配体

In this paper, we study the synergetic effects of second ligands and luminescence enhancement effects of doping ions starting from the binary complexes of europium and terbium with inexpensive benzoic acid and its derivatives, and improve the luminescence of complexes step by step.

本文从比较廉价的苯甲酸衍生物配体与稀土铕、铽的二元配合物入手，研究第二配体的协同效应和掺杂离子的荧光增强效应，逐步提高配合物的荧光性能。

A new free thiol ligand M-C1ABZM based on C1- ABZM was synthesized and characterized 〓 and MS analysis.

以C1-ABZM为原生配体首次合成了含有巯基的单齿配体M-C1ABZM，其结构通过各种图谱方法得到指认。

We also tested the ligands in the asymmetric epoxide ring opening reaction with thiophenol, and as high as 67%ee was gained while using L7. 3. Studies on the reaction of α-hydroxyketone with nitroalkene.

此外我们还初步尝试了将配体应用于催化苯硫酚对环氧的不对称开环反应中，当使用甲基取代H8-BINOL衍生的配体L7时最高取得了67%ee的结果。

When normal platelets are stimulated by thrombogen, ADP or collagen, the GPⅡb/Ⅲa receptor on the surface of platelet combine with fibrinogen that induces platelet aggregation.

正常血小板在各种刺激下，如凝血酶原，ADP，胶原诱导下被激活，其表面糖蛋白Ⅱb/Ⅲa受体由配体-非结合状态变为配体-结合状态，导致血小板聚集，形成血小板血栓。

Such one-dimensional chains interconnect via hydrogen bonding and π-π interaction to form an extended undulated sheet-like structure.

经配体桥联的两个金属离子的距离是6.703〓。这样的一维链通过配体的NH部分〓Cl及溶剂分子甲醇相互之间形成的氢键连接扩展成二维波浪状结构。甲醇分子被包容在层间。

It was found that the asymmetric induction level of H〓-MAP was exclusively higher than that of corresponding MAP. Under the optimized reaction conditions, the allylation product could be obtained in up to 90.9% ee with H〓-MAP having 3, 5-xylyls as chiral inducer.

发现H〓-MAPs比MAPs类配体取得了更好的不对称诱导效果，在优化的反应条件下，可以得到90.9％ee值的产物，大大高于文献中报道的MAPs配体的最好结果（73％ee）。

Of bidentate ligand DABCO is added exactly as axial ligand to the catalytic system.

以双齿配体DABCO作为轴向配体，双核铁双卟啉催化环己烷羟化反应

Chiral N, P bidentate ligands, were used for the first time in Ag -catalyzed asymmetric addition of allyltributyltin to benzaldehyde.

在此催化体系中，MAP系列氮膦配体的不对称诱导性能明显好于H〓-MAP系列的氮膦配体。

The invention comprises a cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand as well as the synthesis thereof, and the application of the catalyst with cyclopalladated catalyst with axial chiral binaphthyl backbone containing phosphine ligand with a similar structure to the hetero atom norbornadiene ring cleavage reaction through an asymmetric catalytic organic boron agent.

本发明包括一类具有轴手性联萘骨架含膦配体的环钯催化剂及其合成，以及其与具有类似结构的轴手性联萘骨架含膦配体的环钯催化剂在不对称催化有机硼试剂对杂原子降冰片二烯开环的应用。

The intermetallic distance is 7.920(2)〓 which is nearly 2 〓 longerthan that of a analogue formed with olgobipyridine containing two bipyridine linked by〓 at 6,6'- positions.

新配体〓和〓按下列路线合成：〓为首例5，6-位连接的不对称位置取代的寡聚二联吡啶配体，〓的合成也是首次报道。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。