配位体

It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

By using different bidentate auxiliary ligands, a number of one- and two-dimensional azido-bridged coordination polymers and molecular magnets were synthesized, including some with novel structures, and the influences of the ligands on the structure and the magneto-structural correlations in some systems were analyzed.

以不同二齿配体为辅助配体合成了多种一维及二维叠氮桥配位聚合物和分子磁体，较系统地分析了辅助配体对结构的影响及部分体系的磁构关系，并获得几种新的叠氮桥联结构类型。

Three new fulvene polymeric compounds, namely 1[Ag (L3]CH2C12 , 2[Ag2(L25(H2O)(S03CF3)2]0.5C6H6 and 3 Mn(L42(C2H5OH)2 , were synthesized, respectively. Compounds 1 and 2 reported herein represent the organometallic polymers based on both Ag-N and Ag-C coordination interactions. In the solid state, compound 3 are bound together by strong intermolecular N H-O hydrogen bonding system into a supramolecular one-dimensional H-bonded chain.B.

一、富烯有机配体的合成及与金属离子的反应化学利用富烯负离子的芳酰化反应和Heck-偶联反应合成了富烯配体L1-L18，并合成了三个基于富烯配体的金属有机配位聚合物1[Ag(L3]·CH_2Cl_2、2[Ag_2(L25(H_2O)(SO_3CF_3)_2]·0.5C_6H_6和氢键驱动的超分子聚集体3Mn(L4_2(C_2H_5OH)_2。

Two qina ligands chelate a cobalt ion by 0 and N atoms and two DMSO ligands coordinate a cobalt ion by two O atoms at an axis. The complex formed inerratic octahedron configuration, and π-π stacking weak interaction was observed between the molecules.

配合物为单斜晶系，P2(1)/C空间群，2个qina配体以氮原子和氧原子与Co离子螯合配位，2个DMSO以氧原子与Co离子轴向配位，形成规则的八面体构型配合物，分子之间存在π-π堆积弱相互作用。

In complexes 8～16 synthesized by hydrothermal method, most of the ligands adopt multidentate coordination modes joining several lanthanide ions into high-dimensional coordination polymers. And changing of 5-substituting group on isophthalic acid has a little effect on the coordinated abilities of the meta-carboxyl groups.

水热法制备的配合物8～16中，配体多采取多齿配位模式桥连多个稀土离子，形成高维配位聚合物，同时由于羧基氧原子和稀土离子的强的键合力，间苯二甲酸的5位取代基的变化对间位羧基的配位能力的影响不大。

We have studiedthe coordination water-substituted reactions and the phase-transferchemistry of dozens of trinuclear or tetranuclear sandwich-typePOMs and found that organic molecules or polymers can becoordinated to these polyanions after dehydration, thus more thanone hundred coordinated products are obtained, indicating that thesepolyanions are excellent ligands in organic solvents.

我们首次对夹心三、四核等几十种化合物中配位水进行了配位水取代反应及相转移化学研究，脱水后可配位有机分子或有机高分子，得到上百种配位产物，因此在有机溶剂中它们是优秀的配体。

The crystal consists of two similar but independent molecules in the asymmetric unit and the Ce ion coordinated toward ten donor atoms, six of which belong to the nitrogen atoms of two tridentate ligands and four oxygen atoms from two bidentate picrates.

晶体中一个不对称单元内有两个结晶学上独立的分子，这两个分子的构型基本相同，中心Ce3＋均与两个三齿配位的配体及两个双齿配位的苦味酸根配位，配位数为10。

In order to investigate the relation between the ligands and rare earth ions, in this dissertation, two new polyaza cryptands, two new tripyrazolone ligands, a macrobicyclic rare earth cryptates, a tripyrazolone and a tripodal ligands rare earth complexes have been synthesized.

为了进一步研究和探讨穴醚、吡唑啉酮、三脚架化合物配体对稀土元素的配位作用，论文首次报道了两个新氮杂穴醚配体、两个新三脚架吡唑啉酮结构配体、一个系列大二环新型的稀土配合物、一个系列三脚架吡唑啉酮结构配合物、一个系列三脚架结构三酸配合物的合成。

Employing high-dilute method and 5-fold excess amine prepared two new "two-armed" acyclic diamine intermediates I_a and I_b, which are also intermediates of synthesizing microcyclic compounds, and eight aromatic Schiff bases, II_, were synthesized from reaction of I_a or I_b condensing with different aromatic aldehydes. Their composition and structure were characterized by Elemental analysis, IR, UV-Vis, LIF,~1HNMR and MS. The hydrogen bond interactions and MS fragmental patterns were also discussed.3. Several novel transition metal complexes using II_a as ligand were synthesized and identified by Elemental analysis, IR, UV-Vis,~1HNMR and molar conductivity.

1，采用高度稀释及胺过量五倍的方法合成了两个具有吡啶双酰胺臂的非环二胺Ⅰ_a和Ⅰ_b，并以它们为中间体进一步合成了八个芳香席夫碱Ⅱ_a-Ⅱ_h，通过元素分析及各种波谱测试鉴定了它们的组成与结构，对化合物的UV-Vis、LIF、IR、~1HNMR及MS进行了较为详细的讨论，还探讨了席夫碱的氢键相互作用及质谱裂解方式； 2，以席夫碱Ⅱ_a为配体合成了几个新型的过渡金属配合物，并通过元素分析、UV-Vis、IR、~1HNMR、摩尔电导及DTA—TG对其进行了表征，讨论了化合物的配位情况及配体在配位中的脱质子行为。

The Laser Raman Microprobe study of these quenching melts has obviously shown that within the high frequency region (900~1200cm-1), the higher the pressure, the smaller the frequency of T-Onb symmetry and antisymmetry stretching vibration.

其激光拉曼微探针研究表明：随压力增大，T-Onb在高频区(900~1200cm-1)的对称和反对称伸缩振动频率明显减小；过铝质熔体中存在六配位铝，且随压力增大，铝的配位数可能有从四配位向六配位转化的倾向。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。