配位体

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构，化合物8是白花丹素的Na盐，以离子化合物形式存在；化合物9～16为白花丹素的La，Y，Dy，Sm，Gd，Nd，Er，Eu的稀土金属配合物；化合物17是白花丹素的双核钇结构；化合物18为白花丹素的单核钇结构，该配合物除了含白花丹素外，还有来自白花丹植物中的另一个单体化合物也参与配位；化合物19～21是以2，2\'-联吡啶和邻菲咯啉等含N配体为辅助配体，具有白花丹素—含N配体—金属离子的三元配合物，化合物19是白花丹素和2，2\'-联吡啶与Cu的配合物，具有五配位的四方锥构型，通过Cu…O弱的成键作用形成二聚体，再通过分子间的氢键作用进一步形成一维链状结构，化合物20和化合物21是白花丹素分别与2，2\'-联吡啶和邻菲咯啉的Zn配合物，都具有六配位八面体构型的双核锌配合物，呈一维链状结构，化合物20中链与链之间的大量氢键将一维链扩展成二维层，分子间的π-π堆积作用进一步形成三维结构。

The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配位的配合物的晶体结构；得到了一个在空间上存在位阻作用的配体与金属离子2：1结构的晶体；解析了具有特色的一个配体（LA4）和三个配合物（4、7和10）的晶体结构，其中的配体与金属离子的配位作用显示出细微的差异，表明在同一金属配合物的晶胞中，可以同时存在着多个稳定的构象。

Usage: useful for pharmaceutical intermediate,especially useful for intermediate of synthesis aids inhibitor and high temperature resistant resins and metallocen catalyst for olefine polymerization.

用途：用作各种医药合成中间体，特别是抗艾兹病药物，治疗糖脲病药物以及治疗心律不齐病药物的中间体以及烯烃聚合用金属茂络合物催化剂配位体和透明的耐热性树脂原料。

A new method is presented for synthesis of organosilicon compounds directly from precipitated white carbon black by reduced pressure distillation.

该文研究了以沉淀白炭黑为原料，采用减压蒸馏法直接合成六配位体有机硅化合物的新方法。

It is shown from study results that the soluble iron has a strong controlling effect on the phytoplanktonic growth, and most of soluble iron is chelated with ligand such as siderophore with high affinity to Fe 3+.

研究表明，可溶性铁对浮游植物生长有很强的控制作用，大部分可溶性铁是同具有极强铁亲和力的配位体螯合在一起的，如铁载体。

The salt effect of biosorption process might be related with the radii of cations and the stability of chelates, maybe also related to the interaction between anions and functional groups which had positive charge.

生物吸附过程的盐效应可能与阳离子的半径以及与配位体所形成的配合物的稳定性有关，也可能与菌体表面带正电荷的官能团与阴离子之间的静电作用有关。

The results show that when alkaline earth metal oxides are used as the medium, the products are hexacoordinate silicon complexes, and that under the optimum synthetic conditions, the conversion yields of barium salt and calcium salt are greater than 90% and 60% respectively.

结果表明：以碱土金属氧化物为介质时，合成产物为六配位体有机硅化合物；在最佳合成条件下，钡盐的转化率达90%以上，钙盐的转化率在60%以上。

The influence of the distance from the ligands on the one-lectron energy levels are discussed.

讨论了配位体的距离对单电子轨道和基态组态的影响，也讨论了对称性变化的影响。

Exchang reaction of carbonyl with organic or inorganic ligands of electron-doner and metathesis of metal halids with carbonyl metal negative ion have been used to prepare some heteronuclear atomic clusters. The reaction condition are often moderate. They performed easier and have, a mord yield.

利用给电子有机和无机配位体的交换反应和金属卤化物与羰基金属阴离子的复分解反应，合成异核原子簇具有反应条件温和易于控制，收率较高的特点。

Heavier terminal halogenatoms can also increase the values of Ka and Kr.

较重的卤族终端配位体也能提高Ka和Kr值。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。