配位

The spectral data suggest that intramolecular carbonyl oxygen to tin coordination in 1 is existent and is not allowedin order to accommodate two and three bidentate dithiocarbamate ligands in 3 and 4 respectively.

波谱数据表明化合物1和2存在着分子内羰基氧原子对锡原子的配位，而在化合物3和4中这一配位则被两个或三个双齿二硫代氨基甲酸配体所替代。

Metal-Organic coordination polymers are formed by self-assemblythrough coordination bonds between bidentate or multbentate organic ligands and central metal ions.

金属有机配位聚合物是通过含给电子基团的双齿或多齿有机配体和一种或几种中心金属离子通过配位键自组装而形成的。

Metal-Organic coordination polymer is formed by self-assembly through coordination bond between bidentate or multbentate organic ligand and central metal ion.

金属有机配位聚合物是通过含给电子基团的双齿或多齿有机配体和一种或几种中心金属离子通过配位键自组装而形成的。

The chelating ability of its enolate anion (TTF-ph-tfac) has been investigated with [MIICl_2·xH_2O] (M = Zn and Co) leading to complexes Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7) and Co(TTF-ph-tfac)_2(CH_3OH)_2 (8), where the metal center is coordinated by two TTF-ph-tfac ligands. This redox active ligand shows promising features for the elaboration of hybrid organic-inorganic building blocks.

具有反铁磁行为的化合物5在110-120K观察到了相转变的发生，是目前已报道的该类化合物中最高的相变温度。3、TTF-ph-tfac烯醇阴离子具有很强的配位能力，与金属氯化物螯合配位分别生成了配合物Zn(TTF-ph-tfac)_2(CH_3OH)_2 (7)和Co(TTF-ph-tfac)_2(CH_3OH)_2 (8)，每个中心金属都桥连两个TTF-ph-tfac配体。

The crystal is monoclinic,space group 〓, the ligand coordinates to Ni acetate in the enolic form,and produces a square complex.

单晶的结构是：晶体属于单斜晶系，空间群为〓，镍原子位于平面四方形配位中心，配体分子是以内式的烯醇式向镍原子配位的。

The results show that:(1) When N-methylethylenediamine and N, N'-methylethylenediamine equatorially coordinated to Cd〓, arenedisulfonates such as 1, 5-naphthalenedisulfonate, 2, 6-naphthalenedisulfonate and 4, 4'-bipenyldisulfonate act as a bridging ligands coordinated to adjacent Cd〓 centers, leading to a one dimensional chain structure.

研究结果表明：（1）N-甲基乙二胺和N，N'-二甲基乙二胺与Cd〓在赤道平面配位后，芳烃二磺酸根离子作为桥联配体与相邻的Cd〓在轴向配位形成了一维链状结构。

The results show that:(1) When Cu〓 equatorially coordinated by four nitrogen atoms from amine ligands such as ethylenediamine, N-methylethylenediamine, 1, 2-diaminopropane and 1, 4, 8, 11-tetraazacyclotetradecane, etc., Cu〓 could be axially coordinated by oxygen atoms of-SO〓 group.

研究结果表明：（1）当Cu〓在赤道平面与来自胺配体（如乙二胺、N-甲基乙二胺、1，2-丙二胺和1，4，8，11-四氮杂环十四癸烷等）的四个氮原子配位后，在轴向则可以与来自磺酸根离子的-SO〓基团氧原子配位。

When Ni〓 was equatorially coordinated by four nitrogen atoms from the same amine ligands such as ethylenediamine and N-methylethylenediamine, arenedisulfonates did not axially coordinated to Ni〓.

Ni〓与同样的胺配体（如乙二胺、N-甲基乙二胺）的四个氮原子在赤道平面配位后，芳烃二磺酸根离子并没有在轴向与Ni〓配位，水分子仍然占据轴向的位置。

Totally 17 new type of fulvene ligands have been synthesized by the reaction of substituted-benzoyl chloride with Cp and substituted Cp anions. All the new compounds are fully characterized by infrared spectroscopy,!

我们利用含芳香取代基的环戊二烯丛负离子与含-CN、-I、-CO_2CH_3等配位有机基团的芳酰氯反应成功地合成了17个既含芳香基团又含杂原子配位基团的刚性共轭富烯类配体。

Therefore heteronuclear Cu-Ln compounds have commonly been synthesized with hetero-donor ligands comprising two types of ligating atoms coordinated each to Cu and Ln atoms, respectively.

因此通常用含有能分别和铜，稀土配位的两种配位原子的配体来合成异核Cu-Ln配合物。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。