配体

Chiral ligands mentioned above and their complexes with acetate copper were used as enantio-selective catalysts in asymmetric cyclopropanation reactions of diazoacetate and 1,1-diphenyl ethylene. Investigations indicate that all of them reveal certain optical-selective capability, but chiral C2-symmetric 2,6-bispyridine ligands show better catalytic capability than chiral asymmetric schifF-base ligands.

选择了2个手性2，6-吡啶双噁唑啉配体和6个手性不对称席夫碱配体与醋酸铜形成的配合物作为催化剂，对重氮乙酸乙酯与1，1-二苯乙烯不对称环加成进行催化反应，发现这8个催化剂对1，1-二苯乙烯的不对称环丙烷化反应都表现出了一定的光学活性诱导能力，手性2，6-吡啶双噁唑啉-铜类具有比手性Schiff碱-铜类更好的催化性能。

In addition, there are a large number of strong hydrogenbondings(N-H…O,O-H…O) and weak hydrogen bondings in involving the cations,perchlorate counter-ions,PNOS and water molecules, which result in formation 3-D networkstructure.

晶体中Ni与配体希夫碱中的N 、N(吡吡啶醛类过渡金属希夫碱配合物的合成、晶体结构及谱学表征啶)、O原子配位形成变形的八面体构型，由于分子间，存在大量的强氢键和弱氢键，这些氢键的交互作用使得该配合物形成二维网状结构。

This PhD thesis mainly summarizes the original results on studies of aromatic amide-derived phosphines,including the precatalyst system consisting of Aphos and Pd_2 and the applications for promoting room temperature Suzuki cross-coupling of aryl chlorides and aryl/vinyl bromides,respectively,with aryl/vinyl boronic acids,and alkyl boranes.

本博士学位论文主要总结了对芳基酰胺衍生的膦配体的研究，以及该类型配体与Pd_2组成的催化剂在室温下催化氯代芳烃、溴代芳烃、溴代烯烃分别同芳基硼酸、烯基硼酸及烷基硼试剂进行的Suzuki偶联反应中的表现。

Some stimulators, including viruses, tumor cells and hot shock, could promote the expression of NKG2 receptors and their ligands via activating certain transcription factors which are capable of up-regulating NKG2 promoters' activity. Meanwhile, epigenetic mechanisms including DNA methylation and histone posttranslational modifications are also critical to expression of NKG2 receptors and their ligands and may control the clonally distribution of some NK cell receptors.

病毒、肿瘤和热休克等刺激可以通过激活相应的转录调节因子，提高启动子活性而上调NKG2家族受体及其配体的表达，而启动子区DNA的甲基化状态、组蛋白的乙酰化和甲基化等表观遗传调控，在NK细胞受体及其配体的表达方面亦起重要作用，并决定NK细胞受体的克隆性分布。

Objective To explore the inhibitory effects of total glucosides of paeony on chemokine CCL3 and CCL5 production in Peripheral Blood Mononuclear Cells isolated from patients with rheumatoid arthritis.

目的：探讨白芍总甙对类风湿关节炎患者外周血单个核细胞产生趋化因子配体3(CCL3)、趋化因子配体5(CCL5)的影响。

In order to study the effect of PPh_2 group in the application of chiral ligands 4, 5, 7 and 8 to asymmetric reactions, two ferrocenyl amino alcohols 9a and 9b were Scheme 3 synthesized from chiral amino alcohol derived imines 3 (Scheme 3) and applied in the same asymmetric reactions.

为了探讨二苯氧膦基在配体参与不对称催化反应时对其催化活性和选择性的影响，合成了两个手性二茂铁基氨基醇配体9a和9b(Scheme 3)。

It has been found that the DNA-binding mechanisms and oxidative cleavage of the macrocyclic single nuclear copper complexes are relevant to the rigidity of macrocycle, substitute groups on the side chain, the shape and structure of the complexes.

对一系列结构不同的单核铜配合物的研究表明，大环配体结构的刚性、配体支链上的取代基、配合物的形状与结构等因素对配合物与DNA的相互作用及对质粒DNA的氧化断裂有显著的影响。

Five new solid complexes were synthesized by the coordination of tranisition metals with a Schiff base(C17H21NO,HL) derived from adamantaneamine and salicylaldehyde ,and characterized by elemental analysis,molar conductance,infrared spectra,1H NMR spectra,thermal analysis.

合成了金刚烷胺水杨醛Schiff碱配体(C17H21NO，以HL表示)与5种过渡金属的新的配合物[MCl22]M=Mn(Ⅱ、Co、Ni、Cu、Cd，用元素分析、摩尔电导、红外光谱、1H NMR谱和热重分析对产物进行了表征；讨论了配体与中心金属离子的键合情况，并推测了配合物的结构。

One has the ability of photo-cleavage of DNA and another one as potential anti-cancer drug has the ability of oxidative cleavage of DNA. 1. As for the first system, a new ligand----Tpphz is used as the intercalator of the targeted compound. The 〓 is synthesized and characterized by elemental analysis,〓H NMR, molar conductivity, AgNO〓 titration, UV and fluorescence spectra.

核酸的光切割方面，我们选择了近年来新发现的一个配体Tpphz作为目标化合物的插入配体，合成了新颖的〓单核配合物，并通过元素分析、〓H NMR、摩尔电导测定、中心离子滴定法、紫外光谱和荧光光谱对此化合物进行了详细的表征。

Copper fixation rate affected by retention, fixation time, ligand type, and addictive. For all formulations, while other three conditions is the same, copper fixation rate of preservatives with low retention level is less than those with higher retention level; copper fixation rate of oven-dried bamboo samples is less than air-dried bamboo samples; copper fixation rate of amine-based preservatives is less than ammonia-based ones; copper fixation rate in some formulations containing carbonate and phosphate is higher than non-carbonate and non-phosphate ones.

在其它条件相同时，高吸药量时防腐剂的固着率明显高于低吸药量时的固着率；固着时间长的试样比固着时间短的试样具有更高的铜固着率；以氨水作配体的防腐剂固着性高于以乙醇胺作配体的；碳酸盐和磷酸盐在某些配方中能够改善防腐剂固着性。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。