配体

In the paper, the multidentate carboxylic acid ligands were used to combine with Cd, resulting in the three dimensional MOCPs single crystals—C12H16CdN2O8, with a low temperature hydrothermal synthesis method. The sample was characterized with IR spectra to affirm the organic groups in the frameworks, single-crystal X-ray diffraction to determine the crystal structure and composition of the frameworks, N2 adsorption isotherms at low temperature to measure the specific surface area and pore size distribution, and with TGA/DGA analysis to scale the thermal stability. Furthermore, the dissolution property and the photocatalytic activity of MOCPs under the ultraviolet ray condition were explored.

本文用低温水热合成法，用多齿羧酸配体异烟酸和Cd配位合成出[Cd(C6H4O2N)2(H2O)4]∞三维晶体并进行了表征：采用红外光谱法确认骨架中的有机官能团；用单晶X射线衍射分析法测定MOCPs的晶体结构，并确定其骨架的组成；通过低温氮气吸附等温线测定了其比表面积和孔径分布；以热重分析和差热分析测定材料骨架的热稳定性；测定了晶体的溶解性能；最后以亚甲基蓝为目标降解物，对[Cd(C6H4O2N)2(H2O)4]∞的光催化活性及亚甲基蓝的氧化动力学进行了探索(来源：A2444BC论文网www.abclunwen.com)。

There have been a few studies on the coordination behavior of these metals in both aqueous and nonaqueous media.

组装的原理是通过共价键和分子间力在刚性配体的支持下将构件连接成配位聚合物。

The structure of the compound 〓(1) consists of a pentanuclear molecule which is center-symmetric. One W atom is coordinated by four S atoms and two Cu atom. As expected, the Fe atoms are sandwiched between two staggered pentadiene rings. The most interesting aspect of the structure is that Fe-C-P-Cu-P-Cconstitutes a distorted hexagon and Fe-Cu-W-Cu-Fe is nearly in a line.

结构是以W原子为对称中心含有五个金属原子的线型结构，W原子与四个μ〓-S和两个Cu原子配位；Fe原子在两个戊二烯环中间形成一个三明治夹心结构；Fe〓-C〓-P〓-Cu〓-P〓-C〓-构成扭曲的六边形，由于两边1，1'-双二茂铁配体的作用导致Cu-S键的拉长。

The conductive coordinative polymolecular compounds,which contain thetransition metal ions〓and〓as central metal ions,transition metal ionsor rare earth ions as counter cations and〓or〓as ligand,have been synthesized.

合成出以过渡金属〓、〓、〓、〓和〓作为中心金属离子、过渡金属或稀土离子作为抗衡阳离子、有机小分子〓或〓作为配体的导电性配位高分子化合物，它们均为能在空气中稳定存在且难溶和难熔的无定形粉末状固体。

Adjacent helical chains are racemic. The Ag atom is linked to two nitrogen atoms of the 2-pyridyl and 4'-pyridyl groups from two different 2,4'-bpy ligands as well as to the oxygen atom of the counterion. In 17 and 19, the adjacent helical chains are linked to wavy two-dimensional network structures by the nitrate counterions.

相邻的螺旋链间是外消旋的，Ag 原子与分别来自两个不同2，4'-联吡啶的2-吡啶基和4'-吡啶基的氮原子以及阴离子的氧原子配位，在配合物17和19中，相邻聚合螺旋链被硝酸根离子桥连接起来，变成了一个波浪形的二维网络结构；配合物18是首次通过无桥连配体支持的Ag ××× Ag键将相邻螺旋链连接成二维非穿插的网络结构。

Synthesis and characterization of tridentate chiral ligands, a series of Schiff-bases which are synthesized by salicylaldehyde, 2-pyridinecarboxaldehyde and amino alcohols derived from the amino acids without coordination group on side chain.

由侧链不带配位基团的天然氨基酸合成的氨基醇与水杨醛及2-吡啶醛缩合的Schiff-Base等三齿配体的合成与结构分析。

Five bistin Schiff base complexes were synthesized by the reaction of bistin dichloride with Schiff base derived from amino acids and salicylaldehyde in the presence of triethylamine,and were characterized by IR,1HNMR and MS.

二烃基锡配合物的结构类型及其具有较强的抗癌活性引起了人们极大的兴趣。大量的研究表明，有机锡化合物的生物活性主要取决于烃基，但配位基团也有一定的影响[1-3]，尤其在水解、输送等过程中。某些配体对生物活性的发挥还有协同作用。

Therefore, we characterized the Cyt c P71H/M80V variant protein electrochemically and spectroscopically. All the experimental results showed that the introduced histidine at position 71 did not act as a functional distal-histidine, but most likely coordinated to the heme iron, maybe due to the flexibility of theΩloop segment (resides 70-84) of Cyt c protein.

于是我们对P71H／M80V蛋白性质进行了一系列的研究，结果表明可能是由于Cyt c中Ωloop D肽段(residues 70-84)具有很强的柔韧性，使得His71并没有象HRP中的distal histidine一样起到酸碱催化功能，而是与heme发生了配位作用，无论是在氧化态还是还原态都成了heme的第六轴向配体。

Finally, two tetranuclear Cu~(2+) complexes were constructed from a new salen ligand with alkoxo groups. The two complexes were obtained by the reaction of the same ligand with Cu~(2+) in different solvents, i.e., a stage tetranuclear complex and a pseudo-cubane tetranuclear complex in MeOH and THF, respectively.

最后，本文以Schiff碱类过渡金属配合物发展应用为研究背景，设计并合成了一种新型Schiff碱及其两种构型的Cu金属配合物，发现所设计的具有和三个Schiff碱配体，与Cu_2在不同的反应溶剂中进行配位反应时，可以得到不同结构的配合物。

Three new Cu〓 complexes with quinoline-based new monothioether ligands have been synthesized and characterized, and they take tetranuclear, 1D and 2D structures.

发现三个配合物中都存在Cu…Cu相互作用，皆含有扭椅式的Cu〓I〓骨架，配体倾向于两种模式与Cu〓配位。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。