配位体

From the equilibra configures obtained during simulating, it was suggested that there is mainly chaintype structure in the LiBO〓 melt, and the dominative variations during the process of being fused may be the decomposition of the long chains, then large member of nonbridge oxygen was come into being in the shorter chains resulting from the decommission.

模拟得到的二硼酸锂熔体中，三配位和四配位的硼氧结构共存，其间相互结合成环状结构；而在偏硼酸锂熔体中没有发现四配位构型，由平衡构像分析，该熔体中可能以链式结构为主，熔化过程中主要的结构变化是长链的分解，分解产生的短链结构产生了大量非桥氧。

It crystallizes in the monoclinic space group C2/c, with a=1.6953(3)nm, b=1.9241(4)nm, c=1.7760(4)nm,β=94.75(3)°. Each Gd ion is coordinated by two oxygen atoms from two different radicals NITPh(OCH3)3 and six oxygen atoms from three hfac molecules to form eight-coordinated dodecahedron geometry.

Gd离子采取八配位的模式，两个氮氧自由基作为单齿端基配体分别以氮氧基团的氧原子与Gd离子配位，三个六氟乙酰丙酮阴离子分别以两个氧原子与Gd离子配位，构成十二面体。

Cu and Co ions are coordintated with six oxygen atoms from two water molecules and four ligands to form an octahedral geometry. Each ligand links two metal ions in a μ2-bridge coordination mode and two-dimensional wavelike structures are formed.

Cu和Co均为六配位，八面体构型，每个金属离子与4个配体和2个水分子配位，每个配体采取μ2-桥联模式，形成二维层状结构。

The coordination mode of La can be described as a distorted aquare antiprism, which was completed by two oxygen atoms from one oxalate, four oxygen atoms from four different PDC ligands, and two oxygen atoms from two water molecules.

La呈现四方反棱柱体的配位模式，分别和2个来自同一个草酸配体的氧原子、4个来自4个PDC配体的氧原子以及2个来自2个配位水分子的氧原子配位。

The X-ray crystal structure analysis of the complexes shows that all lanthanidecomplexes exhibit a tripodal ligand coordination mode, with three imino nitrogenfrom benzimidazolyl and pyridyl group, and one amino nitrogen atoms as donors.The ligands show two kinds of configuration: the fan-like and the pincer-like. Bothintra- and intermolecular π-π interactions are found in these complexes.

晶体结果表明，在所有的稀土配合物中，三脚架配体均用三个支脚上的苯并咪唑、吡啶环氮原子及一个顶端的氮原子和稀土离子进行配位，表现出三脚架式配位方式，同时，三脚架配体有风扇形及钳子形两种空间配位构型，并形成了分子内及分子间的π-π堆积作用。

The results are following:(1)We investigated the influence of the positional isomeric effect on structures.Due to the less space-crowding,it is easier for 3-pytpy to behave as bridging ligand than 2-pytpy under the same reaction conditions,while,it is easier for 2-pytpy to function as tridentate chelating ligand to construct supramolecular structures.

研究结果如下：(1)研究了两个吡啶取代三联吡啶配体的位置异构效应对配合物结构的影响。3-pytpy配体比2-pytpy具有更小的空间位阻，在相同的合成条件下容易以单-三齿桥联方式配位；而2-pytpy更易以三齿螯合形式配位，通过π…π堆积作用形成超分子结构。

The results indicated that: Tripyrazolone, tripodal and crptands ligand L〓, L〓 and L〓 have good coordination ability with rare earth ions Rare earth ions were coordinated with their oxygen and nitrogen atoms.

结果表明，三脚架结构吡唑啉酮、三酸和穴醚配体与稀土离子有较好的配位作用，它是通过氮原子、氧原子与稀土离子配位的。而穴醚配体与稀土离子配位效果却不好。

In compound 1, Co is in a distorted octahedron environment with four nitro-gen atoms from the tripodal ligand and two oxygen atoms from the bridged oxalate, and the molecule is a dimmer-ic structure consisting of two LCo unites linked by bridging oxalate.

在配合物1中，Co与来自三脚架配体的4个氮和草酸根桥联配体的2个氧原子配位，处于扭曲八面体配位环境。由草酸根桥联两套LCo，构成了一个双核结构。

For comp ound 7, the cage is consisted by six MoO〓 and four PO〓. The six MoO〓 octahedrons have consisted to the loop structure, the there PO〓 tetra hedron become triangle and the other one lies the centre. The one oxygen of two MoO〓 octahedron is coordinated to Mn atom which linked the other cage like this cag e and this Mn have six ligands.

在化合物7中，每一个笼由6个MoO〓八面体和4个PO〓四面体构成，6个MoO〓八面体构成环，四个PO〓四面体形成一个三角形在其上面，4个P和6个Mo具有C〓的对称性，每二个MoO〓八面体提供一个O原子与Mn原子配位，这个Mn原子再与相同的这样的笼相连，形成一个中间细两端粗的形状，这个Mn原子是6配位的，每一个这样的笼再通过一个Mn原子连接起来，形成二维的网状结构，而这个Mn原子是五配位的。

As the distances between coordination sites of auxiliary ligands increasing, the distances between adjacent two-dimensional [Er(5-NO_2-bdc)_2]~- anion layers enlarged. As the bulks of auxiliary ligands largening, the coordination configuration of Er optimized and the dimensions of coordination polymers increased.

增大辅助配体的配位点之间的距离，增大了二维[Er(5-NO_2-bdc)_2]~-阴离子层之间的距离；增大辅助配体的空间位阻，优化了金属离子的配位几何构型，使配位聚合物的维度增大。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。