配体

The catalyst conditions of 1,3-propanediol were researched, such as main catalyst, accelerant , solvent, etal.

针对一步法和二步法的技术路线，考察了不同催化条件对反应结果的影响，如主催化剂、膦配体、促进剂、活化剂和溶剂等。

A series of platinum terpyridyl acetylide complexes were designed and synthesized, which exhibit 〓MLCT emission with high quantum yield and long lifetime in the fluid solution at room temperature.

本论文设计、合成了一系列炔基为辅助配体的多吡啶Pt络合物，系统地研究了它们的光物理性质，探讨了其在超分子化学中的应用，取得了一系列有意义的研究结果：一。

It is noted that the energy of MLCT excited state can be systematically tuned simply by introducing ancillary acetylide ligand.

其中以脂肪炔为辅助配体的络合物tt6～tt7发光量子产率高达0.30以上，发光寿命长达12μs，这是迄今为止，文献报道室温溶液中发光寿命最长、量子产率最高的三联吡啶Pt络合物。

The platinum terpyridyl acetylide complex containing a simple amine group in the acetylide ligand could be utilized as a chemo-sensor for detection of micromolar concentration of protons by monitoring the changes both in luminescence and color.

实验发现： 1.4-N，N-二甲基苯乙炔为辅助配体的三联吡啶Pt络合物TA在质子存在下吸收和发光变化明显，因此可以通过颜色或发光的变化检测微量质子的存在。

The absorption spectra of the terpyridyl platinum acetylide complex containing monoazacrown moiety in the acetylide ligand was blue-shifted upon complexation with metal cations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的三联吡啶Pt络合物TAC在金属离子的存在下吸收光谱的变化明显不同。

The energy of excited state depended on the nature of different cations. 3. 4-(4-tolyl)-6-phenyl-2, 2'-bipyridine platinum acetylide complex containing a monoazazcrown moiety in the acetylide ligand could signal Mg〓 specifically and displayed large changes both in color and in luminescence intensity upon complexation with Mg〓. The most striking result was that it could signal Mg〓 specifically even in the presence of alkali and alkaline earth metal ions in high concentrations.

对位带有氮杂-15-冠-5冠醚的苯乙炔为辅助配体的4-（4-甲基苯基）-6-苯基-2，2'-联吡啶Pt络合物AC，不仅在碱金属和碱土金属的存在下吸收光谱明显改变，更有意义的是，它只有在Mg〓离子存在时能够发光，因此可以通过发射光谱选择性的识别Mg〓，尤其可以在高浓度的其它金属离子存在下选择性的检出Mg〓离子。

All these observation furthers demonstrated the excited state properties of platinum polypyridyl acetylide complexes could be tuned by ancillary acetylide ligand. Proton or metal cation could be used as switch to change the order of the lowest excited state from LLCT to MLCT.

以上工作从另一角度再次证明，利用辅助配体的电子效应，能明显改善三联吡啶Pt络合物的激发态性质，其中质子或金属离子有效调节HOMO轨道的能量，实现了LLCT激发态向MLCT激发态的转换。

An electron-rich acetylide ligand would render the metal center more electron-rich and hence raise the dπ orbital energy, leading to decrease energy of the MLCT excited state.

证明通过改变乙炔基配体取代基的电子效应，能够调节最低激发态MLCT态的能量。

This paper proposes that weak acid is a coordination compound that regards hydrogen ion as "coordination body" and regards acid radical as central atom.

本文首次提出将弱酸看成是以氢离子为"配体"，以弱酸的酸根为中心"原子"所形成的"配合物"，通过计算该"配合物"的生成函数N并绘制PH－N图，用Bjerrum，N。

Adenosine Receptors Ligands: Past, Present and Future Trends.

腺苷受体的配体：过去，现在和将来发展趋势。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。