配位

In the mixed solvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styrene oxide is good but the conversion of styrene is low due to the coordination to the catalyst of the solvent.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高，但由于溶剂对催化剂的配位作用抑制了催化剂的活性，苯乙烯转化率很低；当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后，苯乙烯的转化率提高，生成环氧苯乙烷的选择性不变。

In this thesis, this system is used for epoxidation of propylene and styrenewith good results. The solvent effect is investigated for epoxidation of styrene. In the mixedsolvent of dimethyl phthalate / TBP or phenyl ether / TBP, the selectivity for styreneoxide is good but the conversion of styrene is low due to the coordination to thecatalyst of the solvent. When part of dimethyl phthalate or phenyl ether is replacedby toluene, the conversion increases and the selectivity keeps constant.

邻苯二甲酸二甲酯或二苯醚等与磷酸三丁酯的混合溶剂中环氧化的选择性较高，但由于溶剂对催化剂的配位作用抑制了催化剂的活性，苯乙烯转化率很低；当部分的邻苯二甲酸二甲酯或二苯醚被甲苯取代后，苯乙烯的转化率提高，生成环氧苯乙烷的选择性不变。

As a result, polymers with hydroxyl end groups would be ideal reductants for controlled synthesis of metal nanostructures.

聚合物PVP中端羟基的弱还原性和N原子的配位能力使其常被作为表面活性剂或模板来合成纳米材料。

Some principles were preposed which should be followed in the production of various color decorative cement.

本文利用晶体场理论解释了所得到的掺杂硅酸钙的光学吸收光谱和电子顺磁共振谱，并由此半定量地计算了对装饰水泥的颜色特性有较大影响的五个过渡金属元素铬、锰、铁、钴、镍在硅酸钙中的晶体场参数，确定了它们的价态，配位状态和置换方式，提出了生产不同颜色的装饰水泥所应遵循的一些原则。

Analyses of spectroscopic and crystal structural data of iridium complexesIr(PR3)Cl and the Vaska's complex reveal that NHC ligands and phosphines have a similar donating ability toward Ir metal center.

并且从光谱分析及晶体结构数据发现[Ir(PR3)Cl]的错合物与Vaska's 错合物相当类似。因此，我们推论其含氮杂环碳烯与膦化物在ㄧ价铱金属上有相似的配位能力。

We studied the number of ordinated water of polyoxometalate catalysts how to affect the catalytic activity.

2，研究了1 ， 2-二氯乙烷做溶剂，催化氧化环己烯的体系中杂多酸所含配位水的数量对催化剂活性的影响。

The calculations on the binding energy and the population analysis of the ribose-Ln complexes were made by using the coordinates obtained from its single-crystal structures. Theoretical interpretions on the coordination between ribose and rare-earth metal ions were given by the results of the calaulation.

利用本论文得到的一系列的核糖—稀土配合物的单晶结构数据，对各配合物分子的结合能、配合物中各原子的净电荷布居以及稀土金属离子中各原子轨道在成键中的作用等方面内容进行了量子化学计算，并为核糖与稀土金属离子的配位作用提供了理论解释。

The intensive discussion, about the competitive reactions in the y-irradiation process of the stock solution, and experimental results indicate the stability constants of the metal chelates with ethylenediamine, the solubility product constants of the metal sulfides, and the standard electrode potentials of the metal ions directly control the formation of metal sulfides.

深入讨论了金属盐和硫粉在γ—射线辐照乙二胺溶液形成的还原气氛中存在的多种竞争反应，以及金属离子和乙二胺的配位常数、金属硫化物的溶度积常数和金属单质的标准电极电势对制备纳米硫化物的影响。

Aspecial sturcture containing two one-fold atoms, two triple bond (1.95),was obtained after geometry optimization.

在模型几何优化中，得到了带有2个一配位原子的特殊结构，它含有2个三键（1.95）。

Misfit dislocation ; epitaxial growth ; thin film ; molecular dynamics ; aluminum

失配位错；外延生长；薄膜；分子动力学；铝

According to the clear water experiment, aeration performance of the new equipment is good with high total oxygen transfer coefficient and oxygen utilization ratio.

曝气设备的动力效率在叶轮转速为120rpm～150rpm时取得最大值，此时氧利用率和充氧能力也具有较高值。

The environmental stability of that world - including its crushing pressures and icy darkness - means that some of its most famous inhabitants have survived for eons as evolutionary throwbacks, their bodies undergoing little change.

稳定的海底环境─包括能把人压扁的压力和冰冷的黑暗─意谓海底某些最知名的栖居生物已以演化返祖的样态活了万世，形体几无变化。