和轴手性两种手性因素的氮膦配体中，轴手性为R构型时，和中心手性S，S构型相匹配。

The asymmetric polymerization of methyl methacrylate is carried out using the chiral binaphthyl crown ether macrocyclic compounds binding n-BuLi or t-BuOK as chiral initiator at -78℃.

以手性联萘冠醚为配体，络合n-BuLi，t-BuOK等有机金属化合物形成手性引发剂体系，初步探讨了甲基丙烯酸甲酯单体的聚合反应。

Starting from 3, 5-dihydroxybenzoic acid, a total of 16 kinds of salicylicaldehyde derivatives have been synthesized by the esterification, substitution, reduction, formylation, condensation, brominate, functional group protection and deprotection reactions, of which 11 have not been reported yet. Enatiomerically pure 2-amino-2'-hydroxy-1, 1'-binaphthyl has been easily obtained from its racemic mixture by the eantioselective formation of inclusion crystals with N-benzylcinchoninium chloride.

树枝状大分子希夫碱三齿手性配体的设计与合成从3，5-二羟基苯甲酸出发，通过酯化、取代、还原、甲酰化、缩合、官能团的保护与去保护等反应合成了四个系列16种水杨醛衍生物，其中11中是未见文献报道的新化合物。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。