配体

In addtion, the β-diketone compound of Ti is complexed with late transition metal Co, Ni complex to furtherly modify the catalytic ability of the catalyst system.

利用配位配体来调节催化剂的催化性能是烯烃聚合催化剂设计和合成的基本思路和重要途径之一，是开发新型功能性聚烯烃材料的重要方法。

The experiment result shows that the copolymer of methyl methacrylate and crylic acid surly coordinate with europium ion.

研究结果表明，共聚物与铕发生了配位，而小分子配体的引入对配合物的荧光强度起到了加强作用。

In the fourth chapter, four new complexes of hydrazide of podophyllic acid with transition metals have been prepared. Elemental analysis, molar conductivity, IR,〓 NMR and TG-DTA were used to characterize them. The results show that general formula of the complexes is M〓(n=0 or 2). The ligand is linked through the carbonyl oxygen and the terminal nitrogen of the hydrazide base to the transition metal ions in bidentate mode.

第四章 合成了四种鬼臼酰肼的过渡金属配合物，通过元素分析、摩尔电导、红外光谱、核磁共振氢谱和热重-差热对配合物进行了表征，研究结果表明，配合物的组成为M〓（n=0或2），配体是通过羰基氧和肼基上的端氮以双齿形式与金属离子配位的。

Up to now, there are many reports about complexes of hydrazone and monohydrazidate, while fewer is reported about bihydrazidate and its complexes.

另一方面，含有多个配位原子的N-取代水杨酰肼是一种强螯合剂，是制备多核配合物的理想配体。

According to the theoretic significance and the applications of the complexes, this paper mainly concluded the following work: The ligand, 2-carboxybenzaldehyde-2,4-dinitrophen hydrazone, was synthesized by 2-carboxybenzaldehyde and 2,4-dinitrophenyl hydrazine in absolute alcohol.

中文摘要本文基于芳香腙类化合物的抑菌活性、稀土元素的生物活性以及二者配位后可能的协同效应，主要进行了以下几个方面的工作：在无水乙醇中，利用2-羧基苯甲醛和2，4-二硝基苯肼缩合反应得到了配体2-羧基苯甲醛-2，4-二硝基苯腙(C14H10N4O6)。

The X-ray structure analysis reveals that the metal is in a square-planar N2O2 coordination environment formed by the phenolate-O, the imine-N and the deprotonated amide-O atoms of hydrazone ligand and the N atom of Himdz.

配合物的晶体结构分析表明，中心金属通过酰腙配体的酚基氧原子、亚胺基氮原子、去质子酰胺氧原子以及咪唑的氮原子形成平面四方形的N2O2配位环境。

The various possible interaction between ligands in coordination compounds both intramolecular or intermolecular were also discussed.

讨论了配位化合物中配体间的各种可能的弱相互作用。

The tetraoxazoline ligands only afforded the-configuration whether monometallic and/or bimetallic palladium complexes were formed upon the complexing process. Using the chelation-induced axially chiral palladium complex as a catalyst, excellent catalytic activities and enantioselectivities in the Wacker- type cyclization of allylphenols with up to 99% ee were gained.

当它与钯离子配位后只得到了轴构型为S的单金属或双金属配合物，并将该配体应用于钯催化的邻烯丙基苯酚的Wacker-type环化反应中，获得了很好催化活性和高达99% ee。

The biological activities of the metal complexes of derivatives of benzaldehyde nitrogen mustard were investigated against 〓,〓 and SMMC-7721 cell lines. The interesting results were found. When the non-activity ligand combines with cobalt and nickel , the complexes have good antitumor activity, while active ligand binds to the metal, the complex has no activity, indicating there are synergic effect and counteraction between the metals and the ligands.

对所获得苯甲醛氮芥衍生物的金属配合物进行研究，观察它们对SMMC-7721、〓细胞株的作用，发现某些有趣的实验结果，无活性的配体，当与钴，镍形成配合物后，具有很好的抗肿瘤活性，而有活性的配体形成配合物后无活性，揭示在它们存在有协同作用及拮抗作用。

The results showed that coordination occurred between palladium and polymers and the catalyst was stable at room temperature to 200℃.

结果表明，高分子胺配体与钯之间形成配位作用，制备的催化剂在室温～200℃有较好的热稳定性。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。