配体

Carboxylate ligands were widely used in this filed because of their strong coordination ability and various coordination modes.

羧酸配体由于其很强的配位能力和丰富的配位模式，在配合物的合成中被广泛地应用。

Furthermore, the structures of the complexes are strange. The tripodal ligand H〓L〓 form a 2: 2 ring-like binuclear complexes [Eu〓·L〓·6DMF] ·CH〓OH·DMF with Eu〓 in DMF. Two DMF molecules are accommodated in the ring and coordinate with Eu〓.

此外配合物的结构还比较特殊，三足配体H〓L〓与铕的配合物在配位能力较强的溶剂DMF中形成环状的2：2型双核配合物[Eu〓。L〓·6DMF]·CH〓OH·DMF，环状空腔刚好能够把两个配位的DMF溶剂分子包在里面。

The tin atom of the title molecule exists in a distorted- trigonal- bipyramidal geometry, defined by three carbon,one iodineand one oxygen atoms leading to a five - membered chelate ring. The x- ray analysis show tha...

标题化合物分子中的锡原子被配体的三个碳、一个碘和一个氧原子配位；配位原子是畸变的三角双锥构型；标题化合物具有与卤素发生取代反应而不发生加成反应的性质。

Mn-complexes in which Mn atom ligand with the N atom within ligand can stimulate the recovery of electron transfer and oxygen evolution. The trinuclear Mn-complex is extremely sensitive to the addition of CaCl2. It is suggested that there is an interaction between Ca2 and carboxyl within the trinuclear Mn-complex during photoactivation and this interaction benefits the ligation of Mn atom to the apo-WOC and form an active WOC. Binuclear MnMn complex shows slightly higher efficiency than binuclear MnMn complex in restoration of O2 evolution activity. It is suggested from our results that recovery of electron transport and O2 evolution with synthetic Mn-complexes is affected by different factors. Cl- can stimulate the reconstitution of WOC at the concentration of over 100mM;the maximal recovery of O2 evolution activity requires the presence of CaCl2 and 33 kDa protein polypeptide together. Bicarbonate can stimulate the reconstitution of WOC.

锰配合物中锰原子与配体中的氮原子配位连接时，能显著恢复电子传递活性和放氧活性；三核锰化合物在重组时对CaCl2的存在非常敏感，我们认为Ca2 与三核锰化合物中的羧基之间存在一定的相互作用，而这种作用有助于锰原子的光配位进而使三核锰化合物易于组装成有活性的水氧化复合物：双核锰化合物MnMn比双核锰化合物MnMn在恢复放氧活性方面更有效；影响锰化合物电子传递能力恢复的因素与影响锰化合物放氧活性恢复的因素不同；在锰蔟重组过程中，氯离子的浓度必须在100mM以上，才能有效进行光重组；最大光重组效率的获得必须有钙离子和33kDa多肽同时存在；碳酸氢根离子促进锰化合物与去锰光系统II的光组装。

The integrated analytical results show that the novel ligand coexists in ketoform and enolform structures under the measuring conditions, the ketoform structure may change into the enolform structure during the coordination and bonds with the central ion by two O atoms of the enolized hydroxyl group of pyrazolone ring and H2O and the N atom of the imine group and the N atom containing H of benzimidazole ring by losing the proton. And the coordination number of these complexes is four.

综合各种分析结果显示：配体在测试条件下以酮式和烯醇式结构共存，配位时酮式可能转化为烯醇式结构，按去质子的方式以吡唑啉酮环羟基和H2O上的两个O原子以及亚胺基上的N原子和苯并咪唑环上的含氢N原子与中心离子成键，配合物的配位数为4。

Ten kinds of metal and three kinds of organic templates, including ethylenediamine, 1,4-butylenediamine and pyrazine were used in the synthesis of metal phosphonate coordination polymers.

在所合成的16种金属有机膦酸盐配位聚合物中，有机配体为2-羟基乙酰基膦酸，用于配位的金属离子共10种，模板剂3种分别为乙二胺(en，1，4-丁二胺，哌嗪。

The experiment results indicate that higher phase splitting speed and extraction factor can be achieved when low-carbon alcohols such as n-butanol are used as organic solvents; by using five different N-carbobenzyloxy-L-amino acids as chiral ligands that are formated with Cu(superscript 2+) or Ni(superscript 2+), it is found that as a ligand, Z-Phe has a low extraction factor, while Z-Hyp, Z-Pro, Z-Glu, Z-Val have higher extraction factors, and among these, Z-Val has the highest distribution coefficient; pH value of extractant, when near to the PI of phenylalanine, helps to improve extraction resolution effect; temperature has no obvious effect on the resolution result.

结果表明：以低碳醇类正丁醇作有机稀释剂，所用5种N-苄氧羰基氨基酸（分别为Z-Phe、Z-Hyp、Z-Pro、Z-Glu、Z-Val）与Cu(上标 2+)或Ni(上标 2+)形成手性配位体后，以Z-Val作手性配体，萃取相pH值接近苯丙氨酸等电点时，萃取拆分效果最佳。

Solid complexes of rare earth picrates with the ligand 2,6-bis(benzimidazol-2-yl)pyridine have been synthesized and characterized by elemental analysis, IR and electronic spectra. The crystal and molecular structures of the complex [CeL22]·(CH3OH)3 have been determined by single crystal X-ray diffraction.

合成了稀土苦味酸盐与配体2，6-二(2-苯并咪唑基)吡啶的配合物，通过元素分析、红外光谱及电子光谱对配体及配合物进行了表征，并用X射线单晶衍射测定了配合物[CeL22]·(CH3OH)3的晶体结构。

Series of ternary and quadruple doping complexes of europium with benzoic acid ,p-aminobenzoic acid,phthalic acid , m-phthalic acid, and 1,10-phenanthroline were synthesized.

合成了铕与以苯甲酸、对氨基苯甲酸、对硝基苯甲酸、邻苯二甲酸和间苯二甲酸等为第一配体，邻菲咯啉为第二配体的掺杂配合物。

Based on the crystal field theory, perturbation formulas of the spin Hamiltonian parameters g-factors (fourth-order) and the hyperfine structure constants (third-order) of 3d9 ions under tetragonal symmetry are established for the cases of small spin-orbit coupling coefficients and large spin-orbit coupling coefficients of the ligands.

本文基于晶体场理论，在较统一的理论模型和计算方法基础上运用微扰法分别对配体旋轨耦合系数较小和配体旋轨耦合系数较大的情况建立了3d9离子的自旋哈密顿参量g因子的四阶微扰公式和A因子的三阶微扰公式。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。