配位体

To our surprise we achieved the ligand 9, 11 and 29 with coordinating atoms fixing at benzylic and benzene ring positions, whose structure is unique in the planar chiral cyclophane chemistry.

以钯催化的烯丙基取代反应对配体进行了考察，硫醚或硒醚取代基在苄位取代的配体表现出更高的反应活性和更高的对映选择性，配体9和11均给出最高为94％的ee值。

In order to solve the backward electron transfer problem, 9 kinds of rhenium bipyridyl photosensitive dyes with different electron donating groups on the p or m-position of the pyridine rings, 2 kinds of rhenium bipyridyl and 2 kinds of ruthenium tris-bipyridyl photosensitive dyes with two tyrosine ethyl ester groups on the bipyridyl rings were designed and synthesized.

本文针对该类太阳能电池中存在的电子回传问题，设计合成了在吡啶配体的间位和对位带有不同供电基团的9种铼联吡啶光敏染料，在联吡啶配体上带有两个酪氨酸基团的2种铼联吡啶和2种钌三联吡啶光敏染料。

The results show that the zirconium sol has good spinnability when n: n= 1:3, reaction time is 6h and aging temperature is 15℃. The ZrO_2precursor fibers are made from hydrous zirconia chelated by acetylacetone. The sintercd fibers arecomposed of metastable tetragonal phase and sized about 15μm in diameter. Moreover, there aremany pores inside the fibers, but no cracks.4. ZrO_2/PVP hybrid fibers were prepared by blending the spinnable zirconium sol and 10 wt%PVP solution.

结果表明，当n(ZrOCl_2·8H_2O)：n(H_2O_2)=1：3，反应时间6h，陈化温度15℃时可得纺丝性能良好的锆溶胶，ZrO_2前驱体连续纤维的组成主要为经乙酰丙酮配位的ZrO_2水合物，热处理后的ZrO_2纤维的相结构为亚稳四方相，纤维的直径为15μm左右，纤维中存在大量的纳米级气孔，但无明显裂纹。4。

Structural analysis reveals that the assemblies of these complexes are mainly directed by counter anions, followed with the change of anions from simple inorganic species (SCN~-/dca/Cl~-) to organic ones (ip/nip/tp/chdc), diversiform structures are formed varying from mononuclear, tetranuclear molecules to infinite 1-D and 2-D frameworks.

第三章利用4-bpt的同分异构体4-氨基-3，5-双(2-吡啶基)-1，2，4-三唑(2-bpt)作为螯合试剂，与多种无机/有机阴离子以及金属Cd~盐反应，得到了一系列Cd~配位化合物(7-15)。

The crystal structures have been determined by X-ray diffraction method, which show that the new complex [Co2-Co(2)(0H2)s] belongs to the bridging binuclear complex and the system of monoclinic with space group P211~,unit cell parameters a8.3850(10)A, b=27.386(4) A, c=9.610(2) A,~=98.280(10)~,V=2 183.8(6) A3 , Z=4, Dc=l.746Mg/m3,~i =l.597mm, F(000)=1168, Final R=O.0253 and wR=O.0610 S1.009 ,The two Co2~ are in distorted octahedrons. The part of [2Co] possess an approximate D2d symmetry, while the part of [OCo(2)(0H2)5] has an approximate C2 symmetry.

结构分析表明配合物(1)[Co1，(DPC2-Co(2)(OH2)5]是一个未见报导的桥联双核配合物，属单斜晶系，空间群为P2_1／c，晶胞参数：a=8.3850(10)A，b=27.386(4)A，c=9.610(2)A，β=98.280(10)A，V=2183.8(6)A~3，Dc=1.746Mg／m3，Z=4，μ=1.597mm-1，F(000)=1168，结构偏离因子R=0.0253和ωR=0.0610，吻合因子S=1.009，Co_(1)和Co_(2)的配位多面体皆为扭曲正八面体，[_2Co_(1)]部分具有近似D_(2d)对称性，[OCo(2)(OH_2)5]部分具有近似C_2对称性。

In case of morphological change, the deactivated catalysts can be partly renewed by impregnating with 12%〓SO〓 solution, in which most of the components can the redissolved and redried and reactivated.

根据对V-K-S-P／SiO〓催化剂综合研究分析，认为影响苯酐收率的主要因素有，活性体在反应状态下所处的相态，催化剂表面V〓、V〓的分布及其与助剂间的配位环境，催化剂表面几何形貌与结构。

The UV-visible spectra of oxidized and reduced F28Y and F106Y were in agreement with the wild NGB, but the oxidized F28Y＇s Sorer band had a 2 nm blue shift, which suggested that the two mutants still remain hexa-coordinated form.

氧化型和还原型F28Y及F106Y的紫外-可见吸收光谱与野生型相似，仅氧化型F28Y的Soret带有2nm的蓝移，说明这两种突变体蛋白仍保持六配位形式。F28Y的荧光最大发射峰明显红移（340nm→347nm），表明其荧光基团更加暴露于极性环境中。

A neutral non-cyanide copper plating (rack plating and barrel plating) process was developed.

开发出钢铁基体上中性无氰镀铜工艺，其配方中的配位剂是需要经过多道工序合成的具有x结构的化合物，还含有醋酸铜和磷酸二氢钠。

The process formulas consist of a complexing agent with a structure ofx synthesized by several procedures, and copper acetate and sodium dihydrogen phosphate.

开发出钢铁基体上中性无氰镀铜工艺，其配方中的配位剂是需要经过多道工序合成的具有x结构的化合物，还含有醋酸铜和磷酸二氢钠。

In compound 1, two independent other than dimerized copper-phenanthroline graups are fused to the oxggen atoms in the vacant site of the mono-lacunary polyanton in parallel.

该化合物分子中2个独立的非二聚体的铜－邻菲啰啉平行地与缺位多酸空穴外的氧配位键合，通过元素分析、红外光谱、热重分析和X射线单晶衍射对其结构进行了表征。

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。