配体

The central Ni ions are coordinated by six nitrogen atoms from the two I single tridentate ligands L and possess distorted octahedral geometry.

中心镍离子与两个配体上的六个氮原子配位构成变形八面体结构。

A series of lanthanide complexes (Ln = Er, Nd, Yb) with infrared emission properties were designed and synthesized by using different anionic ligands [1 -phenyl-3-methyl-4-(4-tertbutylbenzoyl)-5-pyrazolone and l-phenyl-3-methyl-4--5-pyrazolone and 2-naphtoyl trifluoroacetone] and netural ligands (2,2-dipyridine, phenanthroline, triphenylphosphine oxide and water). Three crystal structures of these complexes were obtained and structure studied, and the properties of photoluminescence and fluorescent lifetime were studied in detail.

我们通过选用不同的第一配体[1-苯基-3-甲基-4-(4-异丁酰基)-5-吡唑酮，1-苯基-3-甲基-4-(4-叔丁基苯甲酰基)-5-吡唑酮和2-萘基三氟乙酰丙酮]和第二配体(2，2-联吡啶，邻菲啰啉，三苯基氧膦)合成了16个稀土红外配合物(Ln=Er，Nd，Yb)，获得了其中三个配合物的单晶结构，研究了这些稀土红外配合物的光致发光和荧光寿命等性质。

In this thesis, on the one hand, two new tripodal ligands and twenty-three of their lanthanide complexes were synthesized, and their fluorescence properties were investigated, on the other hand, nine new copper and silver complexes with six kinds of tripodal ligands were synthesized and their crystal and molecular structures were determined by X-ray diffraction analysis.

本论文一方面合成了两个新三脚架配体的23个稀土配合物，并对它们的发光性能进行了探讨；另一方面得到了涉及六种三脚架配体的9个铜、银配合物，并测定了它们的晶体结构。

By following the "self-assisted molecular editing" protocol first established in our labs,a number of Aphos ligands were efficiently prepared from a single starting material and they were screened for catalytic efficacy, leading to the discovery of the best-performing Aphos appended with a 3-nitrophenyl group at the C4 position.Combination of this Aphos with Pd_2 offers a precatalyst for successful cross-coupling of unactivated aryl chlorides with aryl boronic acids at room temperature.The reactions took place under mild basic conditions to produce the products in high yields.

通过我们首次提出的&自助分子剪裁&的概念从单一起始物快速合成和筛选了一系列膦配体，并发现C4位含3-硝基苯基的的膦配体和醋酸钯联用可以在室温下顺利地催化不活泼氯代芳烃和芳基硼酸的偶联反应，反应条件温和且产物收率很高。

In this study, several systems of proteins in complex with halogenated ligands have been investigated by using a two-layer QM/MM ONIOM methodology.

因此，系统地研究生物体系中的卤键，特别是蛋白质与卤代配体间可能的卤键，阐明卤键在配体识别过程中的作用，对药物发现与设计有重要意义。

The competitive binding of two ligands, ibuprofen and salicylic acid, to human serum albumin was studied using NMR chemical shift and relaxation measurments.

第三章 3。随着蛋白质与配体结合研究的深入，开展了多个配体与单个蛋白相结合的研究。

The effect of the concentration, pH of several ligands such as acetate, oxalate, tartrate and phosphate solution and their orders added on the adsorption and activity of BSA and acid phosphatase on yellow brown soil, latosol, kaolinite, goethite and -MnO2 was first systematically studied by using batch and FTIR methods after analyzed and studied the relative literature that reported in the world.

论文在分析总结了国内外有关研究的基础上，用批量法和傅立叶变换红外光谱法首次系统地研究了乙酸、草酸、酒石酸和磷酸几种配体的浓度、pH及加入顺序对牛血清白蛋白、酸性磷酸酶在黄棕壤、砖红壤、高岭石、针铁矿和二氧化锰表面的吸附行为及活性的影响，探讨了这些配体对蛋白吸附机理及二级结构的影响。

The effect of the concentration, pH of several ligands such as acetate, oxalate, tartrate and phosphate solution and their orders added on the adsorption and activity of BSA and acid phosphatase on yellow brown soil, latosol, kaolinite, goethite and δ-MnO〓 was first systematically studied by using batch and FTIR methods after analyzed and studied the relative literature that reported in the world. The impact of these ligands on the adsorption mechanism and secondary structure of protein was simultaneously engaged.

论文在分析总结了国内外有关研究的基础上，用批量法和傅立叶变换红外光谱法首次系统地研究了乙酸、草酸、酒石酸和磷酸几种配体的浓度、pH及加入顺序对牛血清白蛋白、酸性磷酸酶在黄棕壤、砖红壤、高岭石、针铁矿和二氧化锰表面的吸附行为及活性的影响，探讨了这些配体对蛋白吸附机理及二级结构的影响。

Synthesis and structural characterization of novel cycioplatinated complexes with 2-aryl imidazolines 2-arylimidazoline ligands 2a-2d were synthesized from benzoyl chloride or p-methoxybenzoyl chloride with aminoethanol or valinol and 2e was synthesized from 2-phenylimidazoline.

新型2-芳基咪唑啉环铂化合物的合成与结构表征以苯甲酰氯或4-甲氧基苯甲酰氯和氨基醇(2-氨基乙醇或外消旋的缬氨基醇)为原料，合成了四种2-芳基咪唑啉配体2a-2d，以2-苯基咪唑啉为原料合成了配体2e，其中2d为新化合物。

The fluorescent emission mechanism, and the some factors that affect the energy and the intensities of the fluorescent peaks were studied. The strong powder second harmonic generation efficiencies for complexes (1),(2),(3) and (4) were found. The determination of variable-temperature magnetic susceptibility for complex (3) and complex (5) was performed. The magnetic data were analyzed with their structure properties, and the further information about the magnetic coupling capacity of Carbamyldicyanomethanide as bridging ligand was obtained.

测试了配合物(1)，(2)，(3)，(4)的荧光光谱，从配体的结构特点等方面研究了该荧光光谱的产生机理，研究了影响荧光谱峰能量及强度的因素；发现了配合物(1)，(2)，(3)，(4)显示有强的二阶非线性倍频效应；测试了配合物(3)和(5)的变温磁化率，对所得磁数据进行了结构性质分析，进一步获得了甲氨酰二氰基甲基阴离子作为桥联配体的磁耦合信息。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。