配体

With good stability and high reactivity, pyridine-based tridentate N-ligands have been widely used in the fields of coordination chemistry, organic synthesis and homogeneous catalysis.

吡啶基含氮三齿配体具有良好的稳定性和反应活性，在配位化学，有机合成和均相催化中均得到了广泛的应用。

The 〓 coordinate to silver ions as tridentate unit forming two different 12-member rings which combine to make a infinitive one-dimensional chain.

CuL〓〓作为三齿配体与银配位形成了两种不同的十二元环这些环连接成一个无限的—维链。

Tripodal ligand has rich coordination form, and the supramolecular chemistry of its copper and silver complexes is essential for creating new functional materials.

三脚架型配体有着丰富多样的配位方式，其铜、银配合物超分子结构的研究在新型材料的研制中有着重要的指导意义。

Tripodal ligand has rich coordination form, and thesupramolecular chemistry of its copper and silver complexes is essential for creatingnew functional materials.

三脚架型配体有着丰富多样的配位方式，其铜、银配合物超分子结构的研究在新型材料的研制中有着重要的指导意义。

In the last few years, the tripodal ligands bearing nitrogen atoms have drown much attention because of their polydentate, flexility and ease to synthesize.

近年来，含氮三脚架配体因其多配位点、半刚性及易合成等特点，对其稀土配合物的发光研究引起了人们的广泛兴趣。

In this paper, the stable Au complexes are classified according to the coordination atoms and their characteristic structure. The recent development of the researches on the antitumor activity of Au complexes including the structure-activity relationship, biological targets and the mechanisms of action are reviewed. The structure of the coordination ligand and the leaving group have great impact on the in vitro cytotoxicity of the Au complex. Many physical and biological methods are introduced to study the interaction between the Au complexes and the suspected bio-target, such as DNA, protein, mitochondrion, thio-containing biomolecules, etc. The interaction modes (intercalating, electrostatic interaction, covalent bonding, etc.) are focused to illustrate the reason for the antitumor activity of Au complexes.

本文按配位原子的不同总结了稳定三价金配合物的结构特征，按其生物活性的构效关系、生物靶点和作用机制综述了三价金配合物抗肿瘤活性研究的最新成果：配体的结构特点以及离去基团对三价金配合物的体外细胞毒性影响较大；介绍了用于检测三价金配合物与可能的生物靶分子之间的相互作用的多种物理和生物学方法，重点关注了相互作用的模式，如嵌入/静电吸引/共价结合等，并解释了三价金配合物抗肿瘤活性的原因。

In this paper, the stable Au complexes are classified according to the coordination atoms and their structural characteristics. The recent development of the researches on the antitumor activity of Au complexes including the structure-activity relationships, biological targets and the mechanisms of action are reviewed. The structure of the coordination ligand and the leaving group have great impact on the in vitro cytotoxicity of the Au complex. Many physical and biological methods are introduced to study the interaction between the Au complexe and the suspected bio-target, such as DNA, protein, mitochondrion, thio-containing biomolecules, etc. The interaction modes (intercalating, electrostatic interaction, covalent bonding, etc.) are focused to illustrate the reason for the antitumor activity of Au complexes.

本文按配位原子的不同总结了稳定三价金配合物的结构特征，按其生物活性的构效关系、生物靶点和作用机制综述了三价金配合物抗肿瘤活性研究的最新成果：配体的结构特点以及离去基团对三价金配合物的体外细胞毒性影响较大；介绍了用于检测三价金配合物与可能的生物靶分子之间相互作用的多种物理和生物学方法，重点关注了相互作用的模式，如嵌入/静电吸引/共价结合等，并解释了三价金配合物抗肿瘤活性的原因。

The mechanism of co-fluorescence effect has been discussed. In chapter six, the new fluorescence enhancement phenomenon was observed by adding some crown ethers to samarium-thenoyltrifluoroacetone system.

在第六章中，研究发现当向钐-噻吩甲酰三氟丙酮中加入配位能力很强的大环配体冠醚时，冠醚对稀土有机配合物体系产生显著的荧光增强作用，其中冠醚二苯并18冠6后（DB18C6）可使钐-TTA二元配合物体系荧光强度增强280倍。

The ligands donate the lone pair electrons to the central metal to form the covalent bondings, called coordination bondings.

配体提供原子对与金属原子形成的共价键称为配位键。

Oxazaborolidine, which derive from the coordination of amino alcohol and borane, are good catalysts for the borane reduction reaction. A kind of fused cyclic oxazaborolidine invented by Corey and derived from proline has been successfully used in the production of MK-0417 as excellent chiral catalyst by Merck company.

在该反应中氨基醇类配体原位与硼烷配位形成的手性恶唑硼烷是该反应的良好催化剂，其中Corey等发明的由脯氨酸出发制备的稠环手性催化剂性能优异，已经在Merck公司生产碳酸酐酶抑制剂MK-0417中得到成功应用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。