配体

, 80g/l HPZ-Ti solution can be stored stably for more than one year at atmospheric temperature (the highest temp. is 35℃), the precipitation point pH of 0.05M HPZ-Ti solution exceeds 4. 6, the stability can meet the tannage need. The tanning power of HPZ-Ti tanning liquor is better than that of any other titaninum tanning liquors which have been researched.

与钛配位能力适中，在革内有较好的渗透性，HPZ—Ti配合物与胶原有较大的反应活性，HPZ与Ti以0.45mol HPZ/mol Ti比例混和，浓度为80g/l时，在室温下（最高温度35℃）可稳定存放一年以上，浑浊点pH值达4.60以上，其鞣性优于其它配体蒙囿的钛溶液和其它方法制备的钛鞣剂。

By virtue of the coordination of Cr2L (L = CO; PPh3; C3H5 BF4-) with N-vinylcarbazole, acenaphthylene and their derivatives as organic ligands, a series of organometallic complexes have been synthesized. Their spectra characterization and X-ray diffraction analysis have been performed. It is found that this kind of complexes possesses an electronic structure with highly extensive π- delocalization.

以N－乙烯基咔唑、苊烯及其衍生物作为配体与金属基团Cr2L(L = CO； PPh3； C3H5 BF4-)配位，合成了一系金属有机配合物，并对其进行了光谱表征和单晶X射线衍射分析，发现该类配合物具有高度离域的电子结构。

These possible mechanisms for the synthetic reaction and thesubstitution reaction of α-hyperiodine group arsonium ylides were proposed.

将它与亲核试剂作用；产生α-硒代或α-硫代胂叶立德，提出了先配位后配体偶联的可能反应机理。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

The invention pertains to the field of chemical technology, which more particularly relates to a catalyst preparation method of Polystyrene by coordinating an type of bidentate ligand and a transition metal.

本发明属于化工技术领域，具体涉及一类型双齿配体与过渡金属配位的催化剂制备聚苯乙烯方法。

We introduce two pyridinedicarboxylate (2,5-H2pdc and 2,6-H2pdc) ligands, under hydrothermal or solvothermal condition, to yield 7 complexes with InCl3. Complex 17 presents a rare example of chiral binodal (4,8)-connected lattice with self-interpenetration.

选择了两种吡啶二羧酸配体： 2，5-吡啶二羧酸(2，5-H2pdc)； 2，6-吡啶二羧酸(2，6-H2pdc)和InCl3反应合成了七个配位化合物其中17表现了一例少有的手性的(4，8)连接的双节点自穿插拓扑结构。

The exo-cyclic tin atoms are five-coordinate and have coordination geometry of monocapped trigonal bipyramid with very similarly distorted mode.

有关该类化合物的晶体结构研究表明，中心锡原子的配位形式决定于直接与锡原子相连的烃基的结构和羧酸基配体的类型[8～ 10 ] 。

In the crystal, the tin atoms are five-coordinated in trigonal bipyramidal structure by bridging pyridine N atoms, resulting in the chain organotin compound.

该化合物中心锡原子为五配位三角双锥构型，并且通过4-吡啶甲酸配体的氮原子桥联作用形成一维无限链状结构。

Under the instruction of above-mentioned theoretical results, in the thesis chapter 10, the strongly electron-withdrawing anion, C_5O_5~(2-)[dianion of croconic acid (4,5-dihydroxycyclopent-4- ene-1,2,3-trione)], was chosen as the chelator to coordinate with boron to form lithium salt, which will yield high ionic conductivity solutions, and exhibit wide electrochemical stability windows and high thermal stability. As described in the chapter, two new lithium salts containing C_5O_5~(2-), lithium bisborate and its novel derivative, lithium borate for Li-ion battery electrolytes were synthesized.

在上述理论结果的指导下，论文第十章选择了克酮酸二价阴离子——具有很强的酸性、较好的芳香性、较大的电荷分散性、形成的配合阴离子具有较显著的共轭性——作为配体与B配位，合成了二种新的锂盐，通过实验测定了它们的结构和在有机溶剂中的溶解性。

The metalorganic complex NaEu4 is prepared by europium and Dibenzoyl Methane. The coordination polymers Eu-DBM-PAA and NaEu-DBM-PSAA are synthesized by the reaction of NaEu4 with polyacrylic acid M(subscript r=5000and copolymer of acrylic acid and styrene M(subscript r=3000.

研究了铕和二苯甲醯甲烷形成的有机配体NaEu4与聚丙烯酸M(下标 r=5000）、聚M(下标 r=3000发生配位反应分别得到配合物Eu-DBM-PAA和NaEu-DBM-PSAA，得率分别为89.7%和87.3%。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。