配体

The interaction between CaA and Cu and influence of ethylenediaminetetraacetic acid,solvent and pH on the interaction were also studied to help elucidate the detailed prooxidant mechanism using UV-visible spectroscopy, demonstrating that it is CaA phenolate anion,instead of the parent molecule,chelates with Cu as a bidentate ligand,hence facilitating intramolecular electron transfer between CaA and Cu.

可见分光光度计研究了CaA和Cu的相互作用以及EDTA、溶剂、pH对这种相互作用的影响，证实了CaA本身没有与Cu螯合，而是咖啡酸酚氧负离子作为双齿配体与Cu进行螯合，形成的络合物有利于分子内电子转移。

1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.

1.1 为了模拟酪酸铁酶活性中心，设计并合成了含有酚羟基和苯骈咪唑基四齿配体N，N-(2-羟基苯)-N，N-二氨，并合成它的铁配合物：Fe〓、Fe〓〓(2)和Fe〓，并经各种谱学手段表征了这些铁配合物。

For most of tertiary phosphine ligands, the coupling yields of bromobenzene can reach to about 90%.

对大多数的叔膦配体，溴苯的偶合产物的产率均可达到约90％。

We designed and synthesized a new type of chiral phosphine ligand 32 with rigidity skeleton.

另外，还构建了一种结构新颖，具有刚性骨架的手性双膦配体32。

It is shown from both the electronic and stereo structural analyses, that PDBP is a superior coordinate ligand as compared with TPP, which was employed in the rhodium/phosphonium catalyst for the hydroformylation reaction.

采用元素分析、红外、核磁等方法，对其结构进行了表征，并将PDBP用于丙烯氢甲酰化反应的催化剂配体。

NMR and ESI-MS techniques were used to study the interactions between diperoxovanadates and small organic molecules such as pyridine, imidazole, arginine, picoline ester, and picoline amide. Spectroscopic methods were established to explore this type of interactions.

在合成数种双过氧钒化合物的基础上，利用多种NMR技术结合ESI-MS等谱学方法系统研究了双过氧钒化合物和咪唑、吡啶、取代吡啶、精氨酸、皮考啉酯以及皮考啉酰胺等有机配体的相互作用，建立了一套适合研究过氧钒化合物与有机小分子相互作用的谱学方法。

81 Was prepared by the reaction of tris2-(salicylideneiminoethyl amine with zinc picrate [Zn2] in ethanol.

在不加任何碱的条件下，三[2-乙基]胺与苦味酸锌[Zn26H2O]在乙醇中反应，得到了较为少见的多胺单缩合西夫碱配体的配合物[ZnN(CH2CH2NH2)2(CH2CH2N=CH-C6H4O)]Pic。

Two ligands L~Ⅵand L~Ⅶhave been designedand synthesized containing different terminal groups and using benzo-12-crown-4 as theskeleton, and their 18 rare earth nitrate and picrate complexes also have been synthesizedand characterized.

第二章：以五种不同种类水杨酰胺为功能末端基设计合成出以苯并-15-冠-5为骨架的配体L~Ⅰ～L~Ⅴ，并合成了其稀土硝酸盐和苦味酸盐的10个系列共51个稀土配合物。

By using radioactive ligand receptor binding assay and observing animal activities, this paper reports the effects of convulsants of picrotoxin, penicillin and kainic acid on the 3H GABA A binding in the cerebral cortex, hippocampus and cerebellum of mice.

采用放射配体受体结合分析法和动物行为观察，研究了致惊药印防己毒素(picrotoxin ，Pic)、青霉素(Penicillin ，PG)、红藻氨酸(kainicacid ，KA)对小白鼠大脑皮层、海马、小脑三脑区3 H GABA与GABAA 受体结合的影响。

Among which, the ligands with a so-called "pincer" structure have been investigated deeply recent years with regard to their synthesis as well as their potential application in homogeneous catalysis.

其中一类具有"pincer"结构的吡啶基含氮三齿配体的合成及其在均相催化中的潜在应用，近些年得到了较深入的研究报道。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。